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《材料导报》期刊社  2017, Vol. 31 Issue (7): 19-25    https://doi.org/10.11896/j.issn.1005-023X.2017.07.003
  材料综述 |
PEDOT基对电极染料敏化太阳能电池研究进展*
李昱煜1,2,沈沪江2,刘岩2,王炜2,袁慧慧2,谢华清1
1 上海第二工业大学环境与材料工程学院,上海 201209;
2 中国科学院上海硅酸盐研究所能量转换材料 重点实验室,上海 200050
Progress in PEDOT-based Conduct Electrode for Dye-sensitized Solar Cells
LI Yuyu1,2, SHEN Hujiang2, LIU Yan2, WANG Wei2, YUAN Huihui2, XIE Huaqing1
1 School of Environmental and Materials Engineering, Shanghai Polytechnic University, Shanghai 201209;
2 State Key Laboratory of Materials for Energy Transformation, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050
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摘要 染料敏化太阳能电池(DSSC)是新型太阳能电池的研究热点之一,其优异的弱光发电性能被不断探索,同时透明及柔性DSSC在可穿戴设备上的应用也与日俱增。DSSC的循环依靠对电极的作用才能及时高效地完成,因此对电极材料的选择尤为关键。近几年研究者们对对电极材料的研究不断深入,其中可作为DSSC对电极材料使用的高分子导电聚合物聚3,4-乙撑二氧噻吩(PEDOT)因其高导电性、对电解质的催化能力、透明性和柔性等特点受到广泛关注。以含PEDOT或掺杂PEDOT对电极的DSSC为对象,阐述了PEDOT对电极的制备方法,并总结了近几年PEDOT作为DSSC对电极的研究进展。在此基础上,提出未来在电池效率突破研究中应以原位聚合法制备PEDOT对电极为主,以及在大规模工业化生产中应以物理涂覆法为主的观点,为PEDOT对电极DSSC的研究提供依据。
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李昱煜
沈沪江
刘岩
王炜
袁慧慧
谢华清
关键词:  染料敏化太阳能电池  对电极  PEDOT(聚3,4-乙撑二氧噻吩)    
Abstract: Dye-sensitized solar cells (DSSC) is an attracting issue of the new solar cell field. Its low-light electricity generating capacity has been further explored and developed. The application of transparent and flexible DSSC on wearable devices has also attracted more and more attention. The performance of the DSSC highly depends on the conduct electrode (CE), therefore the selection of the material for CE arises as a key issue. Poly(3,4-ethylenedioxythiophene) (PEDOT), a high molecular conductive polymer, has shown its potential as CE material in recent years because of its high conductivity, catalytic ability of the electrolyte, transparency and flexibility. In this paper, we focus on PEDOT and doped PEDOT using for CEs of the DSSCs. The preparation methods of PEDOT and doped PEDOT have been discussed and the progresses of the researches on the application of these materials as CEs of DSSCs have been reviewed. We propose that in situ polymerization is the promising method for preparing PEDOT film CE, whereas physical coating is the potential route for large-scale fabrication. This review provides references for the development of the CEs of DSSCs.
Key words:  dye-sensitized solar cells    conduct electrode    PEDOT(poly(3    4-ethylenedioxythiophene))
               出版日期:  2017-04-10      发布日期:  2018-05-08
ZTFLH:  TB30  
基金资助: *国家自然科学基金重大项目(51590902);国家863计划项目(2014AA052002)
通讯作者:  沈沪江,1979年生,博士,高级工程师,研究方向为太阳能电池材料E-mail:shenhujiang@mail.sic.ac.cn谢华清,男,1970年生,博士,教授,硕士研究生导师,研究方向为环境能源材料及材料热物理E-mail:hqxie@sspu.edu.cn   
作者简介:  李昱煜:女,1992年生,硕士研究生,研究方向为太阳能电池材料E-mail:yihht@163.com
引用本文:    
李昱煜,沈沪江,刘岩,王炜,袁慧慧,谢华清. PEDOT基对电极染料敏化太阳能电池研究进展*[J]. 《材料导报》期刊社, 2017, 31(7): 19-25.
LI Yuyu, SHEN Hujiang, LIU Yan, WANG Wei, YUAN Huihui, XIE Huaqing. Progress in PEDOT-based Conduct Electrode for Dye-sensitized Solar Cells. Materials Reports, 2017, 31(7): 19-25.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.07.003  或          http://www.mater-rep.com/CN/Y2017/V31/I7/19
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