Co1.5CrFeNi1.5 Mo0.5Ti0.5在不同pH值的3.5%NaCl酸性溶液中的钝化行为研究

材料导报

2021, Vol. 35

Issue (z2): 399-403

金属与金属基复合材料

Co_1.5CrFeNi_1.5 Mo_0.5Ti_0.5在不同pH值的3.5%NaCl酸性溶液中的钝化行为研究

田永强^1,2, 苑清英^1,2, 付安庆³, 何石磊^1,2, 周新义^1,2, 汪强^1,2, 杨晓龙^1,2, 陈浩明^1,2

1 国家石油天然气管材工程技术研究中心,宝鸡 721008
2 宝鸡石油钢管有限责任公司,宝鸡 721008
3 石油管材及装备材料服役行为与结构安全国家重点实验室,西安 710077

Passivation Behavior of Co_1.5CrFeNi_1.5Mo_0.5Ti_0.5 in 3.5% NaCl Solution with Different pH Values

TIAN Yongqiang^1,2, YUAN Qingying^1,2, FU Anqing³, HE Shilei^1,2, ZHOU Xinyi^1,2, WANG Qiang^1,2, YANG Xiaolong^1,2, CHEN Haoming^1,2

1 Chinese National Engineering Research Center for Petroleum and Natural Gas Tubular Goods, Baoji 721008, China
2 Baoji Petroleum Steel Pipe Co., Ltd., Baoji 721008, China
3 State Key Laboratory for Performance and Structure Safety of Petroleum Tubular Goods and Equipment Materials, Xi'an 710077, China

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摘要为了研究Co_1.5CrFeNi_1.5Mo_0.5Ti_0.5在不同pH值的3.5%NaCl酸性溶液中的钝化行为,以纯度超过99wt%的钴(Co)、铬(Cr)、钛(Ti)、铁(Fe)和镍(Ni)为原料,用真空感应炉进行熔炼,对熔炼后的Co_1.5CrFeNi_1.5 Mo_0.5Ti_0.5合金运用X射线衍射仪(XRD)、扫描电镜(SEM)、能谱分析仪(EDS)进行显微组织的表征,采用动电位极化、电化学阻抗谱、恒电位极化、XPS分析等手段来研究其在不同pH值的3.5%NaCl溶液中的钝化行为。结果表明,Co_1.5CrFeNi_1.5 Mo_0.5Ti_0.5相结构为单一的fcc结构,其微观组织为树枝晶结构;Co_1.5CrFeNi_1.5 Mo_0.5Ti_0.5合金在不同pH值的3.5%NaCl溶液中具有较强的钝化能力,且随着pH值的增加,其抗腐蚀能力增强;其钝化膜的成分主要包括Cr₂O₃、Cr(OH)₃、Co₃O₄、MoO₃、NiO、Fe₂O₃、Fe₃O₄、TiO₂。

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	田永强
	苑清英
	付安庆
	何石磊
	周新义
	汪强
	杨晓龙
	陈浩明

关键词: 高熵合金显微组织维顿电流密度 XPS 钝化膜

Abstract: IIn order to study the passivation behavior of Co_1.5CrFeNi_1.5 Mo_0.5Ti_0.5 in 3.5% NaCl acid solution with different pH values. Cobalt (Co), chromium (Cr), titanium (Ti), iron (Fe) and nickel (Ni) with a purity of more than 99wt% were melted in a vacuum induction furnace. The microstructure of Co_1.5CrFeNi_1.5 Mo_0.5Ti_0.5 alloy was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS). The passivation behavior of Co_1.5CrFeNi_1.5 Mo_0.5Ti_0.5alloy in 3.5% NaCl acid solution with different pH values was studied by potentiodynamic polarization, electrochemical impedance spectroscopy, potentiostatic polarization and XPS analysis. The results show that the phase structure of Co_1.5CrFeNi_1.5 Mo_0.5Ti_0.5 is a single fcc structure, and its microstructure is dendrite structure; Co_1.5CrFeNi_1.5-Mo_0.5Ti_0.5 alloy has strong passivation ability in different pH 3.5% NaCl acid solution, and its corrosion resistance is enhanced with the increase of pH value; the composition of passivation film mainly includes Cr₂O₃, Cr(OH)₃, Co₃O₄, MoO₃, NiO, Fe₂O₃, Fe₃O₄, TiO₂.

Key words: high entropy alloy microstructure passive current density XPS passivation film

发布日期: 2021-12-09

ZTFLH:

TB31

基金资助: 国家自然科学基金青年科学基金(21908250)

通讯作者: 2236530358@qq.com

作者简介: 田永强,工程师,硕士,2020年毕业于西安石油大学,同年在中石油宝鸡钢管有限责任公司工作,主要从事油井管材研究与开发工作。

引用本文:

田永强, 苑清英, 付安庆, 何石磊, 周新义, 汪强, 杨晓龙, 陈浩明. Co_1.5CrFeNi_1.5 Mo_0.5Ti_0.5在不同pH值的3.5%NaCl酸性溶液中的钝化行为研究[J]. 材料导报, 2021, 35(z2): 399-403.
TIAN Yongqiang, YUAN Qingying, FU Anqing, HE Shilei, ZHOU Xinyi, WANG Qiang, YANG Xiaolong, CHEN Haoming. Passivation Behavior of Co_1.5CrFeNi_1.5Mo_0.5Ti_0.5 in 3.5% NaCl Solution with Different pH Values. Materials Reports, 2021, 35(z2): 399-403.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2021/V35/Iz2/399

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