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材料导报  2026, Vol. 40 Issue (2): 24120127-11    https://doi.org/10.11896/cldb.24120127
  金属与金属基复合材料 |
防腐耐磨高熵合金涂层研究进展
李伟华1,2,3, 周文杰1,2,3, 宋宝睿2,3,*, 黄俊玮4
1 华北水利水电大学土木与交通学院,河南省基础设施腐蚀防控重点实验室,郑州 450046
2 河南省科学院化学研究所,郑州 450046
3 河南省科学院,郑州 450046
4 中国水利水电第十一工程局有限公司,郑州 450001
Research Progress on the Tribo- and Corrosion- Resistant High-entropy Alloy Coatings
LI Weihua1,2,3, ZHOU Wenjie1,2,3, SONG Baorui2,3,*, HUANG Junwei4
1 Henan Key Laboratory of Infrastructure Corrosion and Protection, School of Civil Engineering and Transportation, North China University of Water Resources and Electric Power, Zhengzhou 450046, China
2 Institute of Chemistry, Henan Academy of Sciences, Zhengzhou 450046, China
3 Henan Academy of Sciences, Zhengzhou 450046, China
4 China Water Conservancy and Hydropower Engineering Bureau No.11 Co., Ltd., Zhengzhou 450001, China
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摘要 在过去的20年里,作为高熵合金材料的研究热点,高熵合金涂层因比传统涂层表现出更为独特的物理化学特性,如优异的耐腐蚀性、耐磨性和良好的机械强度,而在材料科学领域引起广泛关注。本综述旨在总结当前防腐耐磨高熵合金涂层的研究进展,主要介绍高熵合金的基本概念与常用定义,分析热力学相形成准则,探讨不同制备技术(如激光熔覆、热喷涂、磁控溅射等)的工艺特点及其对高熵合金涂层微观结构和性能的影响。相对于高熵合金块体材料的制备技术,高熵合金涂层的制备方法更易实现快速冷却,使涂层倾向于形成固溶体或非晶相而具备更为优异的综合性能。通过调整合金成分和优化制备工艺参数,可显著提高高熵合金涂层的防腐和耐磨性能。最后,综述了高熵合金涂层在耐腐蚀、耐磨以及磨蚀性能方面的研究现状,分析了当前面临的机遇与挑战,并对未来研究方向及应用前景进行了展望。
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李伟华
周文杰
宋宝睿
黄俊玮
关键词:  高熵合金涂层  制备技术  腐蚀  磨损  磨蚀    
Abstract: In the past 20 years, as a research hotspot in high-entropy alloy materials, high-entropy alloy coatings have attracted widespread attention in the field of materials science due to their unique physical and chemical properties, such as excellent corrosion resistance, wear resistance, and good mechanical strength, compared to traditional coatings. This review aims to summarize the current research progress on the tribo-and corrosion-resistant high-entropy alloy coatings, introduce the basic concepts and commonly used definitions of high-entropy alloys, analyze the thermodynamic phase formation criteria, and explore the process characteristics of different preparation techniques (such as laser cladding, thermal spraying, magnetron sputtering, etc.) as well as their effects on the microstructure and properties of high-entropy alloy coatings. Compared to the preparation technology of high-entropy alloy bulk materials, the preparation method of high-entropy alloy coatings is easier to achieve rapid cooling, making the coating tend to form solid solutions or amorphous phases, which have better comprehensive performance. By adjusting the alloy composition and optimizing the preparation process parameters, the anti-corrosion and wear resistance of high-entropy alloy coatings can be significantly improved. Finally, the research status of high-entropy alloy coatings in terms of corrosion resistance, wear resistance, and abrasion resistance are summarized, and the opportunities and challenges currently faced are analyzed. The future research directions and application prospects are also discussed.
Key words:  high-entropy alloy coating    preparation technology    corrosion    wear    abrasion
出版日期:  2026-01-25      发布日期:  2026-01-27
ZTFLH:  TV47  
基金资助: 河南省省级科技研发计划联合基金“青年科学家”项目(225200810090);河南省重点研发与推广专项(科技攻关)(232102230039);河南省科学院基本科研业务费项目(230618028);河南省科学院科研启动费项目(231818023)
通讯作者:  *宋宝睿,博士,河南省科学院化学研究所助理研究员,主要从事防腐耐磨高熵合金涂层的表界面改性技术及防护机理方面的研究。mse_sophie@163.com   
作者简介:  李伟华,博士,二级教授,华北水利水电大学学术副校长,河南省科学院首席科学家,河南省基础设施腐蚀防控重点实验室主任等。国家杰出青年科学基金获得者,国家“万人计划”科技创新领军人才。主要围绕重大基础设施及工程装备的健康服役问题,致力于严酷腐蚀环境下材料劣化诱发机理、功能性防护涂层材料、腐蚀控制及防御调控新技术研究。
引用本文:    
李伟华, 周文杰, 宋宝睿, 黄俊玮. 防腐耐磨高熵合金涂层研究进展[J]. 材料导报, 2026, 40(2): 24120127-11.
LI Weihua, ZHOU Wenjie, SONG Baorui, HUANG Junwei. Research Progress on the Tribo- and Corrosion- Resistant High-entropy Alloy Coatings. Materials Reports, 2026, 40(2): 24120127-11.
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https://www.mater-rep.com/CN/10.11896/cldb.24120127  或          https://www.mater-rep.com/CN/Y2026/V40/I2/24120127
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