反铁磁Fe3BO6中自发交换偏置效应调控研究

doi:10.11896/cldb.25010021

材料导报

2026, Vol. 40

Issue (3): 25010021-5 https://doi.org/10.11896/cldb.25010021

无机非金属及其复合材料

反铁磁Fe₃BO₆中自发交换偏置效应调控研究

王立峰^1,†, 何璐^1,†, 梁又元², 孙佳伟¹, 蔡玲¹, 李世琦¹, 何雄^1,*, 许云丽¹, 夏正才², 潘礼庆¹

1 三峡大学数理学院,湖北省弱磁探测工程技术研究中心,湖北宜昌 443002
2 华中科技大学国家脉冲强磁场科学中心,武汉 430074

Modulation of Spontaneous Exchange Bias in Antiferromagnetic Fe₃BO₆

WANG Lifeng^1,†, HE Lu^1,†, LIANG Youyuan², SUN Jiawei¹, CAI Ling¹, LI Shiqi¹, HE Xiong^1,*, XU Yunli¹, XIA Zhengcai², PAN Liqing¹

1 Hubei Engineering Research Center of Weak Magnetic-field Detection, College of Science, China Three Gorges University, Yichang 443002, Hubei, China
2 Wuhan National High Magnetic Field Center, Huazhong University of Science and Technology, Wuhan 430074, China

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摘要交换偏置场的连续可调性对于交换偏置效应的广泛应用至关重要。本工作在Fe₃BO₆多晶样品中发现了显著的自发交换偏置(SEB)效应,并通过控制退火温度对其进行了连续调控。自发交换偏置场H_SEB对退火温度表现出明显的双相响应,即随着退火温度的升高,H_SEB先升高后降低。在1 023 K退火温度下,H_SEB的最大值达到约4.024×10⁶/(4π) A/m。分析认为,H_SEB的退火温度依赖特性源于Fe₃BO₆表面态弱铁磁性和Fe₃BO₆体态反铁磁性之间交换耦合强度的调控。本研究成果有助于将基于SEB效应的器件性能调控至预期值。

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	王立峰
	何璐
	梁又元
	孙佳伟
	蔡玲
	李世琦
	何雄
	许云丽
	夏正才
	潘礼庆

关键词: 反铁磁材料 Fe₃BO₆ 自发交换偏置效应交换耦合表面态

Abstract: The continuous modularity of the exchange bias field is crucial to the wide application of the corresponding exchange bias effect. In this work, we found a giant spontaneous exchange bias (SEB) effect in the Fe₃BO₆ polycrystal samples and modulated it by controlling the annealing temperature. The spontaneous exchange bias field H_SEB exhibits an obvious biphasic response to the annealing temperature, i.e., increasing first and then decreasing with increasing the annealing temperature. The maximum value of the H_SEB reaches up to approximately 4.024×10⁶/(4π) A/m at 1 023 K annealing temperature. Analysis and discussions of the mechanism demonstrate that the annealing temperature-dependent H_SEB property originated from the modulation of the strength of the exchange coupling between the weak ferromagnetism of the surface state and the antiferromagnetism of the bulk state. This study will facilitate the efficient attainment of the desired value for specific devices designed following the SEB effect.

Key words: antiferromagnetic material Fe₃BO₆ spontaneous exchange bias effect exchange coupling surface state

发布日期: 2026-02-13

ZTFLH:

O469

基金资助: 湖北省自然科学基金项目青年项目(2024AFB333);宜昌市自然科学研究项目(A24-3-021);国家自然科学基金(12274258);国家重点研发计划(2023YFA1406500;2022YFA1602701)

通讯作者: ^*何雄,三峡大学数理学院校聘副教授、硕士研究生导师。研究工作主要集中在磁学研究领域,聚焦电磁输运性能及器件设计,另外在热电磁功能材料、反铁磁材料、拓扑半金属材料等的电、热、磁耦合输运性能及其器件设计等方面也开展了大量的前沿工作。

作者简介: 王立峰,三峡大学数理学院硕士研究生,在何雄校聘副教授和潘礼庆教授的指导下进行研究。目前主要研究领域为磁性功能材料。
何璐,三峡大学数理学院硕士研究生,在许云丽副教授的指导下进行研究。目前主要研究领域为反铁磁材料。
^†共同第一作者

引用本文:

王立峰, 何璐, 梁又元, 孙佳伟, 蔡玲, 李世琦, 何雄, 许云丽, 夏正才, 潘礼庆. 反铁磁Fe₃BO₆中自发交换偏置效应调控研究[J]. 材料导报, 2026, 40(3): 25010021-5.
WANG Lifeng, HE Lu, LIANG Youyuan, SUN Jiawei, CAI Ling, LI Shiqi, HE Xiong, XU Yunli, XIA Zhengcai, PAN Liqing. Modulation of Spontaneous Exchange Bias in Antiferromagnetic Fe₃BO₆. Materials Reports, 2026, 40(3): 25010021-5.

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https://www.mater-rep.com/CN/10.11896/cldb.25010021 或 https://www.mater-rep.com/CN/Y2026/V40/I3/25010021

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