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材料导报  2026, Vol. 40 Issue (10): 25040191-6    https://doi.org/10.11896/cldb.25040191
  无机非金属及其复合材料 |
表面涂层协同离子锚定改性富锂锰基正极材料及其性能研究
张康进1,2,†, 陈槐1,2,†, 马俊1,2,*
1 贵州大学化学与化工学院,贵阳 550000
2 贵州大学贵州省绿色化工与清洁能源技术重点实验室,贵阳 550000
Preparation and Performance Study on Synergistically Modified Lithium-rich Manganese-based Cathode Material with Surface Coating and Ion Anchoring
ZHANG Kangjin1,2,†, CHEN Huai1,2,†, MA Jun1,2,*
1 College of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550000, China
2 Guizhou Provincial Key Laboratory of Green Chemical and Clean Energy Technology, Guizhou University, Guiyang 550000, China
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摘要 富锂锰基层状氧化物(LLOs)被认为是高能量密度锂离子电池的理想正极候选材料。然而,LLOs的首圈库仑效率低、容量/电压衰减、倍率和循环性能差等问题阻碍了其实际应用。大量研究表明,对LLOs进行表面改性是提升其电化学性能的有效手段。鉴于此,本工作通过聚乙烯醇(PVA)和聚丙烯酸(PAA)改性LLOs,获得表面包覆PVA与PAA交联有机涂层的LLOs(PPLLOs)。电化学性能测试表明,LLOs和PPLLOs-5在1C下循环100次后的可逆比容量分别为152.9 mAh·g-1和175.2 mAh·g-1,容量保持率分别为79%和90.5%。该性能的提升是由于有机涂层可缓解LLOs在电化学循环过程中因锂离子的反复脱嵌带来的不均匀应力积累,同时抑制界面副反应,提高LLOs的结构稳定性;氢键网络锚定了LLOs表相的过渡金属离子,抑制了LLOs中的过渡金属离子在电化学循环过程中的迁移与溶解。本工作为LLOs的表面改性提供了新的见解。
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张康进
陈槐
马俊
关键词:  富锂锰基层状氧化物(LLOs)  锂离子电池  表面改性  电化学性能    
Abstract: Lithium-rich manganese layered oxides(LLOs) are considered as ideal cathode candidates for high-energy-density lithium-ion batteries. Ho-wever, the lower initial coulombic efficiency, capacity/voltage decay, poorer rate and cycle performance of LLOs hinder their practical application. A large number of studies have shown that surface modification of LLOs is an effective means to improve the electrochemical performance of LLOs. In view of this, LLOs (PPLLOs) coated with PVA and PAA cross-linked organic coatings were obtained by modifying LLOs with polyvinyl alcohol (PVA) and polyacrylic acid (PAA). The electrochemical performance test indicates that the reversible specific capacities of LLOs and PPLLOs-5 after 100 cycles at 1C are 152.9 mAh·g-1 and 175.2 mAh·g-1, respectively, and the capacity retention rates are 79% and 90.5%, respectively. The improvement of this performance is due to the fact that the organic coating can alleviate the unevenly accumulated stress caused by the repeated deintercalation of lithium ions during the electrochemical cycle of LLOs, inhibit the interfacial side reactions, and improve the structural stability of LLOs. The hydrogen bond network anchored the transition metal ions in the surface phase of LLOs, which inhibited the migration and dissolution of transition metal ions in LLOs during the electrochemical cycle. This work provides new insights into the surface modification of LLOs.
Key words:  lithium-rich manganese layered oxides (LLOs)    lithium-ion battery    surface modification    electrochemical characteristic
发布日期:  2026-06-03
ZTFLH:  TM912  
基金资助: 贵州省科技厅计划项目(QKHJC-ZK[2022]YB088);贵州省铜仁市工信厅横向项目([2021]15)
通讯作者:  *马俊,博士,现就职于贵州大学,研究兴趣主要包括储能与转化用先进材料、功能化磁性材料的设计与应用,以及化工过程模拟计算。jma3@gzu.edu.cn   
作者简介:  †共同第一作者。张康进,贵州大学化学与化工学院硕士研究生,主要研究方向为光催化有机合成和富锂锰基正极材料。陈槐,贵州大学化学与化工学院硕士研究生,主要从事锂离子电池先进正极材料及金属空气电池的相关研究。
引用本文:    
张康进, 陈槐, 马俊. 表面涂层协同离子锚定改性富锂锰基正极材料及其性能研究[J]. 材料导报, 2026, 40(10): 25040191-6.
ZHANG Kangjin, CHEN Huai, MA Jun. Preparation and Performance Study on Synergistically Modified Lithium-rich Manganese-based Cathode Material with Surface Coating and Ion Anchoring. Materials Reports, 2026, 40(10): 25040191-6.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25040191  或          https://www.mater-rep.com/CN/Y2026/V40/I10/25040191
1 Cheng F, Liang J, Tao Z, et al. Advanced Materials, 2011, 23(15), 1695.
2 Zhu Z, Jiang T, Ali M, et al. Chemical Reviews, 2022, 122(22), 16610.
3 Xu J, Lin F, Doeff M M, et al. Journal of Materials Chemistry A, 2017, 5(3), 874.
4 Melin H E, Rajaeifar M A, Ku A Y, et al. Science, 2021, 373(6553), 384.
5 Murdock B E, Toghill K E, Tapia-Ruiz N. Advanced Energy Materials, 2021, 11(39), 2102028.
6 Zuo W, Luo M, Liu X, et al. Energy & Environmental Science, 2020, 13(12), 4450.
7 He W, Guo W, Wu H, et al. Advanced Materials, 2021, 33(50), 2005937.
8 Chen Z, Nguyen H D, Zarrabeitia M, et al. Advanced Functional Materials, 2021, 31(41), 2105343.
9 Chen Z, Kim G T, Bresser D, et al. Advanced Energy Materials, 2018, 8(27), 1801573.
10 Yan P, Zheng J, Liu J, et al. Nature Energy, 2018, 3(7), 600.
11 Yu H, Cao Y, Chen L, et al. Nature Communications, 2021, 12(1), 4564.
12 Yang H, Gao R M, Zhang X D, et al. Advanced Materials, 2022, 34(38), 2204835.
13 Mu K, Cao Y, Hu G, et al. Electrochimica Acta, 2018, 273, 88.
14 Zhang X D, Shi J L, Liang J Y, et al. Advanced Materials, 2018, 30(29), 180751.
15 Zhai X, Zhang P, Huang H, et al. Solid State Ionics, 2021, 366-367, 115661
16 Wang C, Fu X, Lin S, et al. Journal of Energy Chemistry, 2022, 64, 485.
17 Ju Z, Xie Q, Sheng O, et al. Nano Letters, 2023, 22(13), 5473.
18 Lee J H, Yeon J S, Kim J, et al. Journal of Materials Chemistry A, 2021, 9(45), 25463.
19 Qin Y, Wang X. Angewandte Chemie-International Edition, 2024, 63(2), e202315464.
20 Luo K, Roberts M R, Guerrini N, et al. Journal of the American Chemical Society, 2016, 138(35), 11211.
21 Zhang J, Wang J, Yang J, et al. Electrochimica Acta, 2014, 117, 99.
22 Sun Z, Xu L, Dong C, et al. Nano Energy, 2019, 63, 103887.
23 Jiang B, Luo B, Li J, et al. Ceramics International, 2019, 45(1), 160.
24 Zhang K, Li B, Zuo Y, et al. Electrochemical Energy Reviews, 2019, 2, 606.
25 Kim N Y, Moon J, Ryou M H, et al. Advanced Energy Materials, 2022, 12(1), 2102109.
26 Zhang H Z, Qiao Q Q, Li G R, et al. Journal of Materials Chemistry, 2012, 22(26), 13104.
27 Yu H, Kim H, Wang Y, et al. Physical Chemistry Chemical Physics, 2012, 14(18), 6584.
28 Cui C, Fan X, Zhou X, et al. Journal of the American Chemical Society, 2020, 142(19), 8918.
29 Yuan Z L, Hu B R, Liao F F, et al. Modern Chemical Research, 2025(8), 36 (in Chinese).
袁自力, 胡本睿, 廖芳芳, 等. 当代化工研究, 2025(8), 36.
30 Yu C Y, Kou P Z, Zhang Z G, et al. Nonferrous Metals, 2025, 15(2), 217 (in Chinese).
于楚瑶, 寇鹏祖, 张志贵, 等. 有色金属(中英文), 2025, 15(2), 217.
31 Liu X P, Zhao L Y, Li H Y, et al. Chinese Journal of Inorganic Chemistry, 2024, 40 (6), 1105 (in Chinese).
刘新朋, 赵刘洋, 李泓漪, 等. 无机化学学报, 2024, 40 (6), 1105.
32 Huang Y Z, Zhen W Y, Yi Z Y, et al. Materials Reports, 2026, 40(5), 25020187 (in Chinese).
黄亦聪, 郑文育, 易卓彦, 等. 材料导报, 2026, 40(5), 25020187.
33 Huang Z, Xiong T, Lin X, et al. Journal of Power Sources, 2019, 432, 8.
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