Abstract: Reduced graphene oxide-platinum (rGO-Pt) nanocomposites were produced by high temperature synthetic process from the graphene oxide and H2PtCl6. Transmission electron microscopy and micro-spectrum results showd that Pt nanoparticles with a average diameter of 30 nm were uniformly distributed on the rGO surface. The Pt nanoparticles had porous structure with good crystallinity. GO was transferred to rGO at high temperature. With the similar method, rGO-Au or rGO-Ag nanocomposites could also be prepared, and the resulted composites exhibit typical surface plasmon resonance adsorption against visible light. In this method, oleylamine acted as solvent, reduction agent for metal salt and surfactant simultaneously. The synthetic process is simple, rapid, and has wide practical application prospect.
1 Shen X, Wang Z, Wu Y, et al. Multilayer graphene enables higher efficiency in improving thermal conductivities of graphene/epoxy composites [J]. Nano Lett,2016,16(6):3585. 2 Mao H Y, Laurent S, Chen W, et al. Graphene: Promises, facts, opportunities, and challenges in nanomedicine [J]. Chem Rev,2013,113(5):3407. 3 Georgakilas V, Tiwari J N, Kemp K C, et al. Noncovalent functio-nalization of graphene and graphene oxide for energy materials, biosensing, catalytic, and biomedical applications [J]. Chem Rev,2016,116(9):5464. 4 Li N, Cao M, Hu C. Review on the latest design of graphene-based inorganic materials [J]. Nanoscale,2012,4(20):6205. 5 Xiao C, Goh T W, Qi Z, et al. Conversion of levulinic acid to γ-valerolactone over few-layer graphene-supported ruthenium catalysts [J]. ACS Catal,2016,6(2):593. 6 Sarno M, Cirillo C, Scudieri C, et al. Electrochemical applications of magnetic core-shell graphene-coated feco nanoparticles [J]. Ind Eng Chem Res,2016,55(11):3157. 7 Huisman E H, Shulga A G, Zomer P J, et al. High gain hybrid graphene-organic semiconductor phototransistors [J]. ACS Appl Mater Interf,2015,7(21):11083. 8 Ni Y, Chen L, Teng K, et al. Superior mechanical properties of epoxy composites reinforced by 3D interconnected graphene skeleton [J]. ACS Appl Mater Interface,2015,7(21):11583. 9 Qi L, Xin Y, Zuo Z, et al. Grape-like Fe3O4 agglomerates grown on graphene nanosheets for ultrafast and stable lithium storage [J]. ACS Appl Mater Interface,2016,8(27):17245. 10 Du T, Zhang H D, Fan T X. Recent progress on graphene/metal composites [J]. Mater Rev:Rev,2015,29(3):121(in Chinese). 独涛, 张洪迪, 范同祥. 石墨烯/金属复合材料的研究进展 [J]. 材料导报:综述篇,2015,29(3):121. 11 Shang N, Papakonstantinou P, Wang P, et al. Platinum integrated graphene for methanol fuel cells [J]. J Phys Chem C,2010,114:15837. 12 Qiu J D, Wang G C, Liang R P, et al. Controllable deposition of platinum nanoparticles on graphene as an electrocatalyst for direct methanol fuel cells [J]. J Phys Chem C,2011,115(31):15639. 13 Yoo E, Okata T, Akita T, et al. Enhanced electrocatalytic activity of pt subnanoclusters on graphene nanosheet surface [J]. Nano Lett,2009,9(6):2255. 14 Yang Zijuan,Zhao Mengxi,Chen Sen, et al. Platinum-palladium bimetallic nanospheres supported on graphene nanosheets as enhanced electrocatalyst formethanol oxidation [J]. Chem Res,2014,3:273. 15 Du C, Hei X Z, Luo W, et al. Synthesis of 3D nitrogen-doped graphene supported AgPd nanocatalysts and application in catalytic dehydrogenation of formic acid for chemical hydrogen storage[J]. Sci Sin Chim,2016,46(5):487(in Chinese). 杜成, 黑秀泽, 罗威,等. N掺杂石墨烯负载AgPd纳米催化剂室温高效催化甲酸分解制氢 [J].中国科学,2016,46(5):487. 16 Kellici S, Acord J, Vaughn A, et al. Calixarene assisted rapid synthesis of silver-graphene nanocomposites with enhanced antibacterial activity [J]. ACS Appl Mater Interface,2016,8(29):19038. 17 Kumar D, Lee A, Lee T, et al. Ultrafast and efficient transport of hot plasmonic electrons by graphene for Pt free, highly efficient visible-light responsive photocatalyst [J]. Nano Lett,2016,16(3):1760. 18 Navalon S, Dhakshinamoorthy A, Alvaro M, et al. Metal nanoparticles supported on two-dimensional graphenes as heterogeneous ca-talysts [J]. Coord Chem Rev,2016,312:99. 19 Luo Y, Kong F Y, Li C, et al. One-pot preparation of reduced graphene oxide-carbon nanotube decorated with Au nanoparticles based on protein for non-enzymatic electrochemical sensing of glucose [J]. Sens Actuators B,2016,234:625. 20 Rao D, Sheng Q, Zheng J. Preparation of flower-like Pt nanoparticles decorated chitosan-grafted graphene oxide and its electrocatalysis of hydrazine [J]. Sens Actuators B,2016,236:192. 21 Yin P T, Shah S, Chhowalla M, et al. Design, synthesis,and chara-cterization of graphene-nanoparticle hybrid materials for bioapplications [J]. Chem Rev,2015,115(7):2483. 22 An’amt Mohamed Noor P R, Norazriena Yusoff, Huang Nay Ming, et al. Microwave synthesis of reduced graphene oxide decorated with silver nanoparticles for electrochemical determination of 4-nitrophenol [J]. Ceram Int,2016, doi.org/10.1016/j.ceramint.2016.09.026 23 Xin L, Yang F, Rasouli S, et al. Understanding Pt nanoparticle anchoring on graphene supports through surface functionalization [J]. ACS Catal,2016,6(4):2642. 24 Lee Y H, Polavarapu L, Gao N, et al. Enhanced optical properties of graphene oxide-Au nanocrystal composites [J]. Langmuir,2012,28(1):321. 25 Mayavan S, Sim J B, Choi S M. Simultaneous reduction, exfoliation and functionalization of graphite oxide into a graphene-platinum na-noparticle hybrid for methanol oxidation [J]. J Mater Chem,2012,22(14):6953. 26 De I P P, Multigner M, et al. Structural and magnetic characterization of oleic acid and oleylamine-capped gold nanoparticles [J]. J Appl Phys,2006,100(12):123915. 27 Li F, Du X Y, Yang R C. Synthesis of monodisperse Fe3O4 magnetite schistic hexagonal nanocrystals by polyol reduction method [J]. Chemical J Chinese Universities,2011,32(8):1688(in Chinese). 李芳, 杜雪岩, 杨瑞成. 多元醇还原法制备片状六边形Fe3O4纳米颗粒 [J]. 高等学校化学学报,2011,32(8):1688. 28 Wang C, Yin H, Chan R, et al. One-pot synthesis of oleylamine coated AuAg alloy NPs and their catalysis for CO oxidation [J]. Chem Mater,2009,21(3):433. 29 Polavarapu L, Venkatram N, Ji W, et al. Optical-limiting properties of oleylamine-capped gold nanoparticles for both femtosecond and nanosecond laser pulses [J]. ACS Appl Mater Interface,2009,1(10):2298. 30 Liu J, Chang M J, Gou X C, et al. One-step synthesis of antibody-stabilized aqueous colloids of noble metal nanoparticles [J]. Colloids Surf A,2012,404(404):112. 31 Kavitha H J M K, Gopinath P, Philip R. Synthesis of reduced graphene oxide-ZnO hybrid with enhanced optical limiting properties [J]. J Mater Chem,2013,1(23):3669. 32 Mourdikoudis S, Liz-Marzán L M. Oleylamine in nanoparticle synthesis [J]. Chem Mater,2013,25(9):1465.