水系铵离子电池研究进展

doi:10.11896/cldb.25020072

材料导报

2025, Vol. 39

Issue (19): 25020072-9 https://doi.org/10.11896/cldb.25020072

无机非金属及其复合材料

水系铵离子电池研究进展

孙淑敏¹, 雷海波¹, 吕署虎¹, 王培远^1,2,*, 曹霞^1,3,*

1 郑州轻工业大学材料与化学工程学院,郑州 450001
2 郑州轻工业大学河南省表界面科学重点实验室,郑州 450001
3 环境污染治理与生态修复河南省协同创新中心,郑州 450001

Research Progress of Aqueous Ammonium-ion Batteries

SUN Shumin¹, LEI Haibo¹, LYU Shuhu¹, WANG Peiyuan^1,2,*, CAO Xia^1,3,*

1 School of Materials and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China
2 Henan Provincial Key Laboratory of Surface and Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450001, China
3 Collaborative Innovation Center of Environmental Pollution Control and Ecological Restoration of Henan Province, Zhengzhou 450001, China

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摘要近年来,电池技术在消费电子设备、新能源汽车及各类储能系统中得到广泛应用,但传统电池在使用过程中存在的安全隐患日益引发关注。相较于采用有机电解液的电池,新型水系电池凭借其独特的安全性和环保特性,逐渐成为储能领域的重要研究方向。与当前普遍研究的金属离子(如Li⁺、Na⁺、Zn²⁺)相比,NH₄⁺具有来源丰富、摩尔质量低的优势,加之其水合离子半径显著小于上述金属离子,使得水系铵离子电池(AAIBs)成为研究热点。尽管多种电极材料(包括无机与有机材料)已被开发为NH₄⁺的存储载体,并在AAIBs研究中取得了一定进展,但这些材料在实际测试与应用中仍面临诸多挑战与限制。本文系统综述了近年来AAIBs的研究进展:首先概述AAIBs的基本原理与特性,继而分别从正极材料、负极材料及电解质三个方面阐述最新成果,最后针对AAIBs的发展前景、现存问题及潜在解决方案进行总结与展望,以期为推动AAIBs及其电极材料的深入研究提供参考。

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	孙淑敏
	雷海波
	吕署虎
	王培远
	曹霞

关键词: 电化学储能水系铵离子电池电极材料电解质

Abstract: In recent years, battery technology has been widely applied in consumer electronic devices, new energy vehicles, and various energy sto-rage systems. However, the safety concerns associated with conventional batteries during usage have increasingly attracted attention. Compared to batteries using organic electrolytes, novel aqueous batteries are gradually emerging as a significant research direction in the energy sto-rage field due to their unique safety advantages and environmental benefits. In contrast to the commonly studied metal ions (such as Li⁺, Na⁺, Zn²⁺), NH₄⁺ has become a research hotspot for aqueous ammonium ion batteries (AAIBs) owing to its abundant sources, low molar mass, and significantly smaller hydrated ion radius compared to the aforementioned metal ions. Although various electrode materials (including inorganic and organic materials) have been developed as carriers for NH₄⁺ storage and some progress has been made in AAIBs research, these materials still face numerous challenges and limitations in practical testing and applications. This paper systematically reviews the recent research progress in AAIBs. It first outlines the basic principles and characteristics of AAIBs, then elaborates on the latest achievements from the perspectives of ca-thode materials, anode materials, and electrolytes, and finally summarizes and prospects the development prospects, existing problems, and potential solutions for AAIBs, aiming to provide references for promoting in-depth research on AAIBs and their electrode materials.

Key words: electrochemical energy storage aqueous ammonium-ion battery electrode material electrolyte

出版日期: 2025-10-10 发布日期: 2025-09-24

ZTFLH:

TM912.9

基金资助: 国家自然科学基金联合重点项目(U23A20579);河南省自然科学基金(242300421258);河南省重点研发与推广专项(科技攻关)(252102240010)

通讯作者: *王培远,郑州轻工业大学材料与化学工程学院副教授、硕士研究生导师。目前主要研究领域为电化学、能源转换与存储材料。peiyuanwang@zzuli.edu.cn
曹霞,郑州轻工业大学材料与化学工程学院教授、硕士研究生导师。目前主要研究领域为环境污染防治与能源规划。2020003@zzuli.edu.cn

作者简介: 孙淑敏,郑州轻工业大学材料与化学工程学院副教授、硕士研究生导师。目前主要研究领域为电化学、能源转换与存储材料。

引用本文:

孙淑敏, 雷海波, 吕署虎, 王培远, 曹霞. 水系铵离子电池研究进展[J]. 材料导报, 2025, 39(19): 25020072-9.
SUN Shumin, LEI Haibo, LYU Shuhu, WANG Peiyuan, CAO Xia. Research Progress of Aqueous Ammonium-ion Batteries. Materials Reports, 2025, 39(19): 25020072-9.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.25020072 或 https://www.mater-rep.com/CN/Y2025/V39/I19/25020072

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