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材料导报  2026, Vol. 40 Issue (9): 25030244-6    https://doi.org/10.11896/cldb.25030244
  无机非金属及其复合材料 |
绿茶与PVP制备碳纳米管导电浆料及应用于锂离子电池性能的研究
龚泽晖, 张涵, 马青青, 陈海龙*
青岛科技大学机电工程学院,山东 青岛 266061
Preparation of Carbon Nanotube Conductive Paste from Green Tea and PVP and ItsApplication to Lithium-ion Batteries
GONG Zehui, ZHANG Han, MA Qingqing, CHEN Hailong*
School of Electromechanical Engineering, Qingdao University of Science and Technology, Qingdao 266061, Shandong, China
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摘要 导电浆料在锂电池等领域应用广泛,碳纳米管制备的导电浆料因良好的热稳定性、导电性等优势备受关注,但碳纳米管易团聚,影响其性能发挥。本工作旨在解决该问题,尝试用绿茶与聚乙烯吡咯烷酮(PVP)混合分散碳纳米管,并应用于锂离子电池。实验制备了不同绿茶浓度的碳纳米管导电浆料,利用SEM、动态光散射(DLS)、拉曼光谱等手段进行表征,测试其在锂离子电池中的电化学性能。结果表明,当绿茶添加量为4 g时,其与PVP混合对碳纳米管的分散效果最佳。此时碳纳米管平均直径最小,为203.68 nm,拉曼光谱中G峰、D峰强度之比(IG/ID)最高(0.973 6),分散稳定性好,且所得电极片电阻率最低(0.091 Ω·cm)。将该浆料用于锂离子电池后,电池电荷转移电阻和Warburg阻抗低,0.1C放电比容量达130.2 mAh/g,高于仅使用PVP分散时的127.1 mAh/g,而且100次循环后比容量为129.8 mAh/g,放电容量保持率达99.8%,倍率性能和循环性能优异。本工作的成果表明,绿茶与PVP混合分散碳纳米管在锂离子电池领域具有潜在应用价值。
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龚泽晖
张涵
马青青
陈海龙
关键词:  绿茶  碳纳米管  导电浆料  锂离子电池  电化学性能    
Abstract: Conductive pastes are widely used in lithium batteries and other fields, and the conductive pastes prepared from carbon nanotubes have attracted much attention because of their good thermal stability, electrical conductivity, and other advantages, but the carbon nanotubes are prone to agglomeration, which affects their performance. This study aims to solve this problem and tries to disperse carbon nanotubes with green tea mixed with polyvinylpyrrolidone (PVP) and applied to lithium-ion batteries. Carbon nanotube conductive pastes with different green tea concentrations were prepared and characterized by SEM, DLS, and Raman spectroscopy to test their electrochemical performance in lithium-ion batteries. The results show that when the green tea addition is 4 g, its mixing with PVP has the best dispersion effect on carbon nanotubes. At this time, the carbon nanotubes had the smallest average diameter of 203.68 nm, the highest IG/ID ratio in the Raman spectrum (0.973 6), good dispersion stability, and the lowest resistivity of the resulting electrode sheet (0.091 Ω·cm). After the paste was used in lithium-ion batteries, the battery charge transfer resistance and Warburg impedance were low, and the specific capacity of 0.1C discharge reached 130.2 mAh/g, which was higher than that of 127.1 mAh/g when PVP was dispersed alone, and the specific capacity was 129.8 mAh/g after 100 cycles, with a discharge capacity retention of 99.8%, which was excellent in multiplicity performance and cycling performance. This suggests that the mixed dispersion of green tea and PVP carbon nanotubes has potential application in the field of lithium-ion batteries.
Key words:  green tea    carbon nanotubes    conductive paste    lithium-ion battery    electrochemical property
收稿日期:  2026-05-10      出版日期:  2026-05-10      发布日期:  2026-05-18
ZTFLH:  TM912.9  
基金资助: 山东省自然科学基金(ZR2019BEE022)
通讯作者:  *陈海龙,博士,讲师,硕士研究生导师,主要从事橡胶纳米复合材料制备工艺及性能研究、碳纳米材料导电浆料制备工艺、性能及应用研究等方面的科研工作。chlqust@163.com   
作者简介:  龚泽晖,青岛科技大学硕士研究生,在陈海龙导师的指导研究碳纳米管导电浆料的制备及在锂离子电池中的应用。
引用本文:    
龚泽晖, 张涵, 马青青, 陈海龙. 绿茶与PVP制备碳纳米管导电浆料及应用于锂离子电池性能的研究[J]. 材料导报, 2026, 40(9): 25030244-6.
GONG Zehui, ZHANG Han, MA Qingqing, CHEN Hailong. Preparation of Carbon Nanotube Conductive Paste from Green Tea and PVP and ItsApplication to Lithium-ion Batteries. Materials Reports, 2026, 40(9): 25030244-6.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25030244  或          https://www.mater-rep.com/CN/Y2026/V40/I9/25030244
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