CeO2光催化原理及改性研究进展

doi:10.11896/cldb.23080150

材料导报

2024, Vol. 38

Issue (21): 23080150-6 https://doi.org/10.11896/cldb.23080150

无机非金属及其复合材料

CeO₂光催化原理及改性研究进展

莫日格吉乐¹, 包莫日根¹, 白璐¹, 谢兵³, 于晓丽⁴, 曹鸿璋⁴, 赵丹蕾⁵, 赵斯琴^1,2,*

1 内蒙古师范大学化学与环境科学学院,呼和浩特 010022
2 内蒙古自治区环境化学重点实验室,呼和浩特 010022
3 中国北方稀土(集团)高科技股份有限公司,内蒙古包头 014010
4 白云鄂博稀土资源研究与综合利用全国重点实验室,内蒙古包头 014060
5 内蒙古大学化学化工学院,呼和浩特 010022

Research Progress on the Principle and Modification of CeO₂ Photocatalysis

LIU Morigejile¹, BAO Morigen¹, BAI Lu¹, XIE Bing³, YU Xiaoli⁴, CAO Hongzhang⁴, ZHAO Danlei⁵, ZHAO Siqin^1,2,*

1 School of Chemistry and Environmental Sciences, Inner Mongolia Normal University, Hohhot 010022, China
2 Inner Mongolia Autonomous Region Key Laboratory of Environmental Chemistry, Hohhot 010022, China
3 China North Rare Earth (Group) High Tech Co., Ltd., Baotou 014010, Inner Mongolia, China
4 National Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization, Baotou 014060, Inner Mongolia, China
5 College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010022, China

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摘要光催化技术是一种新兴的环境保护技术,可用于处理水和空气中的有机和无机污染物。CeO₂光催化剂由于其高稳定性和强光吸收能力而备受关注。但是CeO₂对自然可见光的吸收很弱,光生电子反应受限,在光催化中不能直接利用可见光促进电荷分离,这限制了催化活性和效率。本文主要从CeO₂自身的基本性能、结构和基本原理出发,综述了通过负载、掺杂及半导体复合等方法改性CeO₂光催化剂的研究进展,并展望了这一领域的发展前景。

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	莫日格吉乐
	包莫日根
	白璐
	谢兵
	于晓丽
	曹鸿璋
	赵丹蕾
	赵斯琴

关键词: CeO₂ 光催化改性负载掺杂半导体复合

Abstract: Photocatalytic technology is an emerging environmental protection technology that can be used to treat organic and inorganic pollutants in water and air. CeO₂ photocatalysts have attracted much attention due to their high stability and strong light-absorption. However pure CeO₂ can absorb only a quite small part of natural visible light, restraining its photo-induced electron generation reaction. In photocatalysis conditions, CeO₂ cannot directly utilize visible light to promote charge separation, thereby limiting its catalytic activity and efficiency. Starting from the basic properties, structure, and principles of CeO₂, this review summarizes the modification of CeO₂ using methods such as loading, doping, and semiconductor hybridization, and discusses the future development prospect of this field.

Key words: cerium oxide photocatalysis modification load doping semiconductor hybridization

出版日期: 2024-11-10 发布日期: 2024-11-11

ZTFLH:

O616

基金资助: 国家自然科学基金(22266025);内蒙古自然科学联合基金项目(2022LHMS02001);内蒙古师范大学基本科研业务费专项(2022JBTD009);北方稀土项目(课题)技术开发基金(2022H2490)

通讯作者: *赵斯琴,内蒙古师范大学化学与环境科学学院教授、博士研究生导师。1995年内蒙古师范大学化学系化学专业本科毕业,2001年内蒙古师范大学化学专业硕士毕业后到内蒙古师范大学工作至今,2010年北京科技大学化学专业博士毕业。目前主要从事TiO₂纳米材料的改性制备及污水处理研究、稀土光催化剂的反应机理研究。发表论文100余篇,包括Applied Catalysis B: Environmental、Ceramics International、Macromolecular Research等。Zhaosq@imnu.edu.cn

作者简介: 莫日格吉乐,2021年6月于内蒙古师范大学获得理学学士学位。现为内蒙古师范大学化学与环境科学学院博士研究生,在赵斯琴教授的指导下进行研究。目前主要研究领域为无机纳米材料。

引用本文:

莫日格吉乐, 包莫日根, 白璐, 谢兵, 于晓丽, 曹鸿璋, 赵丹蕾, 赵斯琴. CeO₂光催化原理及改性研究进展[J]. 材料导报, 2024, 38(21): 23080150-6.
LIU Morigejile, BAO Morigen, BAI Lu, XIE Bing, YU Xiaoli, CAO Hongzhang, ZHAO Danlei, ZHAO Siqin. Research Progress on the Principle and Modification of CeO₂ Photocatalysis. Materials Reports, 2024, 38(21): 23080150-6.

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http://www.mater-rep.com/CN/10.11896/cldb.23080150 或 http://www.mater-rep.com/CN/Y2024/V38/I21/23080150

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