缓凝剂对碱激发胶凝材料凝结时间及流变性能影响的研究进展

doi:10.11896/cldb.23070036

材料导报

2024, Vol. 38

Issue (19): 23070036-9 https://doi.org/10.11896/cldb.23070036

无机非金属及其复合材料

缓凝剂对碱激发胶凝材料凝结时间及流变性能影响的研究进展

仲小凡¹, 王爱国^1,*, 于乐乐¹, 刘开伟¹, 张祖华², 徐志杰¹, 孙道胜¹

1 安徽建筑大学安徽省先进建筑材料重点实验室,合肥 230022
2 同济大学材料科学与工程学院,上海 201804

Research Progress on the Influence of Retarders on the Setting Time and Rheological Properties of Alkali-Activated Cementitious Materials

ZHONG Xiaofan¹, WANG Aiguo^1,*, YU Lele¹, LIU Kaiwei¹, ZHANG Zuhua², XU Zhijie¹, SUN Daosheng¹

1 Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei 230022, China
2 School of Materials Science and Engineering, Tongji University, Shanghai 201804, China

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摘要碱激发胶凝材料具有制备能耗低、高强和耐久性好等特点,因其利废、节能、减碳而受到全球科技界和工业界的高度重视。但碱激发胶凝材料所用原材料来源广泛,品质波动较大,导致碱激发胶凝材料的性能变化差异较为明显,稳定性控制难度较高。其中对凝结时间的调控是当下亟待解决的问题,掺入缓凝剂是调控碱激发胶凝材料凝结时间的有效途径之一。本文总结了缓凝剂对碱激发胶凝材料凝结硬化及流变性能的影响,阐明了不同类型缓凝剂对碱激发胶凝材料的调凝机理(包覆、增黏和中和),并分析了其推广应用的可行性,以期为突破碱激发胶凝材料大规模工程应用的技术瓶颈提供理论基础和技术支持。

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关键词: 碱激发胶凝材料缓凝剂凝结时间流变性能调凝机理

Abstract: Alkali-activated cementitious materials are characterised by low energy consumption, high strength and good durability, and are highly valued by the global scientific and industrial community for its utilization of waste production, energy saving and carbon reduction. However, due to the wide range of raw materials used in alkali-activated cementitious materials, the quality fluctuates, resulting in more obvious variations in the performance of alkali-activated cementitious materials and the difficulty of controlling their stability, of which the regulation of the setting time is a pressing problem. The incorporation of retarders is one of the effective ways to regulate the setting time of alkali-activated cementitious materials. This paper summarises the influence of retarders on the setting and hardening and rheological properties of alkali-activated cementitious materials, clarifies the mechanism of different types of retarders on the setting of alkali-activated cementitious materials (coating, viscosity enhancement and neutralisation) and analyses the feasibility of their application, with a view to providing a theoretical basis and technical support for breaking through the technical bottleneck of large-scale engineering applications of alkali-activated cementitious materials.

Key words: alkali-activated cementitious materials retarders setting time rheological property mechanism of adjusting setting time

出版日期: 2024-10-10 发布日期: 2024-10-23

ZTFLH:

TU528

基金资助: 国家自然科学基金(52278236;52172013); 安徽省高校科研创新优秀团队(2022AH010017)

通讯作者: ^*王爱国,通信作者,安徽建筑大学教授、博士研究生导师。2010年毕业于南京工业大学,获材料学博士学位。2017年于澳大利亚University of Southern Queensland作访问学者。主要研究方向为高性能水泥基材料/建筑功能材料/固体废弃物综合利用。主持国家自然科学基金项目、安徽省重点研究与开发计划等省部级以上项目10余项。发表SCI、EI收录论文100余篇,获国家授权发明专利6项。任中国建筑学会建筑材料分会理事。wag3134@126.com

作者简介: 仲小凡,2024年6月毕业于安徽建筑大学,获得硕士学位。研究方向为高性能水泥基材料、海工混凝土。

引用本文:

仲小凡, 王爱国, 于乐乐, 刘开伟, 张祖华, 徐志杰, 孙道胜. 缓凝剂对碱激发胶凝材料凝结时间及流变性能影响的研究进展[J]. 材料导报, 2024, 38(19): 23070036-9.
ZHONG Xiaofan, WANG Aiguo, YU Lele, LIU Kaiwei, ZHANG Zuhua, XU Zhijie, SUN Daosheng. Research Progress on the Influence of Retarders on the Setting Time and Rheological Properties of Alkali-Activated Cementitious Materials. Materials Reports, 2024, 38(19): 23070036-9.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.23070036 或 http://www.mater-rep.com/CN/Y2024/V38/I19/23070036

1 Farhan K Z,Johari M,Demirboga R.Construction and Building Materials,2020,264,120276.
2 Singh N B,Middendorf B.Construction and Building Materials,2020,237(10),117455.
3 Peng J X,Huang L,Zhao Y B,et al.Advance Materials Research,2013,610-613,2120.
4 Habert G,Lacaillerie J,Roussel N.Journal of Cleaner Production,2011,19,1229.
5 Mclellan B C,Williams R P,Lay J,et al.Journal of Cleaner Production,2011,19,1080.
6 Wang A G,Wang X Y,Sun D S,et al.Materials Reports,2021,35(13),5 (in Chinese).
王爱国,王星尧,孙道胜,等.材料导报,2021,35(13),5.
7 Noushini A,Aslani F,Castel A,et al.Cement and Concrete Composites,2016,73,136.
8 Zhang P,Zheng Y X,Wang K J,et al.Composites Part B: Engineering,2018,152,79.
9 Wang A G,Zheng Y,Zhang Z H,et al.Engineering,2020,6(6),695.
10 Zhang D W,Wang D M.Materials Reports,2018,32(5),1519 (in Chinese).
张大旺,王栋民.材料导报,2018,32(5),1519.
11 Kaja A M,Lazaro A,Yu Q L.Construction and Building Materials,2018,189,1113.
12 Zunino F,Bentz D P,Castro J.Cement and Concrete Composites,2018,90,14.
13 Jiang D D,Shi C J,Zhang Z H,et al.Cement and Concrete Composites,2022,134,104795.
14 Wang A G,Zheng Y,Zhang Z H,et al.Materials Reports,2019,33(8),2552 (in Chinese).
王爱国,郑毅,张祖华,等.材料导报,2019,33(8),2552.
15 Zhu Y C,Zhang Z H,Liu Y,et al.Bulletin of the Chinese Ceramic Society,2020,39(8),2458 (in Chinese).
朱颖灿,张祖华,刘意,等.硅酸盐通报,2020,39(8),2458.
16 Si R Z,Guo S C,Dai Q L.Journal of the American Ceramic Society,2019,102(3),1479.
17 Gebregziabiher B S,Thomas R,Peethamparan S.Cement and Concrete Composites,2014,55,91.
18 Sun B,Ye G,Schutter G D.Construction and Building Materials,2022,326,126843.
19 Li N,Shi C,Zhang Z.Composites Part B: Engineering,2019,171,34.
20 Tl A,Hs A,Za A,et al.Construction and Building Materials,2020,233,117354.
21 Kumarappa D B,Peethamparan S,Ngami M.Cement and Concrete Research,2018,109,1.
22 Duxson P, Fernández-Jiménez A,Provis J L,et al.Journal of Materials Science and Technology,2007,42,2917.
23 Fernández-Jiménez A,Palomo A,Criado M.Cement and Concrete Research,2005,35(6),1204.
24 Shi C, Fernández-Jiménez A,Palomo A.Cement and Concrete Research,2011,41(7),750.
25 Rees C A,Provis J L,Lukey G C,et al.Colloids and Surfaces A,Physicochemical and Engineering Aspects,2008,318(1-3),97.
26 Chang J J.Cement and Concrete Research,2003,33(7),1005.
27 Tailby J,Mackenzie K.Cement and Concrete Research,2010,40(5),787.
28 Liu X,Li S Y,Ding Y C,et al.Journal of Building Engineering,2023,64,105694.
29 Zhang P,Gao Z,Wang J,et al.Journal of Cleaner Production,2020,270,122389.
30 Alonso M M,Gismera S, Blanco M T,et al.Construction and Building Materials,2017,145,576.
31 Brough A R,Holloway M,Sykes J,et al.Cement and Concrete Research,2000,30(9),1375.
32 Li Z X,Tang J W.Advanced Materials Research,2012,534,34.
33 Sugiarto A,Satria J,Wijaya S W.Materials Science Forum,2016,857,416.
34 Oderji S Y,Chen B,Shakya C,etal.Construction and Building Materials,2019,229,116891.
35 Fan S D,Li Y X,Wang S J,et al.Concrete, 2014(10),81 (in Chinese).
樊晓丹,李玉祥,王少剑,等.混凝土,2014(10),81.
36 Xie J H,Li L M,Huang J J,et al.Journal of Architecture and Civil Engineering,DOI: http:∥kns.cnki.net/kcms/detail/61.1442.TU.20220309.1352.002.html (in Chinese).
谢建和,李丽明,黄俊健,等.建筑科学与工程学报,DOI: http:∥kns.cnki.net/kcms/detail/61.1442.TU.20220309.1352.002.html.
37 LEE N K,LEE H K.Construction and Building Materials,2013,47,1201.
38 Kalina L,Vlastimil B,Radoslav N,et al.Materials,2016,9(5),395.
39 Kusbiantoro A,Ibrahim M S,Muthusamy K,et al.Procedia Environmental Sciences,2013,17,596.
40 Assi L N,Deaver E,Ziehl P.Construction and Building Materials,2018,191(10),47.
41 Najimi M,Ghafoori N,Sharbaf M.Magazine of Concrete Research,2020,72(18),919.
42 Chen W,Jin L,Fan J F,et al.Bulletin of The Chinese Ceramic Society, 2016,35(6),1682 (in Chinese).
陈伟,金浪,范剑锋,等.硅酸盐通报,2016,35(6),1682.
43 Yu Q J,Zhao S Y,Huang J Q,et al.Journal of the Chinese Ceramic Society,2005,33(7),871 (in Chinese).
余其俊,赵三银,黄家琪,等.硅酸盐学报,2005,33(7),871.
44 Nedunuri A,Muhammad S.Construction and Building Materials,2022,344,128128.
45 Dupuy C,Havette J,Gharzouni A,et al.Construction and Building Materials,2019,200(10),272.
46 Zhang W L,Yang C H,Yang K,et al.Journal of Building Materials,2016,19(5),803 (in Chinese).
张武龙,杨长辉,杨凯,等.建筑材料学报,2016,19(5),803.
47 Sinha A K,Talukdar S.Construction and Building Materials,2021,313,125380.
48 Rakhimova N R,Rakhimov R Z,Morozov V P,et al.Journal of Cleaner Production,2017,149,60.
49 Zhang L,Ji Y,Li J,et al.Construction and Building Materials,2019,212(10),192.
50 Sasaki K,Kurumisawa K,Ibayashi K.Construction and Building Materials,2019,216(20),337.
51 Sun J W D.Journal of Thermal Analysis and Calorimetry,2021,144(1),41.
52 Karthik A,Sudalaimani K,Kumar C.Construction and Building Materials,2017,149,338.
53 Ismail E H.Journal of Sustainable Cement-Based Materials,2017,7,1.
54 JangJ G,Lee N K.Construction and Building Materials,2014,50,169.
55 Lu C F,Zhang Z H,Shi C J,et al.Cement and Concrete Composites,2021,121(1),104061.
56 Yuan Q,Huang Y L,Huang T J,et al.Journal of Central South University,2022,29(1),282.
57 Dai X,Aydin S,Yardimci M Y,et al.Cement and Concrete Research,2022,159,106872.
58 Thirunavukarasu R. Construction and Building Materials,2020,267,120965.
59 Luukkonen T,Abdollahnejad Z,Ohenoja K,et al.Journal of Sustainable Cement-Based Materials,2019,(8),244.
60 Ren J,Zhou Q Z,Yang C H,et al.Cement and Concrete Composites,2023,136,104900.
61 Wang X Y,Wang A G,Zhang Z H,et al.Composites Part B: Engineering,2023,252,110519.
62 Cong X,Zhou W,Geng X,et al.Cement and Concrete Composites,2019,104,103399.
63 Habbaba A,Plank J.Journal of the American Ceramic Society,2012,95(2),768.
64 Lei H K.Cement and Concrete Research,2020,136(1),106150.
65 Thushara Raju,K.P.Ramaswamy,B.Saraswathy.Materials Today,Proceedings,2022,62,846.
66 Weckwerth S A,Temme R L,Flatt R J.Cement and Concrete Research,2022,151,106523.
67 Zhang J Y,Ye H,Gao X J,et al.Journal of Materials Research and Technology,2022,17,1740.
68 Chen X,Mondal P.Journal of the American Ceramic Society,2021,104,2894.
69 Park S,Pour-Ghaz M.Construction and Building Materials,2018,182(10),360.
70 Zhang Z Q,Zhou D L,Li F G,et al.Concrete, 2008(8),63 (in Chinese).
张志强,周栋梁,李付刚,等.混凝土,2008(8),63.

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