新型无机纳米填料改性海泡石的制备及在环氧树脂涂料中的性能

doi:10.11896/cldb.20050172

材料导报

2021, Vol. 35

Issue (12): 12057-12062 https://doi.org/10.11896/cldb.20050172

无机非金属及其复合材料

新型无机纳米填料改性海泡石的制备及在环氧树脂涂料中的性能

颜蜀雋¹, 熊海龙^2,3, 庞忠荣¹, 万鹏颖^2,3, 庄壮¹, 齐福刚^2,3

1 国家能源集团宁夏煤业有限责任公司,银川 750001
2 湘潭大学材料科学与工程学院, 湘潭 411105
3 邦泽科技有限公司,湘潭 411100

Preparation of a New Type of Inorganic Nanofiller Modified Sepiolite and Its Performance in Epoxy Resin Coating

YAN Shujun¹, XIONG Hailong^2,3, PANG Zhongrong¹, WAN Pengying^2,3, ZHUANG Zhuang¹, QI Fugang^2,3

1 National Energy Group Ningxia Coal Industry Co., Ltd., Yinchuan 750001, China
2 School of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, China
3 Hunan Bangzer Technology Co., Ltd, Xiangtan 411100, China

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摘要为了有效地提高环氧树脂(EP)防腐涂料的综合性能,本研究成功制备了新型无机纳米填料改性海泡石(OMSEP),将含量为0%、1%、2%、3%、4%和5%(质量分数,下同)的OMSEP纤维首次添加到纯EP防腐涂料中,并对比分析了纯EP涂料和OMSEP/EP复合涂料的综合性能。结果表明:新型无机纳米填料OMSEP的加入能有效提高纯EP涂料的综合性能,并且当OMSEP的添加量为3%时,OMSEP/EP复合涂料的附着力为1级,耐冲击性为52 kg·cm,磨耗量仅为0.01 g,在低频区(|Z|_{0.01 Hz})的阻抗模量比纯EP涂料高三个数量级,表现出最优的力学性能和耐腐蚀性能。

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	颜蜀雋
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	庄壮
	齐福刚

关键词: 海泡石硅烷偶联剂无机纳米填料环氧树脂

Abstract: In order to effectively improve the comprehensive performance of epoxy resin (EP) anti-corrosive coating, a new type of inorganic nanofiller modified sepiolite (OMSEP) was successfully prepared. Then the OMSEP fibers with a content of 0%, 1%, 2%, 3%, 4% and 5% were ad-ded to the pure epoxy resin (EP) anti-corrosive coating for the first time, and the comprehensive performance of OMSEP/EP composite coating and pure EP coating were compared and analyzed. The results show that the addition of the new inorganic nanofiller OMSEP can effectively improve the overall performance of pure EP coatings, and when the amount of OMSEP added is 3%, the adhesion of OMSEP/EP coating is level 1 and the impact resistance is 52 kg·cm, the abrasion amount is only 0.01 g, the impedance modulus in the low frequency region (|Z|_{0.01 Hz}) is three orders of magnitude higher than that of pure EP coating, showing the best mechanical properties and corrosion resistance.

Key words: OMSEP silane coupling agent inorganic nanofiller epoxy resin

出版日期: 2021-06-25 发布日期: 2021-07-01

ZTFLH:

TQ637

基金资助: 宁夏回族自治区宁东基地科技创新发展专项(2019NDKJLX0008);国家自然科学基金(51701172)

通讯作者: xionghailong1994@163.com;qifugang@xtu.edu.cn

作者简介: 颜蜀雋,国家能源集团宁夏煤业有限责任公司煤炭化学工业技术研究院高级工程师。主要从事催化转化及过程强化领域创新工作,参与国家、省部级科研项目10项,授权专利9项。
熊海龙,湖南邦泽科技有限公司工程师,目前主要从事重防腐涂料等相关方向的研究。
齐福刚,湘潭大学材料科学与工程学院副教授。2004年9月至2013年1月,在重庆大学获得材料科学与工程专业工学学士学位和材料科学与工程专业工学博士学位。以第一作者在国内外学术期刊上发表论文10余篇,申请国家发明专利20项,其中授权6项。同时担任多个学术期刊的审稿人。研究方向主要为重防腐涂料及镁合金新材料,主持包括国家自然科学基金青年项目、中国博士后科学基金面上项目、中央高校基本科研业务费项目等。

引用本文:

颜蜀雋, 熊海龙, 庞忠荣, 万鹏颖, 庄壮, 齐福刚. 新型无机纳米填料改性海泡石的制备及在环氧树脂涂料中的性能[J]. 材料导报, 2021, 35(12): 12057-12062.
YAN Shujun, XIONG Hailong, PANG Zhongrong, WAN Pengying, ZHUANG Zhuang, QI Fugang. Preparation of a New Type of Inorganic Nanofiller Modified Sepiolite and Its Performance in Epoxy Resin Coating. Materials Reports, 2021, 35(12): 12057-12062.

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http://www.mater-rep.com/CN/10.11896/cldb.20050172 或 http://www.mater-rep.com/CN/Y2021/V35/I12/12057

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