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材料导报  2025, Vol. 39 Issue (15): 24050205-8    https://doi.org/10.11896/cldb.24050205
  金属与金属基复合材料 |
铜基催化剂在电催化硝酸根还原制氨中的应用
梁彩凤1,2,†, 赵港1,2,†, 吴琪1,2,*
1 西藏大学理学院,拉萨 850000
2 西藏大学西藏自治区高原制供氧与人居环境重点实验室,拉萨 850000
Application of Copper-based Catalysts in Electrocatalytic Nitrate Reduction to Ammonia
LIANG Caifeng1,2,†, ZHAO Gang1,2,†, WU Qi1,2,*
1 College of Science, Xizang University, Lhasa 850000, China
2 Tibet Key Laboratory of Plateau Oxygen and Living Environment, Xizang University, Lhasa 850000, China
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摘要 地下水硝酸盐污染成为一个关键的环境问题,对人类社会的发展造成严重威胁。电催化硝酸盐还原制氨法(NO3RR),被认为是去除各类废水中的硝酸盐有害物质并将其转化为氨的最有效途径之一,但其催化剂的研究极具挑战性。近期,Cu基催化剂因其低成本、高活性以及能有效抑制析氢副反应等特性,在促进NO3RR性能方面表现出很高的硝酸盐转化效率、氨选择性和法拉第效率。本文主要综述了Cu的金属催化剂、单原子催化剂、合金催化剂以及化合物催化剂(氧化物、氢氧化物)在NO3RR中的最新进展,详细介绍了各种改性手段的利弊以及NO3RR的转化机制,并对该领域未来的发展方向、面临的挑战和机遇进行了简要概述。
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梁彩凤
赵港
吴琪
关键词:  电催化  硝酸盐去除  氨生产  铜基催化剂    
Abstract: Nitrate contamination of groundwater has become a critical environmental issue that poses a serious threat to the development of human society. Electrocatalytic nitrate reduction to ammonia (NO3RR), is considered as one of the most effective ways to remove harmful nitrate substances from various types of wastewater and convert them to advantageous ammonia, but the research of the electrocatalysts are very challen-ging. Recently, Cu-based catalysts have shown high nitrate conversion efficiency, ammonia selectivity, and Faraday efficiency in promoting NO3RR performance due to their low cost, high activity, and ability to effectively inhibit Hydrogen evolution reaction, etc. Here we reviews the recent advances in metal catalysts for Cu, relevant single-atom, alloy, and compounds (oxides, hydroxides) catalysts in NO3RR, details the advantages and disadvantages of the various modifications as well as the conversion mechanism of NO3RR, and provides a brief overview of the future directions, challenges, and opportunities in this field.
Key words:  electrocatalysis    nitrate removal    ammonia production    copper-based catalysts
出版日期:  2025-08-10      发布日期:  2025-08-13
ZTFLH:  TQ15  
  O41  
基金资助: 基金项目:国家自然科学基金(22168036);西藏自治区科技计划项目(XZ202201YD0020C);西藏自治区自然科学基金项目重点项目(XZ202301ZR0026G)
通讯作者:  吴琪,博士,国家海外高层次人才、西藏大学理学院特聘研究员、硕士研究生导师。研究方向主要围绕计算物理和计算材料科学领域开展前瞻性、原创性问题研究,具体包括低维纳米材料的模拟与设计、高原特色环境与材料理论计算的研究工作,专注于电化学析氢制氧以及太阳能电解水制氢制氧理论研究。wuqi_zangda@163.com   
作者简介:  梁彩凤,西藏大学理学院硕士研究生,在吴琪特聘研究员的指导下进行研究。目前主要研究领域为电催化。赵港,西藏大学理学院硕士研究生,在吴琪特聘研究员的指导下进行研究。目前主要研究领域为电催化。†共同第一作者
引用本文:    
梁彩凤, 赵港, 吴琪. 铜基催化剂在电催化硝酸根还原制氨中的应用[J]. 材料导报, 2025, 39(15): 24050205-8.
LIANG Caifeng, ZHAO Gang, WU Qi. Application of Copper-based Catalysts in Electrocatalytic Nitrate Reduction to Ammonia. Materials Reports, 2025, 39(15): 24050205-8.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24050205  或          https://www.mater-rep.com/CN/Y2025/V39/I15/24050205
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