黄磷生产中固废处置与资源化利用研究进展

doi:10.11896/cldb.23080072

材料导报

2024, Vol. 38

Issue (22): 23080072-8 https://doi.org/10.11896/cldb.23080072

无机非金属及其复合材料

黄磷生产中固废处置与资源化利用研究进展

王郎郎¹, 张韶¹, 费政富¹, 宁平^1,*, 王学谦¹, 刘敬业¹, 谢怡冰¹, 马懿星¹, 王华²

1 昆明理工大学环境科学与工程学院,昆明 650500
2 昆明理工大学冶金与能源工程学院,昆明 650093

Research Progress of Solid Waste Disposal and Resource Utilization in Yellow Phosphorus Production

WANG Langlang¹, ZHANG Shao¹, FEI Zhengfu¹, NING Ping^1,*, WANG Xueqian¹, LIU Jingye¹, XIE Yibing¹, MA Yixing¹, WANG Hua²

1 Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China
2 Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China

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摘要黄磷是我国国民经济的重要支柱产业,属于国家战略资源。随着我国磷化工行业的飞速发展,黄磷产能跃居世界首位。我国黄磷生产规模庞大,但生产工艺竞争力不强、磷资源利用率较低。生产过程中磷副产物成分复杂、生成量大。其中黄磷炉渣、泥磷和电除尘灰是主要的固体废弃物,多数企业处理含磷固废时常采用堆积放置的方法,这不仅产生污染,还造成资源极大的浪费。在“双碳”背景下,我国黄磷工业节能减排、绿色发展面临着新的、更大的挑战。本文综述了现阶段对于黄磷工业中产生的黄磷炉渣、泥磷和电除尘灰等固体废物资源化处置的技术和制磷生产中固废的处置现状,指出了未来资源化利用的发展方向,为实现黄磷行业的绿色生产、资源利用、节能减排提供参考。

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	王郎郎
	张韶
	费政富
	宁平
	王学谦
	刘敬业
	谢怡冰
	马懿星
	王华

关键词: 黄磷炉渣泥磷电除尘灰废物处理资源化利用

Abstract: Yellow phosphorus is an important pillar of China's national economy and belongs to national strategic resources too. With the rapid development of China's phosphorus chemical industry, the production capacity of yellow phosphorus ranks first in the world.The production scale of yellow phosphorus in China is very huge, but the competitiveness of production technology is not strong and the utilization rate of phosphorus resources is very low. During the production process, the components of phosphorus by-products are complex and the production volume is large. Among them, yellow phosphorus slag, phosphorus sludge and electrostatic precipitator ash are the main solid wastes. Most enterprises often use the stacking method to treat phosphorus-containing solid wastes, which not only produces pollution but also causes great waste of resources. In the context of "dual carbon", China's yellow phosphorus industry faces new and greater challenges in energy conservation, emission reduction and green development. Here summarizes the current technologies for the resource utilization and disposal of solid wastes such as yellow phosphorus slag, phosphorus sludge and electrostatic precipitator ash generated in the yellow phosphorus industry, as well as the current status of solid waste treatment and disposal in phosphorus production, then points out the future direction of resource utilization of these wastes. It provides a reference for realizing the green production, resource utilization, energy conservation and emission reduction of the yellow phosphorus industry.

Key words: yellow phosphorus slag phosphorus sludge electrostatic precipitator ash waste treatment resource utilization

出版日期: 2024-11-25 发布日期: 2024-11-22

ZTFLH:

X75

基金资助: 国家自然科学基金(52100122;52070090;22266019);云南省科技计划项目(202101BC070001-009;202001AU070031;202101BE070001-030)

通讯作者: *宁平,昆明理工大学环境科学与工程学院教授。于1982年获得昆明工学院(现昆明理工大学)学士学位,同年起任教于昆明工学院;1987年获得昆明工学院硕士学位;1995年获得德国凯泽斯劳滕大学化工系博士学位;1996年在德国凯泽斯劳滕大学从事博士后研究工作;1998年3月—2012年8月任昆明理工大学环境科学与工程学院院长;2022当选为俄罗斯工程院外籍院士。国家万人计划入选者、国家百千万人才、全国先进科技工作者、云南省科技领军人才,开展废气净化及资源化利用研究35年,先后任国家教育部环境工程教学指导分委员会副主任委员、中国环境科学学会理事、中国化学会理事等,现任冶金及化工行业废气资源化国家地方联合工程研究中心主任。主持国家863计划、国家支撑计划、国家自然科学基金重点等项目22项;以第一作者或通信作者发表SCI、EI学术论文165篇;出版专著、教材29部;第一发明人获授权发明专利56项;获国家技术发明二等奖1项,省部级科技成果一等奖5项、二等奖3项;获国家教学成果一等奖、二等奖各1项。ningping_58@163.com

作者简介: 王郎郎,昆明理工大学环境科学与工程学院副教授,云南省兴滇英才支持计划“青年人才”。2011年于河北科技大学取得学士学位,2017年于昆明理工大学环境工程专业博士毕业后留校工作至今。目前主要从事工业废气净化及资源化利用、高炉煤气脱硫等方面的研究工作。主持国家自然科学基金-青年基金1项,国家自然科学基金-地区基金1项,国家重点研发计划子课题1项,云南省科技计划项目3项;作为主要参与人完成了十二五国家863计划课题1项,十三五国家重点研发计划课题2项;发表学术论文20余篇,其中SCI论文10余篇;申请发明专利20余项,获授权专利9项,其中美国发明专利2项;获省部级一等奖3项,二等奖1项。

引用本文:

王郎郎, 张韶, 费政富, 宁平, 王学谦, 刘敬业, 谢怡冰, 马懿星, 王华. 黄磷生产中固废处置与资源化利用研究进展[J]. 材料导报, 2024, 38(22): 23080072-8.
WANG Langlang, ZHANG Shao, FEI Zhengfu, NING Ping, WANG Xueqian, LIU Jingye, XIE Yibing, MA Yixing, WANG Hua. Research Progress of Solid Waste Disposal and Resource Utilization in Yellow Phosphorus Production. Materials Reports, 2024, 38(22): 23080072-8.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.23080072 或 http://www.mater-rep.com/CN/Y2024/V38/I22/23080072

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