感应加热40Cr表面Cr-Al共渗组织及其性能分析

doi:10.11896/cldb.18040083

材料导报

2019, Vol. 33

Issue (21): 3552-3555 https://doi.org/10.11896/cldb.18040083

材料与可持续发展（二）――材料绿色制造与加工^*

感应加热40Cr表面Cr-Al共渗组织及其性能分析

胡建军^1,2, 张雨晴¹, 郭宁³, 杨显¹, 李晖¹, 金艳²

1 重庆理工大学材料科学与工程学院,重庆 400054
2 模具技术重庆市高校市级重点实验室,重庆 400054
3 西南大学材料与能源学院,重庆 400715

Microstructures and Properties of Chromaluminized Layer on 40Cr Steelby Induction Heating

HU Jianjun^1,2, ZHANG Yuqing¹, GUO Ning³, YANG Xian¹, LI Hui¹, JIN Yan²

1 College of Material Science and Engineering, Chongqing University of Technology, Chongqing 400054
2 Mould Technology Chongqing Municipal Key Laboratory of Institutions of Higher Education, Chongqing 400054
3 Faculty of Materials and Energy, Southwest University, Chongqing 400715

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摘要以40Cr为基材,利用电磁感应加热方式制备了Cr-Al共渗层,并对其进行了组织表征和性能测试。对比了感应加热Cr-Al共渗工艺和传统箱式炉加热Cr-Al共渗工艺,并探讨了感应加热Cr-Al共渗机理。实验结果表明,感应加热与箱式炉加热制得的Cr-Al共渗层的物相差异明显,感应加热后的主要产物为FeCr相;箱式炉加热后的主要产物为FeAl相,且氧化物较多。感应加热方式的扩散效率更高,渗层更厚,层厚约362 μm,渗层与基体的结合部分为合金珠光体与贫碳层;箱式炉加热制得的渗层厚度约为20 μm,渗层和基体交界处存在富碳区。Cr-Al共渗层能提高基体材料在H₂SO₄、Na₂SO₄混合水溶液中的耐腐蚀性,且感应加热制得的Cr-Al共渗试样的耐NaCl腐蚀性远优于箱式炉加热制得的Cr-Al共渗试样与基体材料的耐NaCl腐蚀性。

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关键词: 感应加热 Cr-Al共渗热扩渗组织耐腐蚀性

Abstract: Chromaluminized layer was prepared by electromagnetic induction heating on the surface of the 40Cr steel. The microstructures and properties were carried out and compared with the traditional box type furnace. The difference between both processes and the mechanism of induction heating chromaluminizing were discussed. The results show that, the above two processes produced different phases. The induction heating layer is mainly composed of FeCr phase, while the box type furnace heating layer mainly presents FeAl phase and has more oxides. Induction heating has faster diffusion rate and thicker layer depth which is about 362 μm, and the bonding part between the layer and substrate is alloy pearlite accompanied by carbon deficiency. However, the thickness of the box type furnace layer is only 20 μm, and there is a rich carbon zone at the interface of the substrate and layer. Both chromaluminized layers can improve the corrosion resistance in the mixed aqueous solution of H₂SO₄ and Na₂SO₄. Induction heating chromaluminized layer also indicates an improved corrosion resistance in NaCl compared with the box type furnace sample and substrate.

Key words: induction heating chromaluminizing thermal diffusion microstructure corrosion resistance

出版日期: 2019-11-10 发布日期: 2019-09-12

ZTFLH:

TB31

基金资助: 国家自然科学基金(51575073); 国家国际合作专项(2015DFR70480); 重庆市科委资助(cstc2014gjhz70003;cstc2017jcyjBX0031); 重庆高校创新团队建设计划资助(CXTDG20162017)

作者简介: 胡建军,重庆理工大学教授。主要从事齿轮表面工程新技术、模具CAD/CAM方向研究。主持国家自然科学基金面上项目1项,重庆市级项目6项。参与国家国际合作专项等重大项目20余项;发表论文80余篇,获得授权专利25项,其中发明专利7项,公开出版教材3部。获得重庆市科技进步奖2项。

引用本文:

胡建军, 张雨晴, 郭宁, 杨显, 李晖, 金艳. 感应加热40Cr表面Cr-Al共渗组织及其性能分析[J]. 材料导报, 2019, 33(21): 3552-3555.
HU Jianjun, ZHANG Yuqing, GUO Ning, YANG Xian, LI Hui, JIN Yan. Microstructures and Properties of Chromaluminized Layer on 40Cr Steelby Induction Heating. Materials Reports, 2019, 33(21): 3552-3555.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.18040083 或 http://www.mater-rep.com/CN/Y2019/V33/I21/3552

1 Hu J J, Ma C C, Xu H B, et al. Science and Technology of Nuclear Installations, DOI:10.1155/2016/5852328.
2 Ke W, Gao N W, Li M, et al. Journal of NanJing Tech University (Natural Science Edition), 2010, 32(6), 45(in Chinese).
柯威, 高能文, 李梅, 等. 南京工业大学学报(自然科学版), 2010, 32(6), 45.
3 Guo C J, Chen J S, Li J J, et al.Heat Treatment of Metals, 2017, 42(5), 108(in Chinese).
郭诚君, 陈金水, 李家节, 等. 金属热处理, 2017, 42(5), 108.
4 Sheng C S, Li X T, Chao J R, et al.Corrosion & Protection in Petrochemical Industry, 2010, 27(6), 52(in Chinese).
盛长松, 李选亭, 晁君瑞, 等. 石油化工腐蚀与防护, 2010, 27(6), 52.
5 Li W C. Studies on formation and oxidantion behavior of Al-Cr alloy coa-ting. Master's Thesis, Zhejiang University, China, 2011 (in Chinese).
李文川. Al-Cr合金涂层的制备及氧化行为研究. 硕士学位论文, 浙江大学, 2011.
6 Jin P, Xu G, Tazawa M, et al. Journal of Vacuum Science & Technology A Vacuum Surfaces & Films, 2002, 20(6), 2134.
7 Wu D L, Jiang S M, Fan Q X, et al. Acta Metallurgica Sinica, 2014, 50(10), 1170(in Chinese).
吴多利, 姜肃猛, 范其香, 等. 金属学报, 2014, 50(10), 1170.
8 Li J H.Heavy Castings and Forgings, 2004(1), 50(in Chinese).
李旌海. 大型铸锻件, 2004 (1), 50.
9 Zhang R M.Industrial Furnace, 2000, 22(4), 15(in Chinese).
张汝淼. 工业炉, 2000, 22(4), 15.
10 Zhang J X, Zhang G L.Heat Treatment, 2011, 26(6), 21(in Chinese).
张家雄, 张国梁. 热处理, 2011, 26(6), 21.
11 Zhao M, Xu L F, Chen F.China Metal Forming Equipment & Manufacturing Technology, 2006, 41(3), 33(in Chinese).
赵敏, 许雷峰, 陈峰. 锻压装备与制造技术, 2006, 41(3), 33.
12 Hu J J, Ma C P, Yang X, et al. Journal of Materials Engineering and Performance, 2017, 26(11), 5530.
13 Zeng M Q, Meng J L.Heat Treatment of Metals, 2000(8), 18(in Chinese).
曾美琴, 蒙继龙. 金属热处理, 2000(8), 18.
14 Tong F L. The study on high temperature oxidation resistance of coating on GH586 nickel base superalloy prepared by pack cementation process. Master's Thesis, Jiangsu University, China, 2017 (in Chinese).
童福利. GH586镍基高温合金包埋渗涂层的抗高温氧化性能研究. 硕士学位论文, 江苏大学, 2017.
15 Godlewska E, Godlewski K. Oxidation of Metals, 1984,22,117.
16 Medyukh R M, Medyukh V K, Uvarova I V. Powder Metallurgy & Metal Ceramics, 2018, 56(1), 1.
17 Chi C Z. Research of middle temperature chromizing on carbon steel with double glow plasma surface alloying process and carbon migration in the chromized layer. Ph.D. Thesis, Taiyuan University of Technology, China, 2004 (in Chinese).
池成忠. 碳钢表面中温双辉等离子渗铬合金化及渗层中碳迁移的研究. 博士学位论文, 太原理工大学, 2004.
18 Hu J J, Zhang Y Q, Yang X, et al. Surface & Coatings Technology, 2018, 344, 656.
19 Gao X X, Guo J Z, Zhang H B.Materials Review B:Research Papers, 2017, 31(3), 93(in Chinese).
高心心, 郭建章, 张海兵. 材料导报:研究篇, 2017, 31(3), 93.

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