不同类型锌卟啉自组装染料敏化太阳能电池

材料导报

2021, Vol. 35

Issue (z2): 479-482

高分子与聚合物基复合材料

不同类型锌卟啉自组装染料敏化太阳能电池

武彧¹, 刘家成²

1 黔南民族师范学院化学化工学院,都匀 558000
2 西北师范大学化学化工学院,兰州 730070

Novel Self-assembly Dye-sensitized Solar Cells: Using Different Types of Electron Donor Zinc Porphyrin

WU Yu¹, LIU Jiacheng²

1 School of Chemistry and Chemical Engineering, Qiannan Normal University for Nationalities, Duyun 558000, China
2 College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

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摘要光敏染料在染料敏化太阳能电池中起到关键作用,设计新型光敏剂是提高自组装染料敏化太阳能电池效率的有效策略。为此最根本的问题是光敏剂的结构、组装体光电特性与光伏性能三者的关系。本文介绍了两种不同结构类型的含羧基的供电子体锌卟啉(ZnPx),并对其配位自组装双层染料敏化太阳能电池进行研究。研究结果表明,ZnP1结构(2+2型)供电子体锌卟啉具有较优的电流、电压,展示出较高的光电转换效率(η=1.68%)。最后还对自组装体结构进行了验证。

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	武彧
	刘家成

关键词: 染料敏化太阳能电池配位自组装供电子体锌卟啉光敏剂

Abstract: Dye plays a key role in dye-sensitized solar cells. Designing a new photosensitizer is an effective strategy to improve the efficiency of self-assembled dye-sensitized solar cells. The most fundamental problem is the relationship between the structure of photosensitizer, the photoelectric properties of the assembled body and the photovoltaic performance. In this paper, two kinds of zinc porphyrin (ZnPx) with carboxyl group are introduced, and their coordination self-assembly double-layer dye-sensitized solar cells are studied. The results show that zinc porphyrin, a structure of ZnP1 (2+2), has better current and voltage, and shows a high efficiency of photoelectric conversion (η=1.68%). The self-assembly structure is also verified in this paper.

Key words: dye-sensitized solar cells coordination self-assembly electron donor zinc porphyrin photosensitizer

发布日期: 2021-12-09

ZTFLH:

O614.24⁺1

基金资助: 贵州省科技厅科学技术基金项目(黔科合基础-ZK〔2021〕一般064);贵州省教育厅自然科学基金项目(黔教合KY字〔2020〕200;黔教合KY字〔2020〕203);黔南民族师范学院科研创新基金重大专项计划项目(QNSY2018BS020);黔南民族师范学院校级项目(qnsy201503)

通讯作者: ywu5@sgmtu.edu.cn

作者简介: 武彧,黔南民族师范学院副教授,硕士研究生导师。2017年,在西北师范大学获得理学博士学位,毕业后进入黔南民族师范学院任教。以第一作者在国内外学术期刊上发表论文20余篇,申请国家发明专利3项,其中授权1项。研究工作主要围绕卟啉配位自组装染料敏化太阳能电池,开展关于功能配合物,基础化学教育教学研究,主持包括贵州省科技厅项目、贵州省教育厅青年科技人才成长项目、黔南州科技局工业类项目等。

引用本文:

武彧, 刘家成. 不同类型锌卟啉自组装染料敏化太阳能电池[J]. 材料导报, 2021, 35(z2): 479-482.
WU Yu, LIU Jiacheng. Novel Self-assembly Dye-sensitized Solar Cells: Using Different Types of Electron Donor Zinc Porphyrin. Materials Reports, 2021, 35(z2): 479-482.

链接本文:

http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2021/V35/Iz2/479

1 O'Regan B, Grátzel M. Nature, 1991, 353, 737.
2 Hagfeldt A, Boschloo G, Sun L, et al.Chemical Reviews, 2010, 110, 6595.
3 Ahmad S, Guillen E, Kavan L, et al.Energy & Environmental Science, 2013, 6, 3439.
4 Lee C P, Lin R Y Y, Lin L Y, et al. RSC Advances, 2015, 5, 23810.
5 Nazeeruddin M K, Kay A, Rodicio I, et al. Journal of the American Chemical Society, 1993, 115, 6382.
6 Urbani M, Grátzel M, Nazeeruddin M K, et al. Chemical Reviews, 2014, 114, 12330.
7 Higashino T, Fujimori Y, Sugiura K, et al.Angewandte Chemie-International Edition, 2015, 54, 9052.
8 Imahori H, Umeyama T, Ito S.Accounts of Chemical Research, 2009, 42, 1809.
9 Liang M, Chen J.Chemical Society Reviews, 2013, 42, 3453.
10 Joly D, Pelleja L, Narbey S, et al.Energy & Environmental Science, 2015, 8, 2010.
11 Kang S H, Choi I T, Kang M S, et al. Journal of Materials Chemistry A, 2013, 1, 3977.
12 Qian X, Yan R, Shao L, et al.Dyes Pigments, 2016, 134, 434.
13 Seo K D, Lee M J, Song H M, et al. Dyes Pigments, 2012, 94, 143.
14 Chen J, Ko S, Liu L, et al.New Journal of Chemistry, 2015, 39, 3736.
15 Lu F, Feng Y, Wang X, et al.Dyes Pigments, 2017, 139, 255.
16 Yella A, Mai C L, Zakeeruddin S M, et al. Angewandte Chemie-International Edition, 2014, 53, 2973.
17 Mathew S, Yella A, Gao P, et al.Nature Chemistry, 2014, 6, 242.
18 Martir D R, Averardi M, Escudero D, et al. Dalton Trans, 2017, 46, 2255.
19 Charalambidis G, Karikis K, Georgilis E, et al.Sustainable Energy Fuels, 2017, 1, 387.
20 Parussulo A L A, Iglesias B A, Toma H E, et al. Chemical Communications, 2012, 48, 6939.
21 Subbaiyan N K, Wijesinghe C A, D'Souza F. Journal of the American Chemical Society, 2009, 131, 14646.
22 Islam A, Akhtaruzzaman M, Chowdhury T H, et al.ACS Applied Materials & Interfaces, 2016, 8, 4616.
23 Jia H L, Huang M Z, Peng Z J, et al. Dalton Transactions, 2017, 46, 15124.
24 Zhang J X, Han F M, Liu J C,et al. Tetrahedron Letters, 2016, 57, 1867.
25 Wu Y, Liu J C, Cao J, et al. Research on Chemical Intermediates, 2015, 41, 6833.
26 Han F M, Yang J Y,Zhe Y, et al. Dalton Transactions, 2016, 45, 8862.
27 Liu H, Wu Y, Wu F Y,et al. Organic Electronics, 2019, 71, 290.
28 Wu Y, Liu H, Liu J C, et al. Journal of Coordination Chemistry, 2019, 72, 69.
29 Wu Y, Zhang Q, Liu J C, et al.Journal of Porphyrins and Phthalocyanines, 2017, 21, 116.
30 Palomares E, Martínez-Díaz M V, Haque S A, et al. Chemical Communications, 2004, 18, 2112.
31 Kira A, Umeyama T, Matano Y, et al. Journal of the American Chemical Society, 2009, 131, 3198.
32 Hay P J,Wadt W R. The Journal of Chemical Physics, 1985, 82, 270.
33 Wang Q, Moser J E,Grátzel M. The Journal of Physical Chemistry B, 2005, 109, 14945.
34 Fabregat-Santiago F, Garcia-Belmonte G, Mora-Sero I, et al. Physical Chemistry Chemical Physics, 2011, 13, 9083.
35 Yu L, Fan K, Duan T, et al.ACS Sustainable Chemistry & Engineering, 2014, 2, 718.
36 Song B J, Song H M, Choi I T, et al.Chemistry-A European Journal, 2011, 17, 11115.
37 Song H M,Seo K D, Kang M S, et al. Journal of Materials Chemistry, 2012, 22(9), 3786

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