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材料导报  2026, Vol. 40 Issue (10): 25050168-11    https://doi.org/10.11896/cldb.25050168
  无机非金属及其复合材料 |
废旧锂离子电池正极材料湿法冶金回收技术研究进展
郭战永, 任祥睿, 孙静静, 冯振*
河南工学院材料科学与工程学院,河南省金属材料改性技术工程技术研究中心,河南省线缆先进材料与智能制造重点实验室,河南 新乡 453003
Research Progress on Hydrometallurgical Recycling Technology for Cathode Materials in Waste Lithium-ion Batteries
GUO Zhanyong, REN Xiangrui, SUN Jingjing, FENG Zhen*
Henan Key Laboratory of Advanced Cable Materials and Intelligent Manufacturing, Henan Engineering Research Center for Modification Technology of Metal Materials, School of Materials Science and Engineering, Henan Institute of Technology, Xinxiang 453003, Henan, China
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摘要 随着锂离子电池在电子设备、电动汽车等领域的广泛应用,废旧锂离子电池的数量急剧增加。作为锂离子电池的关键组成部分,正极材料富含锂、钴、镍、锰等有价金属,对其进行有效回收具有显著的环保及经济效益。湿法冶金技术凭借操作条件温和、金属回收率高、环境友好等优势,成为废旧锂离子电池正极材料重要的回收手段。本文聚焦废旧锂离子电池正极材料的湿法冶金回收技术,介绍了锂离子电池正极材料的结构特点,系统讨论了金属离子在浸出液中的分离与提纯技术,如沉淀法、溶剂萃取法、离子交换法等的优势与局限性。最后对废旧锂离子电池正极材料湿法冶金回收技术的发展趋势进行了展望,以期推动废旧锂离子电池正极材料回收技术的突破,助力锂离子电池产业的可持续发展。
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郭战永
任祥睿
孙静静
冯振
关键词:  废旧锂离子电池  正极材料  湿法冶金回收  回收效益    
Abstract: As the extensive application of lithium-ion batteries (LIBs) in electronic devices, electric vehicles and other fields has led to a sharp increase in the quantity of waste LIBs, the cathode materials-as a key component of LIBs that are rich in valuable metals such as lithium, cobalt, ni-ckel, and manganese-have become the focus of effective recycling for their significant environmental and economic benefits. Hydrometallurgical technology, owing to its advantages of mild operating conditions, high metal recovery rate and environmental friendliness, has emerged as an important recycling method for waste LIB cathode materials. This paper focuses on the hydrometallurgical recycling technology of waste LIB cathode materials, introduces the structural characteristics of LIB cathode materials, and systematically discusses the advantages and limitations of separation and purification technologies for metal ions in leachate, such as the precipitation method, solvent extraction method, and ion exchange method. Finally, an outlook on the development trends of hydrometallurgical recycling technology for waste LIB cathode materials is proposed, aiming to promote the breakthrough of recycling technology for waste LIB cathode materials and facilitate the sustainable development of the LIB industry.
Key words:  spent lithium-ion battery    cathode material    hydrometallurgical recycling    recycling benefit
发布日期:  2026-06-03
ZTFLH:  TG115.3  
基金资助: 河南省教育厅青年骨干教师项目(2024GGJS156);河南省线缆先进材料与智能制造重点实验室开放课题(CAMIM2025008);河南省科技攻关项目(262102241059;242102321162);河南省高等学校重点科研项目(25B480008)
通讯作者:  *冯振,博士,河南工学院材料科学与工程学院副教授。目前主要从事能量转化与存储材料的智算设计与模拟的研究。fengzhen@hait.edu.cn   
作者简介:  郭战永,博士,河南工学院材料科学与工程学院副教授、硕士研究生导师。目前主要从事新能源材料综合利用等方面的研究。
引用本文:    
郭战永, 任祥睿, 孙静静, 冯振. 废旧锂离子电池正极材料湿法冶金回收技术研究进展[J]. 材料导报, 2026, 40(10): 25050168-11.
GUO Zhanyong, REN Xiangrui, SUN Jingjing, FENG Zhen. Research Progress on Hydrometallurgical Recycling Technology for Cathode Materials in Waste Lithium-ion Batteries. Materials Reports, 2026, 40(10): 25050168-11.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25050168  或          https://www.mater-rep.com/CN/Y2026/V40/I10/25050168
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