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材料导报  2024, Vol. 38 Issue (14): 23050050-7    https://doi.org/10.11896/cldb.23050050
  无机非金属及其复合材料 |
洁净金属冶炼用CaO材料的防水化措施及作用机理
顾强1,2, 马渭奎1,2, 钱凡1,2, 刘国齐1,2,*, 李红霞1,2,*
1 中钢集团洛阳耐火材料研究院有限公司, 先进耐火材料国家重点实验室,河南 洛阳 471039
2 有色金属新材料与先进加工技术省部共建协同创新中心,河南 洛阳 471023
Anti-hydration Measures and Mechanism of CaO Material for Clean Metal Smelting
GU Qiang1,2, MA Weikui1,2, QIAN Fan1,2, LIU Guoqi1,2,*, LI Hongxia1,2,*
1 State Key Laboratory of Advanced Refractories, Sinosteel Luoyang Institute of Refractories Research Co., Ltd., Luoyang 471039, Henan, China
2 Provincial and Ministerial Co-construction of Collaborative Innovation Center for Non-ferrous Metal New Materials and Advanced Processing Technology, Luoyang 471023, Henan, China
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摘要 CaO是冶炼洁净金属最具潜力的耐火材料,其运用可推动我国高端制造业的高质量发展,然而易水化是其推广应用的主要限制性因素。本文综述了提高CaO材料水化性能的措施,包括高温煅烧法、添加剂法和表面处理法等,并对其作用机理进行分析和作用效果进行评价,最后指出,采用多方式协同将成为提高CaO抗水化性的重要方向,以及从晶体结构入手才能从根本上解决CaO易水化问题。
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顾强
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钱凡
刘国齐
李红霞
关键词:  CaO  水化  高温烧结  添加剂  表面包覆    
Abstract: CaO is the most promising refractories for clean metal smelting. Its application can promote the high-quality development of China's high-end manufacturing industry. However, easy hydration is the main limiting factor for its application. This article reviews the measures to improve the hydration properties of CaO materials, including high temperature calcination method, additive method, and surface treatment method, and analyzes their mechanism and evaluates their effect. Finally, it is pointed out that the use of multi-method synergy would become an important direction to improve the hydration resistance of CaO, and starting from the crystal structure can fundamentally solve the problem of easy hydration of CaO.
Key words:  CaO    hydration    high temperature sintering    additives    surface coating
出版日期:  2024-07-25      发布日期:  2024-08-12
ZTFLH:  TQ175  
基金资助: 国家自然科学基金(51932008);中原科技创新领军人才(204200510011)
通讯作者:  * 刘国齐,工学博士,中钢集团洛阳耐火材料研究院高级技术专家、正高级工程师、硕士研究生导师。1997年河北理工学院无机非金属专业本科毕业,2000年洛阳耐火材料研究院无机非金属材料专业硕士毕业后在该院工作至今,2006年北京科技大学材料学专业博士毕业,目前主要从事功能耐火材料等方面的研究。主持或参与了多项省部级以上科研课题的研究开发工作,获国家技术发明二等奖(排名第3)1项,在Ceramic International、Journal of Alloy and Compounds、《耐火材料》等期刊上发表学术论文100余篇,授权发明专利18件,主持修订《连铸用功能耐火制品》标准,获国务院政府特殊津贴。liugq@lirrc.com
李红霞,工学博士,正高级工程师,博士研究生导师,中国宝武首席科学家、先进耐火材料国家重点实验室主任、中国金属学会常务理事、全国耐火材料标准化委员会主任委员、“新世纪百千万人才工程”国家级人选等。1987年和1990年在天津大学分别获技术陶瓷专业学士学位和无机非金属材料专业硕士学位,1994年在中国科学院上海硅酸盐研究所无机非金属材料专业获博士学位,期间在美国密西根大学学习。长期围绕冶金产品高端化和绿色制造新技术开展先进耐火材料研究,主持国家级项目21项,获国家技术发明二等奖1项(排名第1)、省部科技进步一等奖5项(三项排名第1),制定国际标准2项,授权发明专利60件,发表论文321篇,出版专著6部,多次编制行业发展规划和技术路线图等。lihongx0622@126.com   
作者简介:  顾强,工学博士,中钢集团洛阳耐火材料研究院有限公司工程师。2015年7月于华北水利水电大学获得工学学士学位,2018年7月于郑州大学获得工学硕士学位,2022年12月于郑州大学获得工学博士学位。目前主要从事功能耐火材料等方面的研究。在Ceramic International、Journal of Alloy and Compounds、ISIJ International、《材料导报》《硅酸盐学报》等期刊发表论文20余篇,授权专利1件。
引用本文:    
顾强, 马渭奎, 钱凡, 刘国齐, 李红霞. 洁净金属冶炼用CaO材料的防水化措施及作用机理[J]. 材料导报, 2024, 38(14): 23050050-7.
GU Qiang, MA Weikui, QIAN Fan, LIU Guoqi, LI Hongxia. Anti-hydration Measures and Mechanism of CaO Material for Clean Metal Smelting. Materials Reports, 2024, 38(14): 23050050-7.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.23050050  或          http://www.mater-rep.com/CN/Y2024/V38/I14/23050050
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