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材料导报  2021, Vol. 35 Issue (6): 6200-6205    https://doi.org/10.11896/cldb.19120098
  高分子与聚合物基复合材料 |
白炭黑负载抗氧剂在天然橡胶中的分散性及防老化作用
熊亚1, 江猛1, 李宜航1, 吴江兵1, 杨航1, 熊玉竹1,2
1 贵州大学材料与冶金学院,贵阳 550025
2 贵州省橡胶复合材料工程实验室,贵阳 550025
Dispersibility of Silica-loaded Antioxidant in Natural Rubber and Its Anti-aging Function
XIONG Ya1, JIANG Meng1, LI Yihang1, WU Jiangbing1, YANG Hang1, XIONG Yuzhu1,2
1 College of Materials and Metallurgy, Guizhou University,Guiyang 550025, China
2 Guizhou Province Engineering Laboratory for Rubber Composites, Guizhou University, Guiyang 550025, China
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摘要 将抗氧剂4-[(4,6-二辛硫基-1,3,5-三嗪-2-基)氨基]-2,6-二叔丁基苯酚(抗氧剂565)负载在白炭黑(SiO2-565)或经双(二辛氧基焦磷酸酯基)乙撑钛酸酯和三乙醇胺的螯合物(NDZ-311w)改性的白炭黑(SiO2-N-565)表面,制备了白炭黑负载抗氧剂/天然橡胶复合材料,并且研究了防老SiO2在天然橡胶基体中的分散性能与其对天然橡胶复合材料的抗热氧老化性能的影响。结果表明:经NDZ-311w改性的白炭黑在橡胶基体中分散均匀,且明显提高了天然橡胶的抗老化性能,当热氧老化3 d时,SiO2-N-565/NR的断裂伸长率变化率与拉伸强度变化率分别为44.36%、48.26%,远低于未改性SiO2/NR的相应变化率(77.51%、84.35%)。
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熊亚
江猛
李宜航
吴江兵
杨航
熊玉竹
关键词:  白炭黑  天然橡胶  偶联剂  分散性  防老化    
Abstract: Antioxidant 4-[(4,6-dioctyl-1,3,5-triazine-2-yl) amino]-2,6-di-tert-butylphenol (antioxidant 565) was loaded on the surface of SiO2(SiO2-565) or SiO2 modified by NDZ-311w (SiO2-N-565) to prepare silica-loaded antioxidant/natural rubber composites. In addition, the disper-sibility of anti-aging SiO2 in natural rubber matrix and its effect on thermal-oxidative aging resistance of natural rubber composites were also stu-died. The results showed that the silica modified by NDZ-311w was evenly dispersed in the rubber matrix, and the aging resistance of natural rubber increased significantly. When the thermal oxidative aging time was three days, the change rate of elongation at break and tensile strength of SiO2-N-565/NR were 44.36% and 48.26%, respectively, which was much lower than that of unmodified rubber (77.51%, 84.35%).
Key words:  silica    natural rubber    coupling agent    dispersibility    anti-aging
               出版日期:  2021-03-25      发布日期:  2021-03-23
ZTFLH:  TQ332  
基金资助: 国家自然科学基金(51663003);贵州省科技计划项目(20192166)
通讯作者:  xyzhu789@126.com   
作者简介:  熊亚,贵州大学硕士研究生,主要研究方向为聚合物复合材料的结构与性能。
熊玉竹,博士,毕业于四川大学,教授,博士研究生导师, 主要研究方向为聚合物复合材料的结构与性能。
引用本文:    
熊亚, 江猛, 李宜航, 吴江兵, 杨航, 熊玉竹. 白炭黑负载抗氧剂在天然橡胶中的分散性及防老化作用[J]. 材料导报, 2021, 35(6): 6200-6205.
XIONG Ya, JIANG Meng, LI Yihang, WU Jiangbing, YANG Hang, XIONG Yuzhu. Dispersibility of Silica-loaded Antioxidant in Natural Rubber and Its Anti-aging Function. Materials Reports, 2021, 35(6): 6200-6205.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19120098  或          http://www.mater-rep.com/CN/Y2021/V35/I6/6200
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