黑色二氧化钛纳米材料研究进展

材料导报

2019, Vol. 33

Issue (z1): 8-15

无机非金属及其复合材料

黑色二氧化钛纳米材料研究进展

张甄^1,2, 王宝冬¹, 徐文强¹, 秦绍东¹, 孙琦¹

1 北京低碳清洁能源研究所,北京 102209
2 中国科学院大连化学物理研究所,大连 116023

Research Progress on Black Titanium Dioxide Nanomaterials

ZHANG Zhen^1,2, WANG Baodong¹, XU Wenqiang¹, QIN Shaodong¹, SUN Qi¹

1 National Institute of Clear-and-Low-Carbon Energy, Beijing 102209
2 Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023

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摘要相较于普通的TiO₂纳米材料,黑色TiO₂纳米材料具有独特的晶体核/非晶核壳结构。该材料通过引入晶格缺陷改善TiO₂的晶体结构来优化其电子能级结构,缩短禁带宽度,改善光学性能,其光响应范围从紫外区域扩展到红外区域,使得黑色TiO₂纳米材料在能源和环境领域有着广泛的应用。本文主要介绍了近年来黑色TiO₂纳米材料的性质、制备方法、改性方式、形貌控制、结构设计及以黑色TiO₂为基体改性材料的催化原理,最后对黑色TiO₂纳米材料的发展方向及实际应用前景(如在光降解有机污染物、光解水、燃料电池及光电化学传感器等方面)进行了展望。

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	张甄
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	孙琦

关键词: 黑色TiO₂ 纳米材料光学性能

Abstract: Compared with the normal white TiO₂ nanomaterials, the black TiO₂ nanomaterials possess a unique crystalline core-amorphous shell structure and can boost its visible and infrared light absorption by band structure engineering. Improving the optical absorption of black TiO₂ nanomaterials have attracted tremendous interest due to their applications in energy field and environmental pollution removal. The current review focuses on the various fabrication methods for black TiO₂ nanomaterials, their morphological variations, structure along with their various chemical/physical properties, photocatalytic reaction mechanism and applications to environmental and technological fields such as photodegradation of organic pollutants, photocatalytic water splitting, dye sensitized solar cells, batteries, super capacitors and photothermal therapy.

Key words: black TiO₂ nanomaterials optical absorption

出版日期: 2019-05-25 发布日期: 2019-07-05

ZTFLH:

O643

基金资助: 863项目 (2012AA06A115)

作者简介: 张甄,2018年1月毕业于天津大学,获得工学博士学位。现为北京低碳清洁能源研究所在站博士后,在孙琦教授的指导下进行研究,主要从事光电催化CO₂转化催化剂的研发。孙琦,北京低碳清洁能源研究所高级研究员,“千人计划”专家,煤化工研发中心主任。主要从事石油化工、煤炭化工的催化过程以及环境催化方面的研究,并在石油化工、煤炭化工、炼油和环境治理等领域取得显著成就。sunqi@nicenergy.com

引用本文:

张甄, 王宝冬, 徐文强, 秦绍东, 孙琦. 黑色二氧化钛纳米材料研究进展[J]. 材料导报, 2019, 33(z1): 8-15.
ZHANG Zhen, WANG Baodong, XU Wenqiang, QIN Shaodong, SUN Qi. Research Progress on Black Titanium Dioxide Nanomaterials. Materials Reports, 2019, 33(z1): 8-15.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2019/V33/Iz1/8

1 Fujishima A, Honda K. Nature,1972,238(5358),37.
2 Fujishima A, Zhang X. Comptes Rendus Chimie,2006,9(5),750.
3 Konstantinou I K, Albanis T A. Applied Catalysis B: Environmental,2004,49(1),1.
4 Liqiang J, Xiaojun S, Jing S, et al. Solar Energy Materials and Solar Cells,2003,79(2),133.
5 Nakata K, Fujishima A. Journal of Photochemistry and Photobiology C: Photochemistry Reviews,2012,13(3),169
6 Tryk D A, Fujishima A, Honda K. Electrochimica Acta,2000,45(15),2363.
7 Schneider J, Matsuoka M, Takeuchi M, et al. Chemical Reviews,2014,114(19),9919.
8 Dette C, Pérez-Osorio M A, Kley C S, et al. Nano Letters,2014,14(11),6533.
9 Chen X, Li C, Grätzel M, et al. Chemical Society Reviews,2012,41(23),7909.
10 Zeng Y, Xue Y, Long L, et al. Water, Air, & Soil Pollution,2019,230(2),50.
11 Ghosh R, Hara Y, Alibabaei L, et al. ACS Applied Materials & Interfaces,2012,4(9),4566.
12 Inturi S N R, Boningari T, Suidan M, et al. The Journal of Physical Chemistry C,2013,118(1),231.
13 Hamedani H A, Allam N K, Garmestani H, et al. The Journal of Physical Chemistry C,2011,115(27),13480.
14 Dukes F M, Iuppa E, Meyer B, et al.Langmuir,2012,28(49),16933.
15 Roberts K G, Varela M, Rashkeev S, et al. Physical Review B,2008,78(1),014409.
16 Liu B, Chen H M, Liu C, et al. Journal of the American Chemical Society,2013,135(27),9995.
17 Mikulas T, Fang Z, Gole J L, et al. Chemical Physics Letters,2012,539(27),58.
18 Likodimos V, Han C, Pelaez M, et al. Industrial & Engineering Chemistry Research,2013,52(39),13957.
19 Hoang S, Guo S, Hahn N T, et al. Nano Letters,2011,12(1),26.
20 Zhang H, Liang Y, Wu X, et al. Materials Research Bulletin,2012,47(9),2188.
21 Jac′imovic′ J, Gaal R, Magrez A, et al. Applied Physics Letters,2013,102(17),172108.
22 Yan C, Yi W, Yuan H, et al. Environmental Progress & Sustainable Ene-rgy,2014,33(2),419.
23 Chen X, Liu L, Yu P Y, et al.Science,2011,331,746.
24 Lu H, Zhao B, Pan R, et al. RSC Advances,2014,4(3),1128.
25 Wei W, Yaru N, Chunhua L, et al. RSC Advances,2012,2(22),8286.
26 Wang Z, Yang C, Lin T, et al. Energy & Environmental Science,2013,6(10),3007.
27 Lu Z, Yip C T, Wang L, et al. Chem Plus Chem,2012,77(11),991.
28 Zeng L, Song W, Li M, et al. Applied Catalysis B: Environmental,2014,147,490.
29 Wang G, Wang H, Ling Y, et al. Nano Letters,2011,11(7),3026.
30 Zhao Z, Tan H, Zhao H, et al.Chemical Communications,2014,50(21),2755.
31 Dong J, Han J, Liu Y, et al. ACS Applied Materials & Interfaces,2014,6(3),1385.
32 Pesci F M, Wang G, Klug D R, et al.The Journal of Physical Chemistry C,2013,117(48),25837.
33 Zhu G, Lin T, Lü X, et al. Journal of Materials Chemistry A,2013,1(34),9650.
34 Lu X, Wang G, Zhai T, et al. Nano Letters,2012,12(3),1690.
35 Wei W, Yaru N, Chunhua L, et al. RSC Advances,2012,2(22),8286.
36 Li H, Chen Z, Tsang C K, et al. Journal of Materials Chemistry A,2014,2(1),229.
37 Aschauer U, Selloni A. Physical Chemistry Chemical Physics,2012,14(48),16595.
38 Lu J, Dai Y, Jin H, et al. Physical Chemistry Chemical Physics,2011,13(40),18063.
39 Liu L, Peter Y Y, Chen X, et al. Physical Review Letters,2013,111(6),065505.
40 Liu N, Schneider C, Freitag D, et al. Nano Letters,2014,14(6),3309.
41 An H R, Park S Y, Kim H, et al. Scientific Reports,2016,6,29683.
42 Tang F, Li M, Gao C, et al. Applied Catalysis B: Environmental,2014,148,339.
43 Yu X, Kim B, Kim YK. ACS Catalysis, 2013,3,2479.
44 Qiu J, Li S, Gray E, et al. Journal of Physical Chemistry C,2014,118,8824.
45 Sasan K, Zuo F, Wang Y, et al.Nanoscale2015,7,13369.
46 Ren R, Wen Z, Cui S, et al. Scientific Reports,2015,5,10714.
47 Wang Z, Yang C, Lin T, et al. Energy & Environmental Science,2013,6(10),3007.
48 Zhu G, Lin T, Lyu X, et al. Journal of Materials Chemistry A,2013,1(34),9650.
49 Cui H, Zhao W, Yang C, et al. Journal of Materials Chemistry A,2014,2(23),8612.
50 Lin T, Yang C, Wang Z, et al. Energy & Environmental Science,2014,7(3),967.
51 Kang Q, Cao J, Zhang Y, et al. Journal of Materials Chemistry A,2013,1(18),5766.
52 Zhang X Q, Chen J B, Wang C W, et al. Nanotechnology2015,26(17),175705
53 Liu X, Gao S, Xu H, et al. Nanoscale,2013,5(5),1870.
54 Xin X, Xu T, Wang L, et al. Scientific Reports,2016,6,23684.
55 Pei Z, Ding L, Lin H, et al. Journal of Materials Chemistry A,2013,1(35),10099.
56 Yang Y, Liao J, Li Y, et al. RSC Advances,2016,6(52),46871.
57 Kim C, Kim S, Hong S P, et al. Physical Chemistry Chemical Physics,2016,18(21),14370.
58 Yang Y, Hoffmann M R. Environmental Science & Technology,2016,50(21),11888.
59 Kim C, Kim S, Lee J, et al. ACS Applied Materials & Interfaces,2015,7(14),7486.
60 Kim C, Kim S, Choi J, et al. Electrochemical Acta,2014,141,113.
61 Dong J, Han J, Liu Y, et al. ACS Applied Materials & Interfaces,2014,6(3),1385.
62 Fan C, Chen C, Wang J, et al.Scientific Reports,2015,5,11712.
63 Chen X, Zhao D, Liu K, et al. ACS Applied Materials & Interfaces,2015,7(29),16070.
64 Pu S, Zhu R, Ma H, et al. Applied Catalysis B: Environmental,2017,218,208.
65 Li P, Xue L, Li Y, et al. Materials Letters,2017,207,217.
66 Barrocas B, Entradas T J, Nunes C D, et al. Applied Catalysis B: Environmental,2017,218,709.
67 Luan X, Wang Y. Materials Science in Semiconductor Processing,2014,25,43.
68 Hong J, Meysami S S, Babenko V, et al. Applied Catalysis B: Environmental,2017,218,267.
69 Cui W, Xue D, Yuan X, et al. Applied Surface Science,2017,411,105.
70 Bai H, Liu Z, Sun D D. Journal of the American Ceramic Society,2013,96(3),942.
71 Zhang W, Xiao X, Zheng L, et al. The Canadian Journal of Chemical Engineering,2015,93(9),1594.
72 Zhang Z, Xiao F, Guo Y, et al. ACS Applied Materials & Interfaces,2013,5(6),2227.
73 Vaiano V, Sacco O, Sannino D, et al. Journal of Chemical Technology and Biotechnology,2014,89(8),1175.
74 Oberdörster G, Ferin J, Gelein R, et al. Environmental Health Perspectives,1992,97,193.
75 Oberdörster G, Ferin J, Lehnert B E. Environmental Health Perspectives,1994,102(Suppl 5),173.
76 Cheng K, Wan J, Liang K. Journal of the American Ceramic Society,1999,82(5),1212.
77 Matsunaga T, Tomoda R, Nakajima T, et al. FEMS Microbiology Letters,1985,29(1-2),211.
78 Chen H, Chen S, Quan X, et al. The Journal of Physical Chemistry C,2008,112(25),9285.
79 Cozzoli P D, Fanizza E, Comparelli R, et al. The Journal of Physical Chemistry B,2004,108(28),9623.
80 Liu N, Schneider C, Freitag D, et al. Nano Letters,2014,14(6),3309.
81 Yu X, Kim B, Kim Y K. ACS Catalysis,2013,3(11),2479.
82 Zhang C, Yu H, Li Y, et al. ChemSusChem,2013,6(4),659.
83 Lin T, Yang C, Wang Z, et al. Energy & Environmental Science,2014,7(3),967.
84 Kako T, Umezawa N, Xie K, et al. Journal of Materials Science,2013,48(1),108.
85 Harris L A, Schumacher R. Journal of the Electrochemical Society,1980,127(5),1186.
86 Liu H, Ma H T, Li X Z, et al. Chemosphere,2003,50(1),39.
87 Liu N, Häublein V, Zhou X, et al. Nano Letters,2015,15(10),6815.
88 Zhi J, Yang C, Lin T, et al. Nanoscale,2016,8(7),4054.

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