Abstract: Different from traditional ball milling, solid-state shear pan-milling is an innovative approach that enables the synthesis of functional micro- and nano-composites. When graphite and nanometer scale Fe3O4 are applied as the raw material and melamine as the nitrogen doping agent, a composite of Fe3O4 and N-doped graphene (Fe3O4/N-G) could be successfully synthesized by employing the solid-state shearing pan-milling method. After characterization by X-ray diffraction (XRD), Raman spectroscopy (RM), transmission electronic microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Brunauer, Emmett and Teller analysis (BET) and electrochemical measurements, it is found that graphite could be exfoliated into few-layered graphene while simultaneously doped by nitrogen and composited with Fe3O4 uniformly. When applied as an anode for lithium ion battery, an excellent cycling stability with a reversible capacity of 869 mAh·g-1 after 100 cycles at 100 mA·g-1 is delivered, which is far superior to pristine Fe3O4 with only 78 mAh·g-1 retained. The technique provides a green, and facile method for the preparation of graphene based composite electrode materials.
王青福, 刘新刚, 康文彬, 张楚虹. 固相剪切磨盘碾磨法制备四氧化三铁/氮掺杂石墨烯复合材料及其在锂离子电池中的应用[J]. 材料导报, 2018, 32(21): 3689-3696.
WANG Qingfu, LIU Xingang, KANG Wenbin, ZHANG Chuhong. Preparation of Fe3O4/Nitrogen-doped Graphene Composite via Solid-state Shear Pan-milling Method and Its Application in Lithium Ion Battery. Materials Reports, 2018, 32(21): 3689-3696.
1 Tarascon J M, Armand M.Issues and challenges facing rechargeable lithium batteries[J].Nature,2001,414(6861):359. 2 Hui W, Yi C.Designing nanostructured Si anodes for high energy lithium ion batteries[J].Nano Today,2012,7(5):414. 3 Lin K Z, Wang X L, Xu Y H.Recent development of tin-based materials as anode of the lithium ion battery[J].Chinese Journal of Power Sources,2005,1:019 4 Poizot P, Laruelle S, Grugeon S, et al.Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries[J].Nature,2001,32(3):496. 5 Zhang W M, Wu X L, Hu J S, et al.Carbon coated Fe3O4 nanospindles as a superior anode material for lithium-ion batteries[J].Advanced Functional Materials,2010,18(24):3941. 6 Cui Z M, Jiang L Y, Song W G, et al.High-yield gas-liquid interfacial synthesis of highly dispersed Fe3O4 nanocrystals and their application in lithium-ion batteries[J].Chemistry of Materials,2015,21(6):1162. 7 Guo C, Wang L, Zhu Y, et al.Fe3O4 nanoflakes in an N-doped carbon matrix as high-performance anodes for lithium ion batteries[J].Nanoscale,2015,7(22):10123. 8 Muraliganth T, Murugan A V, Manthiram A.ChemInform abstract: Facile synthesis of carbon-decorated single-crystalline Fe3O4 nanowires and their application as high performance anode in lithium ion batteries[J].Chemical Communications,2009,41(47):7360. 9 Liu H, Wang G, Wang J, et al.Magnetite/carbon core-shell nanorods as anode materials for lithium-ion batteries[J].Electrochemistry Communications,2008,10(12):1879. 10 Ma F X, Wu H B, Xu C Y, et al.Self-organized sheaf-like Fe3O4/C hierarchical microrods with superior lithium storage properties[J].Nanoscale,2015,7(10):4411. 11 Geim A K.Graphene: Status and prospects[J].Science,2009,324(5934):1530. 12 Zhou G, Wang D W, Li F, et al.Graphene-wrapped Fe3O4 anode material with improved reversible capacity and cyclic stability for lithium ion batteries[J].Chemistry of Materials,2010,22(18):5306. 13 Li X, Huang X, Liu D, et al.Synthesis of 3D hierarchical Fe3O4/graphene composites with high lithium storage capacity and for controlled drug delivery[J].Journal of Physical Chemistry C,2011,115(44):21567. 14 Su J, Cao M, Ren L, et al.Fe3O4-graphene nanocomposites with improved lithium storage and magnetism properties[J].Journal of Physical Chemistry C,2011,115(30):14469. 15 Wu Z S, Ren W, Xu L, et al.Doped graphene sheets as anode materials with superhigh rate and large capacity for lithium ion batteries[J].ACS Nano,2011,5(7):5463. 16 Liu C, Liu X G, Tan J, et al.Nitrogen-doped graphene by all-solid-state ball-milling graphite with urea as a high-power lithium ion battery anode[J].Journal of Power Sources,2017,342:157. 17 Liu Z W, Peng F, Wang H J, et al.Phosphorus-doped graphite la-yers with high electrocatalytic activity for the O2 reduction in an alkaline medium[J].Angewandte Chemie International Edition,2011,50(14):3257. 18 Liu Y, Huang K, Luo H, et al.Nitrogen-doped graphene-Fe3O4 architecture as anode material for improved Li-ion storage[J].RSC Advances,2014,4(34):17653. 19 Jiao J, Qiu W, Tang J, et al.Synthesis of well-defined Fe3O4, nanorods/N-doped graphene for lithium-ion batteries[J].Nano Research,2016,9(5):1. 20 Jiang Z J, Jiang Z.Fabrication of nitrogen-doped holey graphene hollow microspheres and their use as an active electrode material for lithium ion batteries[J].ACS Applied Materials & Interfaces,2014,6(21):19082. 21 Zhu H, Cao Y, Zhang J, et al.One-step preparation of graphene nanosheets via ball milling of graphite and the application in lithium-ion batteries[J].Journal of Materials Science,2016,51(8):3675. 22 Wei P, Bai S.Fabrication of a high-density polyethylene/graphene composite with high exfoliation and high mechanical performance via solid-state shear milling[J].RSC Advances,2015,5(114):93697. 23 Li Z Q, Lu C J, Xia Z P, et al.X-ray diffraction patterns of graphite and turbostratic carbon[J].Carbon,2007,45(8):1686. 24 Jeon I Y, Choi H J, Ju M J, et al.Direct nitrogen fixation at the edges of graphene nanoplatelets as efficient electrocatalysts for energy conversion[J].Scientific Reports,2013,3(30):2260. 25 Zhang M, Liu L, He T, et al.Melamine assisted solid exfoliation approach for the synthesis of few-layered fluorinated graphene nanosheets[J].Materials Letters,2016,171:191. 26 Li L, Dou Y, Wang L, et al.One-step synthesis of high-quality N-doped graphene/Fe3O4 hybrid nanocomposite and its improved supercapacitor performances[J].RSC Advances,2014,4(49):25658. 27 Chen S, Duan J, Ran J, et al.N-doped graphene film-confined nickel nanoparticles as a highly efficient three-dimensional oxygen evolution electrocatalyst[J].Energy & Environmental Science,2013,6(12):3693. 28 Lin Y C, Lin C Y, Chiu P W.Controllable graphene N-doping with ammonia plasma[J].Applied Physics Letters,2010,96(13):133110. 29 Lu W, Shen Y, Xie A, et al.Green synthesis and characterization of superparamagnetic Fe3O4, nanoparticles[J].Journal of Magnetism & Magnetic Materials,2010,322(13):1828. 30 Wal R L V, Tomasek A J, Pamphlet M I, et al. Analysis of HRTEM images for carbon nanostructure quantification[J].Journal of Nanoparticle Research,2004,6(6):555. 31 Zhang C, Fu L, Liu N, et al.Synthesis of nitrogen-doped graphene using embedded carbon and nitrogen sources[J].Advanced Mate-rials,2011,23(8):1020. 32 Qin G, Fang Z, Wang C.Template free construction of a hollow Fe3O4 architecture embedded in an N-doped graphene matrix for lithium storage[J].Dalton Transactions,2015,44(12):5735. 33 Liu Y, Yu L, Ong C N, et al.Nitrogen-doped graphene nanosheets as reactive water purification membranes[J].Nano Research,2016,9(7):1983. 34 Geng D, Yang S, Zhang Y, et al.Nitrogen doping effects on the structure of graphene[J].Applied Surface Science,2011,257(21):9193. 35 Sivakkumar S R, Milev A S, Pandolfo A G.Effect of ball-milling on the rate and cycle-life performance of graphite as negative electrodes in lithium-ion capacitors[J].Electrochimica Acta,2011,56(27):9700. 36 Shan H, Li X, Cui Y, et al.Sulfur/nitrogen dual-doped porous graphene aerogels enhancing anode performance of lithium ion batteries[J].Electrochimica Acta,2016,205:188. 37 Wang L, Yu Y, Chen P C, et al.Electrospinning synthesis of C/Fe3O4, composite nanofibers and their application for high perfor-mance lithium-ion batteries[J].Journal of Power Sources,2008,183(2):717. 38 Wang J Z, Zhong C, Wexler D, et al.Graphene-encapsulated Fe3O4 nanoparticles with 3D laminated structure as superior anode in lit-hium ion batteries[J].Chemistry (Weinheim an der Bergstrasse, Germany),2011,17(2):661. 39 Jin S, Deng H, Long D, et al.Facile synthesis of hierarchically structured Fe3O4/carbon micro-flowers and their application to lit-hium-ion battery anodes[J].Journal of Power Sources,2011,196(8):3887. 40 Fu C, Zhao G, Zhang H, et al.A facile route to controllable synthesis of Fe3O4/graphene composites and their application in lit-hiumion batteries[J].International Journal of Electrochemical Science,2014,9(1):46. 41 Bhuvaneswari S, Pratheeksha P M, Anandan S, et al.Efficient reduced graphene oxide grafted porous Fe3O4 composite as a high performance anode material for Li-ion batteries[J].Physical Chemistry Chemical Physics,2014,16(11):5284.
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