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材料导报  2025, Vol. 39 Issue (8): 24030019-7    https://doi.org/10.11896/cldb.24030019
  金属与金属基复合材料 |
合金钢在氯盐与硫酸盐作用下的腐蚀行为与机理
袁均相1, 刘国建1,*, 刘志勇2, 佘伟2, 张云升2,3
1 苏州科技大学土木工程学院,江苏 苏州 215011
2 东南大学材料科学与工程学院,南京 211189
3 兰州理工大学土木工程学院,兰州 730050
Corrosion Behavior and Mechanism of Alloy Steel Submitted to Chloride and Sulfate
YUAN Junxiang1, LIU Guojian1,*, LIU Zhiyong2, SHE Wei2, ZHANG Yunsheng2,3
1 School of Civil Engineering, Suzhou University of Science and Technology, Suzhou 215011, Jiangsu, China
2 School of Materials Science and Engineering, Southeast University, Nanjing 211189, China
3 School of Civil Engineering, Lanzhou University of Technology, Lanzhou 730050, China
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摘要 通过腐蚀电位、线性极化电阻、腐蚀电流密度和电化学阻抗谱分析,研究了氯盐与硫酸盐作用下预钝化合金钢在饱和Ca(OH)2混凝土模拟孔溶液中的腐蚀演变,利用Fe-Cr-H2O合金系统Pourbaix图分析,探讨了两种离子在腐蚀过程中的作用机理。研究结果表明:氯离子单独存在的情况下,合金钢腐蚀速率最高,硫酸根离子单独存在时腐蚀速率最低;而氯离子和硫酸根离子共存情况下,电化学测试结果均介于两者单独存在的结果之间。根据理论分析,提出了合金钢腐蚀过程中氯盐和硫酸盐竞争吸附-催化腐蚀两阶段反应机理模型。
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袁均相
刘国建
刘志勇
佘伟
张云升
关键词:  合金钢  腐蚀  复合侵蚀离子  氯盐  硫酸盐    
Abstract: The corrosion behavior of pre-passivated alloy steel in a saturated Ca(OH)2 simulated concrete pore solution was analyzed under the action of chlorides and sulfates through corrosion potential, linear polarization resistance, corrosion current density, and electrochemical impedance spectroscopy. By leveraging the Pourbaix diagram of the Fe-Cr-H2O alloy system, the action mechanisms of two ions in the corrosion process was investigated. Results showed that the corrosion rate of steel was the highest with chlorides only, and the lowest with sulfates only, and intermediate with both ions. Finally, based on theoretical analysis, a reaction mechanism model of the competitive adsorption and catalysis of corrosion by chlorides and sulfates in lalloy steel corrosion was proposed.
Key words:  alloy steel    corrosion    composite corrosive ions    chloride    sulfate
出版日期:  2025-04-25      发布日期:  2025-04-18
ZTFLH:  TU528  
基金资助: 国家自然科学基金(52008284)
通讯作者:  刘国建,苏州科技大学土木工程学院副教授、硕士研究生导师。主要研究方向为严酷环境下钢筋腐蚀行为与机理、结构混凝土耐久性、水泥基材料微结构表征等。liuguojian@usts.edu.cn   
作者简介:  袁均相,现为苏州科技大学土木工程学院硕士研究生,在刘国建副教授指导下进行研究。主要从事钢筋锈蚀、严酷环境下混凝土耐久性研究。
引用本文:    
袁均相, 刘国建, 刘志勇, 佘伟, 张云升. 合金钢在氯盐与硫酸盐作用下的腐蚀行为与机理[J]. 材料导报, 2025, 39(8): 24030019-7.
YUAN Junxiang, LIU Guojian, LIU Zhiyong, SHE Wei, ZHANG Yunsheng. Corrosion Behavior and Mechanism of Alloy Steel Submitted to Chloride and Sulfate. Materials Reports, 2025, 39(8): 24030019-7.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24030019  或          https://www.mater-rep.com/CN/Y2025/V39/I8/24030019
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