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材料导报  2024, Vol. 38 Issue (11): 22060235-7    https://doi.org/10.11896/cldb.22060235
  高分子与聚合物基复合材料 |
不同SiC/ZnO含量对光敏树脂固化特性及力学性能的影响
宗学文1,*, 刘亮晶1,2, 田航1,3, 王涛1, 韦毅博1,2
1 西安科技大学机械工程学院,西安 710054
2 比亚迪汽车有限公司,西安 710075
3 隆基绿能科技股份有限公司,西安 710100
Effect of Different SiC/ZnO Contents on the Curing Characteristics and Mechanical Properties of Photosensitive Resin
ZONG Xuewen1,*, LIU Liangjing1,2, TIAN Hang1,3, WANG Tao1, WEI Yibo1,2
1 School of Mechanical Engineering, Xi'an University of Science and Technology, Xi'an 710054, China
2 BYD Automobile Co., Ltd., Xi'an 710075, China
3 Longji Green Energy Technology Co., Ltd., Xi'an 710100, China
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摘要 为评价无机微米、纳米及微-纳米粒子协同改性对光敏树脂的粘度、固化收缩特性及力学性能的影响,利用LCD光固化3D打印技术制备不同质量比的微-纳米SiC/ZnO改性光敏树脂。结果表明:在纳米ZnO和微米SiC填料的共同掺杂下,树脂的粘度随着填料质量比的增加而逐渐降低,能有效提高打印中的铺平能力;在相同的曝光能量下,结合Beer-Lambert光固化方程发现,与纳米ZnO/树脂体系相比,微-纳米SiC/ZnO/光敏树脂具有更高的固化深度,利于成形。当微米SiC与纳米ZnO的质量比为0.5∶2时,光敏树脂的固化收缩率、邵氏硬度、抗拉强度及断裂伸长率均达到最优,分别为0.39%、96.2、21.9 MPa和4.89%。本工作通过LCD光固化3D打印实现了微-纳米SiC/ZnO/树脂体系的制备,为未来微-纳协同改性光敏树脂制件的成型提供了一定的参考。
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宗学文
刘亮晶
田航
王涛
韦毅博
关键词:  光固化3D打印  微纳协同  复合材料  固化特性    
Abstract: To evaluate the effects of inorganic micron, nano and micro-nano particles synergistic modification on the viscosity, curing shrinkage characteristics and mechanical properties of photosensitive resin, micro-nano SiC/ZnO modified photosensitive resins with different mass ratios were prepared by LCD light-curing 3D printing technology. The results show that: under the co-doping of nano-ZnO and micron SiC fillers, the viscosity of the resin gradually decreases as the mass ratio of SiC fillers increases, which can effectively improve the spreading ability in printing; at the same exposure energy, combined with Beer-Lambert model equation, it is found that compared with the nano-ZnO/resin system, the micro-nano SiC/ZnO/photosensitive resin has higher curing depth, which facilitates forming. When the mass ratio of micron-SiC to nano-ZnO is 0.5∶2, the curing shrinkage, shore hardness, tensile strength and elongation at break of the photosensitive reach the optimal effect, which are 0.39%, 96.2, 21.9 MPa and 4.89% respectively. In this work, micro-nano SiC/ZnO/resin system were prepared by LCD light-curing 3D prin-ting, which provides a certain reference for the forming of micro-nano synergistic modified photosensitive resin fabrications in the future.
Key words:  UV-curing 3D printing    micro-nano synergy    composite    curing characteristics
发布日期:  2024-06-25
ZTFLH:  TB332  
基金资助: 陕西省秦创原“科学家+工程师”队伍建设(2022KXJ-012); 国家自然科学基金(51875452)
通讯作者:  *宗学文,博士,西安科技大学增材制造研究所所长、博士研究生导师。2008年西安交通大学快速制造技术研究方向博士毕业。主持国家重大专项子课题、国家自然科学基金、省重点研发、省地市人才等项目11项,开展高分子、陶瓷、金属复杂形体的增材制造关键技术、工艺装备与关键科学问题研究,成果应用于航空、航天、汽车、电子型产品的快速开发制造。完成特种玻璃、国家快速制造工程中心中试线建设项目。出版著作4部,发表中外期刊论文60多篇,获批专利30多项。目前主要从事光固化3D打印技术、金属增材制造技术、快速铸造技术等方面的教学科研及推广应用工作。zongw007@xust.edu.cn   
引用本文:    
宗学文, 刘亮晶, 田航, 王涛, 韦毅博. 不同SiC/ZnO含量对光敏树脂固化特性及力学性能的影响[J]. 材料导报, 2024, 38(11): 22060235-7.
ZONG Xuewen, LIU Liangjing, TIAN Hang, WANG Tao, WEI Yibo. Effect of Different SiC/ZnO Contents on the Curing Characteristics and Mechanical Properties of Photosensitive Resin. Materials Reports, 2024, 38(11): 22060235-7.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22060235  或          http://www.mater-rep.com/CN/Y2024/V38/I11/22060235
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