Abstract: The scandium oxide with layered structure prepared by hydroxide precipitation and roasting was studied in this paper. The effects of reaction temperature, precipitation, stirring rate and aging time on the recovery efficiency of scandium precipitation were studied. It was concluded that the main crystal phase of scandium sediment was ScOOH by XRD and FTIR analysis. Based on the scandium ion content value in scandium sediment, which was measured by inductively coupled plasma spectrometer (ICP-OES). The recovery percentages of scandium in the precipitation reaction were calculated. The results indicated that the recovery percentage of scandium precipitation was up to 97%, when the sodium hydroxide precipitant dosage, reaction temperature, stirring rate and aging time were 27.5 g/L, 60 ℃, 200 r/min and 2 h, respectively. The scan-dium oxide powder was obtained by roasting scandium hydroxide. The scandium oxide powder material was characterized by XRD, SEM-EDS, and FTIR. The scandium oxide had good crystal structure and was relatively pure, which consisted of scandium and oxygen elements. Meanwhile, according to the test of microstructure, the scandium oxide powder material was a layer structure of micron scale and the particles less than 20 μm.
付国燕, 王玮玮, 刘召波, 吕东, 姚心. 氢氧化物沉淀法制备层状结构氧化钪的研究[J]. 材料导报, 2020, 34(Z2): 164-167.
FU Guoyan, WANG Weiwei, LIU Zhaobo, LYU Dong, YAO Xin. Research on the Preparation of Layered Scandium Oxide by Hydroxide Precipitation. Materials Reports, 2020, 34(Z2): 164-167.