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材料导报  2020, Vol. 34 Issue (20): 20070-20075    https://doi.org/10.11896/cldb.19070159
  金属与金属基复合材料 |
热处理对Mg-11Gd-3Y-0.6Ca-0.5Zr合金显微组织和腐蚀行为的影响
张帅1, 李全安1,2, 朱宏喜1,2, 陈晓亚1,3, 王颂博1, 关海昆1
1 河南科技大学材料科学与工程学院,洛阳 471023
2 有色金属新材料与先进加工技术省部共建协同创新中心,洛阳 471023
3 西安理工大学材料科学与工程学院,西安 740048
Effect of Heat Treatment Process on Microstructure and Corrosion Behavior of Mg-11Gd-3Y-0.6Ca-0.5Zr Alloy
ZHANG Shuai1, LI Quan’an1,2, ZHU Hongxi1,2, CHEN Xiaoya1,3, WANG Songbo1, GUAN Haikun1
1 School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, China
2 Provincial and Ministerial Co-construction of Collaborative Innovation Center for Non-ferrous Metal New Materials and Advanced Processing Technology, Henan Province, Luoyang 471023, China
3 School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 740048, China
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摘要 本工作以Mg-11Gd-3Y-0.6Ca-0.5Zr合金为研究对象,对其进行固溶和时效热处理。采用金相显微镜、带能谱的扫描电镜、X射线衍射仪对热处理前后及腐蚀后合金的显微组织和物相进行分析,并采用静态失重法、电化学测试方法研究了热处理前后合金的耐腐蚀性。结果表明:合金铸态组织由α-Mg基体和沿晶分布的粗大共晶相Mg5Gd、Mg24Y5和Mg2Ca组成,经固溶时效后,共晶相种类没有改变,但第二相变得细小、弥散,呈颗粒状和短棒状均匀分布在基体上。在3.5%(质量分数)NaCl溶液中,热处理显著提高了合金的耐蚀性,其中,时效态合金的腐蚀速率最小,自腐蚀电位最高,腐蚀电流密度最小,合金的耐蚀性最好,表现为轻微的均匀腐蚀,其次为固溶态、铸态。合金表面的腐蚀产物主要为Mg(OH)2
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张帅
李全安
朱宏喜
陈晓亚
王颂博
关海昆
关键词:  Mg-11Gd-3Y-0.6Ca-0.5Zr  固溶  时效  显微组织  腐蚀    
Abstract: In this paper, Mg-11Gd-3Y-0.6Ca-0.5Zr alloy was taken as the research object, and solid solution and aging heat treatment are performed. Metallographic microscope, scanning electron microscope with energy spectrum, X-ray diffractometer were used to analyze the microstructure and phase of the alloy before and after heat treatment and corrosion, and the static weight loss method and electrochemical test method were used to study the corrosion resistance of the alloy before and after heat treatment. The results show that the as-cast microstructure of the alloy is composed of α-Mg matrix and the coarse eutectic phases Mg5Gd, Mg24Y5 and Mg2Ca, which are distributed along the grain. In 3.5wt% NaCl solution, heat treatment significantly improves the corrosion resistance of the alloy. Among them, the corrosion rate of the aging alloy is the lo-west, the self-corrosion potential is the highest, the corrosion current density is the lowest, and the corrosion resistance of the alloy is the best, followed by the solid solution state and the casting state. The corrosion products on the surface of the alloy are mainly Mg(OH)2.
Key words:  Mg-11Gd-3Y-0.6Ca-0.5Zr    solid solution    aging    microstructure    corrosion
               出版日期:  2020-10-25      发布日期:  2020-11-06
ZTFLH:  TG146.2  
基金资助: 国家自然科学基金(51571084; 51171059)
通讯作者:  q-ali@163.com   
作者简介:  张帅,河南科技大学,硕士研究生。主要从事高性能镁合金的设计与开发。
李全安,河南科技大学,教授。目前主要从事稀土功能材料、稀土镁合金、稀土铝合金、稀土表面改性等研究。主持国家自然科学基金、河南省杰出人才基金、河南省杰出青年基金等项目10余项。发表研究论文300余篇,获国家发明专利授权20余项。
引用本文:    
张帅, 李全安, 朱宏喜, 陈晓亚, 王颂博, 关海昆. 热处理对Mg-11Gd-3Y-0.6Ca-0.5Zr合金显微组织和腐蚀行为的影响[J]. 材料导报, 2020, 34(20): 20070-20075.
ZHANG Shuai, LI Quan’an, ZHU Hongxi, CHEN Xiaoya, WANG Songbo, GUAN Haikun. Effect of Heat Treatment Process on Microstructure and Corrosion Behavior of Mg-11Gd-3Y-0.6Ca-0.5Zr Alloy. Materials Reports, 2020, 34(20): 20070-20075.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19070159  或          http://www.mater-rep.com/CN/Y2020/V34/I20/20070
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