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材料导报  2025, Vol. 39 Issue (11): 24070213-11    https://doi.org/10.11896/cldb.24070213
  无机非金属及其复合材料 |
钠离子电池关键材料的热行为研究新进展
孙文浩*, 田君, 高洪波, 刘娜, 张锟, 梁晓嫱, 王聪杰, 王浩辰
中国北方车辆研究所,北京 100072
New Development of the Thermal Behavior of Key Materials in Sodium-ion Batteries
SUN Wenhao*, TIAN Jun, GAO Hongbo, LIU Na, ZHANG Kun, LIANG Xiaoqiang, WANG Congjie, WANG Haochen
China North Vehicle Research Institute, Beijing 100072, China
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摘要 钠离子电池凭借其低成本、宽工作温度范围和高安全性等优势,在新能源产业中展现出广阔的应用前景。然而,电极材料与有机电解液在高温下的非本征安全对钠离子电池的工作稳定性造成了较大的威胁。深入研究钠离子电池关键材料的热行为,对于揭示钠离子电池的热失控机制以及指导其安全性设计具有至关重要的意义。因此,本文首先阐述了钠离子电池的热失控过程,然后系统性地归纳和讨论了钠离子电池关键材料(正极、负极和电解液)的热稳定性以及产热/产气特性,最后提出了改善钠离子电池安全性的策略,并对其未来的发展方向进行了展望。
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孙文浩
田君
高洪波
刘娜
张锟
梁晓嫱
王聪杰
王浩辰
关键词:  钠离子电池  热失控  热稳定性  电极材料  电解液    
Abstract: Sodium-ion batteries have demonstrated broad application prospects in the new energy industry due to their advantages of low cost, wide operating temperature range, and high safety. However, the non-intrinsic safety of electrode materials and organic electrolytes at high temperatures poses a significant threat to the operational stability of sodium-ion batteries. A thorough investigation into the thermal behavior of key materials in sodium-ion batteries is crucial for elucidating their thermal runaway mechanisms and guiding safety-oriented design. Therefore, this review first describes the thermal runaway process of sodium-ion batteries, then systematically summarizes and discusses the thermal stability as well as heat/gas generation characteristics of key materials (cathode, anode, and electrolyte) in sodium-ion batteries, and finally proposes stra-tegies aimed at improving the safety of sodium-ion batteries and provides an outlook on their future development directions.
Key words:  sodium-ion battery    thermal runaway    thermal stability    electrode material    electrolyte
发布日期:  2025-05-29
ZTFLH:  TB34  
基金资助: 国家自然科学基金(52075028)
通讯作者:  *孙文浩,博士,工程师。目前主要从事动力及储能电池测试评价技术的研究。563729367@qq.com   
引用本文:    
孙文浩, 田君, 高洪波, 刘娜, 张锟, 梁晓嫱, 王聪杰, 王浩辰. 钠离子电池关键材料的热行为研究新进展[J]. 材料导报, 2025, 39(11): 24070213-11.
SUN Wenhao, TIAN Jun, GAO Hongbo, LIU Na, ZHANG Kun, LIANG Xiaoqiang, WANG Congjie, WANG Haochen. New Development of the Thermal Behavior of Key Materials in Sodium-ion Batteries. Materials Reports, 2025, 39(11): 24070213-11.
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https://www.mater-rep.com/CN/10.11896/cldb.24070213  或          https://www.mater-rep.com/CN/Y2025/V39/I11/24070213
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