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材料导报  2026, Vol. 40 Issue (10): 25040165-13    https://doi.org/10.11896/cldb.25040165
  无机非金属及其复合材料 |
聚甲醛纤维对高性能混凝土性能提升的研究进展
马瑞1,2, 邱晶晶1, 王尔恒1, 胡慧瑛1, 胡勋1, 丁益1, 程杰1, 王爱国1, 孙道胜1,*
1 安徽建筑大学材料与化学工程学院,先进土木工程材料安徽省重点实验室,合肥 230000
2 新加坡国立大学土木与环境工程学院,新加坡 117576
Research Progress on the Properties of Polyoxymethylene Fiber Reinforced Concrete
MA Rui1,2, QIU Jingjing1, WANG Erheng1, HU Huiying1, HU Xun1, DING Yi1, CHENG Jie1, WANG Aiguo1, SUN Daosheng1,*
1 Key Laboratory of Advanced Civil Engineering Materials of Anhui Province, Department of Material and Chemical Engineering, Anhui Jianzhu University, Hefei 230000, China
2 Department of Civil and Environment Engineering, National University of Singapore, Singapore 117576
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摘要 聚甲醛(POM)具有较高的结晶度,是工程领域的一种高分子材料。近年来,该材料以环保和卓越的力学性能在高性能混凝土(HPC)领域的应用逐渐增多。但关于POM纤维增强HPC的综合性研究相对匮乏。本文对该领域的最新研究成果进行了汇总,探讨POM纤维如何影响混凝土的力学性能、耐久性和微观结构。在力学性能方面,POM纤维通过桥接裂纹和能量耗散机制,显著提升混凝土的抗压、抗弯和劈裂抗拉强度,尤其在高应变率下断裂韧性提升显著,过量纤维因界面缺陷而导致性能下降。在耐久性能方面,适量掺加POM纤维可改善混凝土耐久性,降低干燥收缩率,提高耐磨性,增强抗冻融循环能力,提高抗氯离子渗透性;高温性能方面,POM纤维在200~400 ℃时熔融形成孔隙通道,缓解蒸汽压力,但400 ℃以上纤维消失导致强度加速退化;在微观性能方面,POM纤维与基体形成致密界面,通过化学键合和摩擦作用增强界面结合力。同时,介绍了混掺纤维的性能并列出了与其相关的数学模型,对POM纤维混凝土未来的研究发展方向进行了展望。
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马瑞
邱晶晶
王尔恒
胡慧瑛
胡勋
丁益
程杰
王爱国
孙道胜
关键词:  聚甲醛纤维  高性能混凝土  纤维拔出  力学特性  耐久性    
Abstract: Polyoxymethylene (POM), as a polymer material with high crystallization degree, can be used in engineering application. Due to its environmental sustainability and outstanding mechanical properties, POM has drawn much attention in high-performance concrete (HPC) during the last decades. However, the comprehensive research on POM fiber-reinforced HPC is still limited. This summary systematically reviews the recent advances in this field, and discusses the effects of POM fibers on strength, durability, and microstructure of concrete. By the crack-bridging and energy dissipation effects, POM fibers significantly enhance the compressive, flexural, and splitting tensile strength of concrete, and the improvement on fracture toughness is particularly notable under high strain rates. However, excessive fiber content introduces more interfacial defects to decline the properties. For durability, POM fiber with optimized content can reduce drying shrinkage, and improve abrasion resistance, freeze-thaw resistance, and chloride resistance. Under high temperature, POM fiber will melt between 200—400 ℃, forming interconnected pore channels to relieve vapor pressure, but the performance deterioration is accelerated over 400 ℃. Microscopic analysis reveals that POM fiber forms a dense interfacial transition zone with the cement matrix, and strengthens the bonding through chemical interactions and frictional forces. Here also presents the properties of hybrid fibers and provides associated mathematical models, and looks forward to the future development of POM fiber-reinforced concrete.
Key words:  polyoxymethylene fiber    high-performance concrete    fiber pull-out    mechanical property    durability
发布日期:  2026-06-03
ZTFLH:  TU528  
基金资助: 国家自然科学基金青年基金 (52208227);安徽省高校优秀青年科研项目(2022AH030038);安徽省高校中青年教师培养行动项目(JWFX2023024);安徽省高校自然科学优秀科研创新团队支持计划(2022AH010017);水泥制造绿色低碳技术安徽省重点实验室开放基金项目(GLCT202402);安徽省住房城乡建设科学技术计划项目(2024-YF057)
通讯作者:  *孙道胜,博士,安徽建筑大学教授、博士研究生导师。安徽省学术与技术带头人。主要从事高性能水泥基材料、固废资源化利用与节能建材、建筑功能材料等研究。sundaosheng@163.com   
作者简介:  马瑞,博士,安徽建筑大学副教授,新加坡混凝土协会会员。主要研究领域包括超高性能水泥基材料、固废高值化利用等。
引用本文:    
马瑞, 邱晶晶, 王尔恒, 胡慧瑛, 胡勋, 丁益, 程杰, 王爱国, 孙道胜. 聚甲醛纤维对高性能混凝土性能提升的研究进展[J]. 材料导报, 2026, 40(10): 25040165-13.
MA Rui, QIU Jingjing, WANG Erheng, HU Huiying, HU Xun, DING Yi, CHENG Jie, WANG Aiguo, SUN Daosheng. Research Progress on the Properties of Polyoxymethylene Fiber Reinforced Concrete. Materials Reports, 2026, 40(10): 25040165-13.
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https://www.mater-rep.com/CN/10.11896/cldb.25040165  或          https://www.mater-rep.com/CN/Y2026/V40/I10/25040165
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