NiFe2O4/rGO电极材料的制备及电催化HMF氧化性能研究

doi:10.11896/cldb.23110252

材料导报

2024, Vol. 38

Issue (14): 23110252-6 https://doi.org/10.11896/cldb.23110252

无机非金属及其复合材料

NiFe₂O₄/rGO电极材料的制备及电催化HMF氧化性能研究

王洪雷^1,*, 牛彩云², 朱宏跃¹, 李晓明¹, 周丹¹, 孙志刚³, 胡季帆³, 杨昌平^3,*

1 太原科技大学化学工程与技术学院,太原 030024
2 中北大学化学化工学院,太原 030051
3 太原科技大学材料科学与工程学院,太原 030024

Preparation of NiFe₂O₄/rGO Electrode Material and Its Electrocatalytic Performance for HMF Oxidation

WANG Honglei^1,*, NIU Caiyun², ZHU Hongyue¹, LI Xiaoming¹, ZHOU Dan¹, SUN Zhigang³, HU Jifan³, YANG Changping^3,*

1 School of Chemical Engineering and Technology, Taiyuan University of Science and Technology, Taiyuan 030024, China
2 School of Chemistry and Chemical Engineering, North University of China, Taiyuan 030051, China
3 School of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China

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摘要利用五羟甲基糠醛(HMF)电合成的2,5-呋喃二甲酸(FDCA)具有与对苯二甲酸相似的结构和性质,为开发可降解性塑料、减少白色污染提供可能。利用CO₂激光成功合成了NiFe₂O₄/rGO电极材料,其微观形貌呈纳米颗粒镶嵌的氧化石墨烯结构。原位拉曼光谱表明,与Fe₅O₁₂/rGO电极材料相比,在HMF电催化氧化过程中NiFe₂O₄/rGO表面重构为NiOOH和FeOOH物种,证实了Ni的加入使材料更易发生表面重构。表面重构的NiFe₂O₄/rGO电极材料在100 mA· cm^-2时过电位降低至26 mV,且较制氧反应(OER)过电位降低约182 mV。表面重构后的电极材料拥有更大的比表面积,促进了反应物与电极材料的接触。反应物的转化率、目标产物的选择性及法拉第效率分别为99.8%、99.3%和87.6%。本研究为元素加入促进催化材料表面重构进而提高HMF的电催化氧化活性提供了有效途径。

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	王洪雷
	牛彩云
	朱宏跃
	李晓明
	周丹
	孙志刚
	胡季帆
	杨昌平

关键词: 电催化 CO₂激光 NiFe₂O₄/rGO电极材料表面重构

Abstract: The 2,5-furandicarboxylic acid (FDCA) synthesized by electro synthesis of 5-hydroxymethylfurfural (HMF) has a structure and properties similar to terephthalic acid, providing the possibility for developing biodegradable plastics and reducing white pollution. The NiFe₂O₄/rGO electrode material was successfully synthesized using CO₂ laser, and its microstructure presents a nano particle embedded graphene oxide structure. In situ Raman spectroscopy showed that compared with the Fe₅O₁₂/rGO electrode material, the NiFe₂O₄/rGO surface was reconstructed into NiOOH and FeOOH species during the HMF electrocatalytic oxidation process, confirming that the addition of Ni makes the material more prone to surface reconstruction. The surface reconstructed NiFe₂O₄/rGO electrode material showed a decrease in overpotential to 26 mV at 100 mA· cm^-2, and a decrease of approximately 182 mV compared to the oxygen production reaction (OER) overpotential. The electrode material after surface reconstruction has a larger specific surface area, which promotes the contact between reactants and electrode material. The conversion rate of reactants, selectivity of target products, and Faraday efficiency were 99.8%, 99.3%, and 87.6%, respectively. This study provides an effective approach for promoting surface reconstruction of catalytic materials through the addition of elements, thereby enhancing the electrocatalytic oxidation activity of HMF.

Key words: electrocatalysis CO₂ laser NiFe₂O₄/rGO electrode material surface reconstruction

出版日期: 2024-07-25 发布日期: 2024-08-12

ZTFLH:

O646.542

基金资助: 山西省应用基础研究计划(202203021222185);太原科技大学博士科研启动基金(20222092);太原科技大学留晋博士优秀奖励基金(20232058);太原科技大学大学生创新创业项目(XJ2023058)

通讯作者: * 王洪雷,太原科技大学化学工程与技术学院讲师。2022年8月获得大连理工大学博士学位,主要从事微纳材料的合成与表征及其在力、电、磁等作用下的表面行为,并应用与电合成高附加值产品方面。先后在Advanced Energy Materials、Nano Energy、Applied Catalysis B-Environmental、Che-mical Engineering Journal、Journal of Materials Chemistry A、ChemSusChem等期刊发表SCI论文10余篇,授权国家发明专利1项。wanghonglei89@tyust.edu.cn
杨昌平,太原科技大学材料科学与工程学院特聘教授,教育部新世纪优秀人才。1998年7月毕业于中国科学院物理研究所,获理学博士学位。目前主要从事凝聚态物理、磁电功能材料和电化学能源材料与器件的科学研究和技术开发工作,撰写科技专著5部,获批国际发明专利3项,国内发明专利10余项,发表科技论文200余篇,获湖北省自然科学奖励1项。2019074@tyust.edu.cn

引用本文:

王洪雷, 牛彩云, 朱宏跃, 李晓明, 周丹, 孙志刚, 胡季帆, 杨昌平. NiFe₂O₄/rGO电极材料的制备及电催化HMF氧化性能研究[J]. 材料导报, 2024, 38(14): 23110252-6.
WANG Honglei, NIU Caiyun, ZHU Hongyue, LI Xiaoming, ZHOU Dan, SUN Zhigang, HU Jifan, YANG Changping. Preparation of NiFe₂O₄/rGO Electrode Material and Its Electrocatalytic Performance for HMF Oxidation. Materials Reports, 2024, 38(14): 23110252-6.

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http://www.mater-rep.com/CN/10.11896/cldb.23110252 或 http://www.mater-rep.com/CN/Y2024/V38/I14/23110252

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