Research Progress on Corrosion Behavior of Reactor Plant Materials in Supercritical Water Oxidation Environment of Hazardous Waste Treatment
CHEN Siyu1, ZHANG Xian1,*, LI Teng2,*, LIU Jing1, WU Kaiming1
1 State Key Laboratory of Refractories and Metallurgy, Collaborative Innovation Center for Advanced Steels, Hubei Province Key Laboratory of Systems Science in Metallurgical Process, Wuhan University of Science and Technology, Wuhan 430081, China 2 Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, China
Abstract: Supercritical water oxidation technology for waste treatment has the characteristics of high removal efficiency, short residence time and no pollutant and by-products, but because of its harsh reaction conditions, corrosion problems of equipment urgently need to be solved. Especially when the reaction environment is acidic and the reaction materials contain halogen elements, the corrosion is extremely serious. At present, nickel base alloy, titanium alloy, stainless steel and other alloy materials are mainly used to manufacture reactors, but overall and local corrosion is still prone to occur, and may cause reactor leakage or even explosion in serious cases. Therefore, in recent years, researchers have carried out in-depth analysis on the corrosion behavior of different alloys in different types of supercritical water oxidation environment, and then put forward effective protection measures.In this paper, the corrosion behavior and mechanism of nickel base alloy and titanium alloy in acidic solution containing chloride ion, sulfuric acid solution and phosphoric acid solution, as well as stainless steel in acidic solution containing chloride ion and H2O2 solution under subcritical and supercritical conditions are summarized. The occurrence of overall corrosion, pitting corrosion, intergranular corrosion and stress corrosion cracking at different temperature zones and reactor locations are summarized. Corrosion protection measures such as liner and coating used in supercritical water oxidation (SCWO) environment of hazardous waste treatment are reviewed. Finally, the development prospect of improving corrosion resistance of superfine alloy materials by surface nanocrystalline technology is prospected.
1 Zhang L, Wang J Q, Guan H, et al. Corrosion Science and Protection Technology, 2001(5), 270 (in Chinese). 张丽, 王俭秋, 关辉, 等.腐蚀科学与防护技术, 2001(5), 270. 2 Zhang G W, Dong Z H. The Modern Chemical Industry, 2019, 39(1), 18 (in Chinese). 张光伟, 董振海.现代化工, 2019, 39(1), 18. 3 Zhang F, Li Y, Liang Z, et al. Biomass and Bioenergy, 2022, 156, 106322. 4 Li N, Liu C, Liu S N, et al. Energy Saving in Nonferrous Metallurgy, 2020, 36(6), 16 (in Chinese). 李诺, 刘诚, 刘苏宁, 等.有色冶金节能, 2020, 36(6), 16. 5 Hou C X, Ma P S. Chemical Industry and Engineering, 2003(6), 361 (in Chinese). 侯彩霞, 马沛生.化学工业与工程, 2003(6), 361. 6 Dai H, Huang W H, Qian X L, et al. Chemical Industry and Environmental Protection, 2001(2), 79 (in Chinese). 戴航, 黄卫红, 钱晓良, 等.化工环保, 2001(2), 79. 7 Zhao J X. Study on corrosion of hexanitrostilbene in wastewater production by supercritical water oxidation. Master’s Thesis, University of North, 2011 (in Chinese). 赵军霞. 超临界水氧化六硝基茋生产废水设备材料的腐蚀研究. 硕士学位论文, 中北大学, 2011. 8 Mitton D B, et al. ACS Symposium Series 670, 1997, 6, 242 9 Mitton D B, Han E H, Zhang S H, et al.In: ACS Symposium Series 665, Supercritical Fluid, Washington, DC, 1996, pp.242. 10 Mitton D B, Zhang S H, Hautanen K E, et al. Corrosion, 1997, 203, 66. 11 Han E H, Mitton D B, Zhang S H, et al. New progress in corrosion science and anti-corrosion engineering technology, Chemical Industry Press, China, 1996, pp.161 (in Chinese). 韩恩厚, Mitton D B, Zhang S H, et al.腐蚀科学与防腐蚀工程技术新进展, 化学工业出版社, 1996, pp.161. 12 Zilberstein V A. Corrosion, 1995, 24, 558. 13 Kritzer P, Boukis N, Dinjus E. Corrosion, 1998, 54(10), 824. 14 Boukis N. Corrosion, 1997, 10,159. 15 Boukis N, Friedrich C, Habicht W, et al. Eurocorrosion, 1997, 208, 617. 16 Kritzer P. The Journal of Supercritical Fluids, 2004, 29, 1. 17 Latanision R M, Shaw R W. Workshop Summary, 1993, 93, 6 18 Hong G, Ordway D W, Zilberstein V A, In: Proceedings of the 4th International Symposium on Supercritical Fluids. Sendai, Japan, 1997, pp. 865. 19 Kritzer P, Boukis N, Dinjus E. Corrosion, 1998, 54(10), 824. 20 Huang S, Daehling K, Carleson T E, et al. Supercritical Science and Technology, 1989, 406, 276. 21 Bramlette T T, Mills B E, Hencken K R, et al. US patent, US908229, 1991. 22 Okamoto G, Corrosion, 1973, 13, 471. 23 McBee C L, Kruger J. Electrochem,1972, 17, 1337. 24 Moffat T P, Lantanision R M. Electrochem, 1992, 139, 1869. 25 Lin L F, Gragnolino G, Smialowska Z S. Corrosion, 1981, 37, 616. 26 Gragnolino G, Lin L F, Smialowska Z S. Corrosion, 1981, 312(1), 71. 27 Kriksunov L B, Macdonald D D. Electrochem,1995, 142, 4069. 28 Mitton D B, Marrone P A, Latanision R M. Electrochem, 1996, 143, 59. 29 Mitton D B, Zhang S H, Hautanen K E, et al. Corrosion, 1997, 203, 66. 30 Fujii T, Kobayashi T. Corrosion, 1976, 37, 416. 31 Olmedo A M, Villegas M, Alvarez M G, et al. Mater, 1996, 229, 102. 32 Kritzer P, Boukis N, Dinjus E. Corrosion, 1998,54(9), 689. 33 Shibata T, Fujimoto S. Corrosion, 1990, 46, 793. 34 Joshi A, Stein D F. Corrosion, 1972, 28, 321. 35 Cowan R L, Tedmon C S. Advances in Corrosion Science and Technology, 1973, 293, 400. 36 Kriksunov L B, Macdonald D D. Electrochem, 1995, 142, 4069. 37 Wofford W T, Dell’Orco P C, Gloyna E F, et al. Electrochem, 1995, 40, 968. 38 Yashiro H, Oyama A, Tanno K. Corrosion, 1997, 53, 290. 39 Weber J, Sury P. Materials Peform, 1976, 15(2), 34. 40 Malinowski D D, Fletcher W D. Materials Peform, 1978, 37, 103. 41 Herro H M, Banweg,A. Materials Peform, 1995, 34(12), 49. 42 Kritzer P, Boukis N, Dinjus E. Materials and Corrosion, 1998, 49(11), 831. 43 Murray R C, Cobble J W, In: Water Chemistry of Nuclear Reactor Systems. Pittsburgh, 1980, pp. 295. 44 Ryzhenko B N, Bryzgalin O V. Geochem, 1987, 24, 122. 45 Mesmer R E, Herting D L, Solut J. 1978, 7, 901. 46 Haufe P, Solut J. Electrochem, 1985, 14, 73. 47 Atrens A, Baroux B, Mantel M. Electrochem, 1997, 144, 3697. 48 Bogaerts W F, Bettendorf C. Electric Power Research Institute Report, 1988, 2, 5863. 49 Armellini F J, Tester J W. Supercritical Fluids, 1991, 4, 254. 50 Ma C Y, Jiang A X, Peng Y L, et al. Journal of Yunnan University (Na-tural Science), 2006(S1), 274 (in Chinese). 马承愚, 姜安玺, 彭英利, 等. 云南大学学报(自然科学版), 2006(S1), 274. 51 Boukis N, Friedrich C, Dinjus E. Corrosion, 1998, 417, 7. 52 Frayret C, Botella P, Jaszay T, et al. Journal of the Electrochemical So-ciety, 2004, 151(10), 543. 53 Tang X, Wang S, Qian L, et al. Chemical Engineering Research and Design, 2015, 100, 530. 54 Zha L, Li H P, Wang N. Electrochem, 2019, 14, 4546. 55 Tang X, Wang S, Xu D, et al. Industrial & Engineering Chemistry Research, 2013, 52(51), 18241. 56 Li N. Effect of high temperature and high pressure water medium on corrosion properties of 304 stainless steel. Master’s Thesis, Tianjin University, China, 2012 (in Chinese). 李娜. 高温高压水介质对304不锈钢腐蚀性能的影响研究. 硕士学位论文, 天津大学, 2012. 57 Yoon J H, Son K S, Kim H S, et al. Materials Science Forum, 2005, 475, 4207. 58 Liu Q Y, Li H P, Zhou L,et al. Petrochemical Corrosion and Protection, 2006, 23(5), 1 (in Chinese). 刘庆友, 李和平, 周丽, 等.石油化工腐蚀与防护, 2006, 23(5), 1. 59 Cheng X Q, Li X G, Du C W. Journal of Metal, 2006, 42(3), 299 (in Chinese). 程学群, 李晓刚, 杜翠薇.金属学报, 2006, 42(3), 299. 60 Lin Z X. Experimental study on stress corrosion of 304 austenitic stainless steel in NaOH+Cl-+H2O complex medium. Master’s Thesis, Zhejiang University of Technology, China, 2017 (in Chinese). 林志祥. 304奥氏体不锈钢在NaOH+Cl-+H2O复杂介质环境下的应力腐蚀试验研究. 硕士学位论文, 浙江工业大学, 2017. 61 Ma Z, Xu D, Guo S, et al. Oxidation of Metals, 2018, 90(5), 599. 62 Guo S, Xu D, Ma Z, et al. Journal of Materials Engineering and Performance, 2020, 29(3), 1919. 63 Sun M, Wu X, Zhang Z, et al. Corrosion Science, 2009, 51(5), 1069. 64 Gao X, Wu X, Zhang Z, et al. The Journal of Supercritical Fluids, 2007, 42(1), 157. 65 Hayward T M, Svishchev I M, Makhija R C. The Journal of Supercritical Fluids, 2003, 27(3), 275. 66 Xu D H, Guo S W. Corrosion Characteristics, Mechanisms and Control Methods of Candidate Alloys in Sub-and Supercritical Water, Springer Nature, 2022, pp. 241. 67 Hazlebeck D A, Downey K W, Jensen D D, et al. Spritzer, Supercritical water oxidation of chemical agents, propellants, and other DOD hazardous wastes, in: H.G. White, J.V. Sengers, D.B. Neuman, J.C. Bellows (Eds.). Physical Chemistry of Aqueous Systems: Meeting the Needs of Industry. Begell House, New York, 1995, pp. 632. 68 Philip A M,Glenn T H. The Journal of Supercritical Fluids, 2009, 51(2). 69 Hong G T, Zilberstein V A. U.S. patent, US5527471, 1996. 70 Hong G T, Killilea W R, Ordway D W. U.S. patent, US5358645, 1994. 71 Hong G T. U.S. patent, US5545337, 1996. 72 Nauflett G W, Farncomb R E, Kumar M L. U.S. patent, US5461648, 1995. 73 Gui Y, Cheng Y, He C L. Science and Technology Information, 2021, 19(23), 1 (in Chinese). 桂艳, 程盈, 何炽灵. 科技资讯, 2021, 19(23), 1. 74 Duan B B, Wang Z G, Cai J, et al. Surface Technology, 2021, 50(12), 202 (in Chinese). 段冰冰, 王治国, 蔡晋, 等. 表面技术, 2021, 50(12), 202. 75 Zhang H C, He X M. Rare Metals, 2009, 33(6), 769 (in Chinese). 张聪惠, 何晓梅. 稀有金属, 2009, 33(6), 769. 76 Yang Y Q. Study on thermal corrosion resistance of Laser shot peening Nickel-based superalloy Inconel X-750. Master’s Thesis, Jiangsu University, China, 2017 (in Chinese). 杨颖秋. 激光喷丸强化镍基高温合金Inconel X-750抗热腐蚀性能研究. 硕士学位论文, 江苏大学, 2017. 77 Yang Y Q, Zhou J Z, Sheng J, et al. Journal of the Optical, 2017, 37(6), 160 (in Chinese). 杨颖秋, 周建忠, 盛杰, 等.光学学报, 2017, 37(6), 160. 78 Karthik D, Swaroop S. Journal of Alloys and Compounds, 2017, 694, 1309. 79 Pradhan D, Mahobia G S, Chattopadhyay K, et al. Journal of Materials Engineering and Performance, 2018, 27(8), 4235.
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2023, Vol. 37 
