多组元Ni/NiO/rGO纳米复合材料的制备及电化学储锂性能

doi:10.11896/cldb.21060194

材料导报

2022, Vol. 36

Issue (23): 21060194-8 https://doi.org/10.11896/cldb.21060194

无机非金属及其复合材料

多组元Ni/NiO/rGO纳米复合材料的制备及电化学储锂性能

杨文飞¹, 张钟元¹, 张雪¹, 王轶农¹, 郭显娥², 董星龙^1,*

1 大连理工大学材料科学与工程学院,三束材料改性教育部重点实验室,辽宁大连 116024
2 山西大同大学计算机与网络工程学院,山西大同 037009

Synthesis and Electrochemical Lithium Storage Properties of Multicomponent Ni/NiO/rGO Nanocomposites

YANG Wenfei¹, ZHANG Zhongyuan¹, ZHANG Xue¹, WANG Yinong¹, GUO Xian'e², DONG Xinglong^1,*

1 Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China
2 School of Computer and Network Engineering, Shanxi Datong University, Datong 037009, Shanxi, China

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摘要 NiO由于理论容量高(718 mAh·g^-1)、密度大、安全无污染,被认为是极具潜力的锂离子电池负极材料。然而,低电导率和固有体积膨胀限制了其在储能领域的应用。针对以上问题,本工作使用直流电弧等离子体法制备了Ni纳米粒子,在空气中氧化烧结后获得一维链状Ni/NiO纳米复合材料,将其与还原氧化石墨烯(Reduction graphene oxide, rGO)在无水乙醇溶液中均匀混合,并使用喷雾干燥及焙烧工艺获得了Ni/NiO/rGO纳米复合材料(Nanocomposites, NCs)。一维Ni/NiO纳米链被均匀地担载到二维石墨烯片层结构上,其中Ni、NiO和rGO组元含量分别为2.15%、87.83%和10.02%(质量分数)。Ni/NiO纳米链的一维状结构可有效缓解NiO活性组分在电化学循环过程中的体积膨胀,均匀分布的金属Ni粒子和石墨烯基体为电子输运提供了有利条件,从而提高了Ni/NiO/rGO NCs的电导率。此复合材料电极在0.1 A·g^-1电流密度下循环100次后容量保持在1 016.8 mAh·g^-1,表现出优异的电化学循环稳定性能和倍率性能。NiO基纳米材料的结构调控和性能优化为锂离子电池负极材料的多样性提供了可能。

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	杨文飞
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	王轶农
	郭显娥
	董星龙

关键词: 氧化镍还原氧化石墨烯直流电弧等离子体喷雾干燥锂离子电池负极材料

Abstract: Nickel oxide is considered as a potential anode material for lithium-ion batteries (LIBs) due to the merits, such as high theoretical capacity (718 mAh·g^-1), high density, good safety and environmental friendly. Unfortunately, the application in the field of energy storage is dramatically limited due to its low electrical conductivity and inherent volume variation. In response to the above problems, nickel nanoparticles were prepared by DC(Direct Current) arc discharge plasma method, those were further oxidized and sintered in air to obtain one-dimensional (1D) Ni/NiO nanochains. The as-prepared Ni/NiO nanochains were then uniformly mixed with graphene oxide (GO) in ethanol solution to synthesize Ni/NiO/rGO nanocomposites (NCs) through a spray drying and calcining process. 1D Ni/NiO nanochains are uniformly loaded onto the 2D rGO sheets, the mass fractions of Ni, NiO and rGO phases are of 2.15%, 87.83% and 10.02%, respectively. The 1D structure of Ni/NiO nanochains can effectively alleviate the volume expansion of active NiO phase during cycling. Meanwhile, the metallic Ni nanoparticles and rGO provide favorable conditions for electron transport, thus raising electrical conductivity of the Ni/NiO/rGO NCs. The Ni/NiO/rGO NCs electrode delivers a superior capacity of 1 016.8 mAh·g^-1 at a current density of 100 mA·g^-1 after 100 cycles. The reconstruction in structure and the performance optimization of NiO-based nanomaterial provide the possibility for the diversity of anode materials for LIBs.

Key words: NiO reduction graphene oxide direct current arc plasma spray drying lithium-ion battery anode material

发布日期: 2022-12-09

ZTFLH:

TB333

基金资助: 国家自然科学基金联合重点项目(U1908220)

通讯作者: ^*dongxl@dlut.edu.cn

作者简介: 杨文飞,2016年6月毕业于贵州师范大学材料科学与工程专业,获得工学学士学位。现为大连理工大学硕博连读研究生,研究方向为直流电弧等离子体下纳米复合材料的制备及电化学性能。
董星龙,大连理工大学教授、博士研究生导师,教育部“新世纪优秀人才”。1997年获得中国科学院金属研究所博士学位,韩国材料研究所(KIMS)访问学者(1998—2001年),美国华盛顿大学材料系访问学者(2002—2009年)。在国内外学术刊物发表论文150余篇,专/译著3部,申请国家发明专利20余项,承担973、国家自然科学基金、省部级、企业项目30余项。其团队主要研究方向包括:纳米粉体材料制备技术与工程化应用、核/壳型纳米复合电磁功能材料、锂离子电池纳米复合负极材料、金属单原子催化剂、电子浆料及微电子核心器件等。

引用本文:

杨文飞, 张钟元, 张雪, 王轶农, 郭显娥, 董星龙. 多组元Ni/NiO/rGO纳米复合材料的制备及电化学储锂性能[J]. 材料导报, 2022, 36(23): 21060194-8.
YANG Wenfei, ZHANG Zhongyuan, ZHANG Xue, WANG Yinong, GUO Xian'e, DONG Xinglong. Synthesis and Electrochemical Lithium Storage Properties of Multicomponent Ni/NiO/rGO Nanocomposites. Materials Reports, 2022, 36(23): 21060194-8.

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http://www.mater-rep.com/CN/10.11896/cldb.21060194 或 http://www.mater-rep.com/CN/Y2022/V36/I23/21060194

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