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材料导报  2025, Vol. 39 Issue (24): 25010122-9    https://doi.org/10.11896/cldb.25010122
  无机非金属及其复合材料 |
高熵氧化物在钠离子电池电极材料中的研究进展
蒋悦1, 肖明军1,2,*
1 兰州理工大学材料科学与工程学院,兰州 730050
2 兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室,兰州 730050
Research Progress of High-entropy Oxides in Electrode Materials for Sodium-ion Batteries
JIANG Yue1, XIAO Mingjun1,2,*
1 School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China
2 State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China
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摘要 随着能源危机和环境污染日益严重,迫切需要开发出全新的、更加环保且高效的新能源材料以缓解能源紧张的局势,并尽可能地降低传统化石能源体系对环境的影响。在众多探索的新能源材料中,钠离子电池(SIBs)因钠资源丰富和价格低廉而被广泛研究,展现出巨大的潜力。同时高熵氧化物(HEO)由于多金属氧化物效应,在能源储存与转换中得到广泛应用,其在SIBs中的应用最为广泛。然而HEO作为SIBs电极材料的综述较少,大部分研究只是聚焦于某一方面,缺乏对其全面、系统且深入的梳理与总结。基于此,本文系统地综述了HEO的基本定义、合成方法,重点分析了其在SIBs电极中的应用和性能变化。本综述可为HEO在SIBs中的发展提供方案,为促进其在SIBs中的产业化提供指导。
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蒋悦
肖明军
关键词:  高熵氧化物  钠离子电池  储钠机制  合成方法  电极材料    
Abstract: With the increasingly serious energy crisis and environmental pollution, it is urgent to develop new, more environmentally friendly and efficient new energy materials to alleviate the energy shortage and reduce the impact on the environment as much as possible. Among the many exploration directions of new energy materials, sodium-ion batteries (SIBs) have received extensive research from scholars due to the abundance and low price of sodium resources, showing great potential. At the same time, high-entropy oxides (HEOs) are widely used in energy storage and conversion due to the multi-metal oxide effect, and are most widely used in SIBs. However, there are few detailed reviews of HEO as an electrode material for SIBs. Most of the studies may only focus on a local aspect, lacking a comprehensive, systematic and in-depth review and summary. Based on this, this paper systematically reviews the basic definition and synthesis methods of HEO, and focuses on its application and performance changes in SIBs electrodes. This review provides a solution for the development of HEO in SIBs and provides guidance for promoting its industrialization in SIBs.
Key words:  high-entropy oxides    sodium-ion batteries    sodium storage mechanism    method of combining    electrode material
出版日期:  2025-12-25      发布日期:  2025-12-17
ZTFLH:  TB34  
  TM912  
基金资助: 甘肃省科技计划项目(24GRRA193);兰州市青年科技人才创新项目(2024-QN-107)
通讯作者:  *肖明军,博士,兰州理工大学材料科学与工程学院教师。目前主要从事原位TEM、离子电池、光电催化、第一性原理计算、二次资源高值化利用等方面的研究工作。xiaomj@lut.edu.cn   
作者简介:  蒋悦,兰州理工大学材料科学与工程学院硕士研究生。目前研究方向为高熵氧化物在钠离子电池和光电催化中的应用。
引用本文:    
蒋悦, 肖明军. 高熵氧化物在钠离子电池电极材料中的研究进展[J]. 材料导报, 2025, 39(24): 25010122-9.
JIANG Yue, XIAO Mingjun. Research Progress of High-entropy Oxides in Electrode Materials for Sodium-ion Batteries. Materials Reports, 2025, 39(24): 25010122-9.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25010122  或          https://www.mater-rep.com/CN/Y2025/V39/I24/25010122
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