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材料导报  2019, Vol. 33 Issue (23): 3862-3875    https://doi.org/10.11896/cldb.18120017
  材料与可持续发展(二)――材料绿色制造与加工* |
电子封装无铅软钎焊技术研究进展
姜楠1, 张亮1,2, 熊明月1, 赵猛1, 徐恺恺1
1 江苏师范大学机电工程学院,徐州 221116
2 哈尔滨工业大学先进焊接与连接国家重点实验室,哈尔滨 150001
Research Progress on Lead-free Soldering Technology for Electronic Packaging
JIANG Nan1, ZHANG Liang1,2, XIONG Mingyue1, ZHAO Meng1, XU Kaikai1
1 School of Mechatronic Engineering, Jiangsu Normal University, Xuzhou 221116
2 State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001
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摘要 软钎焊技术被广泛应用于电子封装领域,可实现电子封装器件与材料之间的互连。SnPb钎料因其良好的润湿性能、焊接性能和合适的价格,一直是电子封装领域中使用较为普遍的钎焊材料。但是,Pb是一种会对人体和环境造成伤害的元素。随着人们环保意识的增强,铅的使用受到了极大的限制,无铅钎料取代SnPb钎料是钎料发展的必然趋势,加速了软钎焊技术向无铅化发展的进程。
在钎焊时,助焊剂的性能决定了焊接的效率和质量,因此选择合适的助焊剂是关键。目前,国内外研究学者对无铅软钎焊进行了大量研究,并取得了丰富的成果,例如:通过合金化、颗粒强化等方法研发出多种新型无铅钎料;美、日、欧三方分别发布了无铅钎料和无铅软钎焊发展指南;研发出多种无铅免清洗型助焊剂。因此,基于软钎焊技术的基础研究和应用开发体系已经成熟。应用较为广泛的软钎焊技术有三种,包括波峰焊、回流焊和半导体激光焊。波峰焊一般应用于混合组装方面,回流焊主要应用于表面贴装方面。作为群焊工艺的半导体激光焊经常应用于印刷电路板上焊接电子元件、片状元件的组装等方面。随着电子产品逐渐向小型化和多功能化的方向发展,对连接可靠性的要求越来越高,但基于无铅软钎焊技术的研究和应用开发仍显不足。
本文针对电子封装无铅软钎焊技术,探讨了软钎焊技术的研究进展和发展方向。首先,对无铅钎料、助焊剂的种类和组成进行介绍。然后针对无铅化带来的Sn和Cu界面反应的问题,通过Cu基板提出了基板合金化、对基板进行退火处理和化学镀三种解决措施。最后重点阐述了回流焊、波峰焊和半导体激光焊及其应用,为研究电子封装无铅软钎焊技术提供了进一步的理论基础。
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姜楠
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熊明月
赵猛
徐恺恺
关键词:  电子封装  颗粒强化  微合金化  无铅软钎焊  助焊剂    
Abstract: Soldering technology is widely used in the field of electronic packaging to enable interconnection between electronic packaging devices and materials. SnPb solder has been a commonly used brazing material in the field of electronic packaging due to its good wetting properties, solderability and suitable price. However, Pb is an element that causes harm to the human body and the environment. With the increasing awareness of environmental protection, the use of lead has been greatly restricted. The replacement of SnPb solder by lead-free solder is an inevitable trend in the development of solder, accelerating the lead-free process of soldering technology.
When brazing, the performance of the flux determines the efficiency and quality of the solder, so choosing the right flux is key. At present, domestic and foreign research scholars have done a lot of research on lead-free soldering, and have achieved rich results, such as the development of a variety of new lead-free solder by alloying, particle strengthening and other methods; the United States, Japan and Europe have released development guide for lead-free solder and lead-free soldering; development of a variety of lead-free no-clean fluxes. Therefore, basic research and application development systems based on soldering technology have matured. There are three widely used soldering techniques, including wave soldering, reflow soldering, and semiconductor laser soldering.Wave soldering is generally used in hybrid assembly, and reflow soldering is mainly used in surface mount. Semiconductor laser welding as a group welding process is often applied to soldering electronic components and assembly of chip components on a printed circuit board. With the gradual development of electronic products in the direction of miniaturization and multi-functionality, the requirements for connection reliability are getting higher and higher, but the research and application development based on sol-dering technology is still insufficient.
In this paper, the research progress and development direction of soldering technology are discussed for the lead-free soldering technology of selectronic packaging. First, introduce the types and composition of lead-free solders and fluxes. Then, for the problem of the interface reaction between Sn and Cu brought by lead-free, three kinds of solutions for substrate alloying, annealing treatment and electroless plating are proposed through Cu substrate. Finally, the reflow, wave soldering and semiconductor laser welding and their applications are elaborated, which provides a further theoretical basis for the study of lead-free soldering technology for electronic packaging.
Key words:  electronic packaging    particle strengthening    microalloying    lead-free soldering    flux
               出版日期:  2019-12-10      发布日期:  2019-09-30
ZTFLH:  TG425  
基金资助: 国家自然科学基金(51475220);中国博士后科学基金(2016M591464);江苏省“六大人才高峰”资助项目(XCL-022);江苏省“青蓝工程”中青年学术带头人计划资助;先进焊接与连接国家重点实验室开放课题重点项目(AWJ-19Z04);江苏师范大学研究生科研创新计划项目(2019XKT161)
作者简介:  姜楠,2018年6月毕业于江苏师范大学科文学院,获得工学学士学位。现为江苏师范大学机电工程学院硕士研究生,在张亮教授的指导下进行研究。目前主要研究领域为微电子封装材料与技术。
张亮,江苏师范大学机电工程学院教授、硕士生导师。2006年7月毕业于南昌航空大学获材料成型与控制工程学士学位,2011年5月毕业于南京航空航天大学,获材料加工工程专业博士学位。2013年4月至2014年7月作为公派访问学者至美国加州大学洛杉矶分校电子薄膜实验室从事访问研修。主要从事电子封装技术、3D封装芯片堆叠、无铅钎料及互连技术、焊点可靠性、钎焊材料与技术等领域的研究。发表论文100余篇,其中SCI收录70余篇。
引用本文:    
姜楠, 张亮, 熊明月, 赵猛, 徐恺恺. 电子封装无铅软钎焊技术研究进展[J]. 材料导报, 2019, 33(23): 3862-3875.
JIANG Nan, ZHANG Liang, XIONG Mingyue, ZHAO Meng, XU Kaikai. Research Progress on Lead-free Soldering Technology for Electronic Packaging. Materials Reports, 2019, 33(23): 3862-3875.
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http://www.mater-rep.com/CN/10.11896/cldb.18120017  或          http://www.mater-rep.com/CN/Y2019/V33/I23/3862
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