Please wait a minute...
材料导报  2026, Vol. 40 Issue (5): 25020128-8    https://doi.org/10.11896/cldb.25020128
  生物质助力建筑材料可持续发展 |
偶联表面处理咖啡渣粉改性沥青的高温流变特性及储存稳定性
高英力1,2,*, 黄国泰1, 李昀博1, 朱俊材1
1 长沙理工大学交通运输工程学院,长沙 410114;
2 长沙理工大学湖南省碳中和道路新材料工程技术研究中心,长沙 410114
High Temperature Rheological Properties and Storage Stability of Coffee Grounds Powder Modified Asphalt by Coupling Surface Treatment
GAO Yingli1,2,*, HUANG Guotai1, LI Yunbo1, ZHU Juncai1
1 School of Traffic and Transportation Engineering, Changsha University of Science & Technology, Changsha 410114, China;
2 Hunan Provincial Engineering Technology Research Center for Novel and Carbon Neutral Road Material, Changsha University of Science & Technology, Changsha 410114, China
下载:  全 文 ( PDF ) ( 16355KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 为开发废弃咖啡渣有效资源化利用的新途径,探索表面处理新技术,采用硅烷偶联剂溶液(KH-550)对废弃咖啡渣进行表面处理,制备不同掺量咖啡渣(3%、6%、9%、12%)的改性沥青。通过常规性能、高温黏度、软化点差及高温流变等试验,研究偶联表面改性咖啡渣对沥青高温流变性能及储存稳定性的影响,并采用扫描电镜和红外光谱测试分析其改性机理。结果表明,表面处理能提高咖啡渣改性沥青的高温性能,且能显著改善其储存稳定性;偶联表面处理咖啡渣改性沥青相较于原样沥青,软化点提升22.1%,135 ℃黏度提升116%,52 ℃车辙因子增大56.3%;咖啡渣经处理后表面更粗糙,与沥青相容性更好,其与沥青为物理混合;但表面处理对咖啡渣改性沥青低温性能没有明显改善;使用表面处理咖啡渣改性沥青,具有良好的经济与环保效益。综合考虑,咖啡渣与表面处理咖啡渣在沥青中的建议掺量分别为9%、12%。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
高英力
黄国泰
李昀博
朱俊材
关键词:  咖啡渣粉  硅烷偶联剂  改性沥青  高温流变特性  储存稳定性    
Abstract: To develop new ways for the effective resource utilization of discarded coffee grounds and study new surface treatment technologies, waste coffee grounds were surface-treated with a silane coupling agent solution (KH550) to prepare modified asphalt with different coffee grounds contents (3%, 6%, 9%, and 12%). Through tests such as conventional performance, high temperature viscosity, softening point difference, and high temperature rheology, the influence of the coupling surface modified coffee grounds on the high temperature rheological properties and storage stability of asphalt was studied. Moreover, scanning electron microscopy and infrared spectroscopy were used to test and analyze the modification mechanism. The results show that surface treatment can improve the high-temperature performance of coffee ground modified asphalt and significantly improve its storage stability. Compared with the original asphalt, the softening point of the coupling surface-treated coffee ground modified asphalt is increased by 22.1%, the viscosity at 135 ℃ is increased by 116%, and the rutting factor at 52 ℃ is increased by 56.3%. After surface treatment, the surface of coffee grounds is rougher and has better compatibility with asphalt. It is a physical mixture with asphalt. However, surface treatment has no obvious improvement on the low-temperature performance of coffee ground modified asphalt. The use of surface-treated coffee ground modified asphalt has good economic and environmental benefits. Considering comprehensively, the recommended contents of coffee grounds and surface-treated coffee grounds in asphalt are 9% and 12%, respectively.
Key words:  coffee grounds    silane coupling agent    modified asphalt    rheological performance at high temperature    storage stability
出版日期:  2026-03-10      发布日期:  2026-03-10
ZTFLH:  U414  
基金资助: 国家自然科学基金(52278239;52308234;52209154);湖南省自然科学基金(2022JJ30042;2023JJ30040);国家教育部“春晖计划”合作科研项目(HZKY20220358);湖南省“三尖”创新人才工程-“荷尖”人才项目(2022RC1175);湖南省教育厅项目(23C0127)
通讯作者:  *高英力,博士,教授,长沙理工大学博士研究生导师。目前主要从事工业固体废弃物综合利用、道路结构新材料的研发及应用等方面的研究工作。yingligao509@126.com   
引用本文:    
高英力, 黄国泰, 李昀博, 朱俊材. 偶联表面处理咖啡渣粉改性沥青的高温流变特性及储存稳定性[J]. 材料导报, 2026, 40(5): 25020128-8.
GAO Yingli, HUANG Guotai, LI Yunbo, ZHU Juncai. High Temperature Rheological Properties and Storage Stability of Coffee Grounds Powder Modified Asphalt by Coupling Surface Treatment. Materials Reports, 2026, 40(5): 25020128-8.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25020128  或          https://www.mater-rep.com/CN/Y2026/V40/I5/25020128
1 Srivastava N, Singh P, Srivastava M, et al. Renewable and Sustainable Energy Reviews, 2024, 199, 114477.
2 Araujo M N, dos Santos K C, do Carmo Diniz N, et al. Bioresource Technology Reports, 2022, 18, 101013.
3 Strieder M M, Velásquez Piñas J A, Ampese L C, et al. Journal of Cleaner Production, 2023, 415, 137716.
4 Kang S B, Oh H Y, Kim J J, et al. Renewable Energy, 2017, 113, 1208.
5 Veitía-de-Armas L, Reynel-Ávila H E, Bonilla-Petriciolet A, et al. Industrial Crops and Products, 2024, 214, 118535.
6 Nguyen Q A, Cho E J, Lee D, et al. Bioresource Technology, 2019, 272, 209.
7 Cho D, Yoon K, Kwon E E, et al. Environmental Pollution, 2017, 229, 942.
8 Cuong N X, Thanh H N T, Hong C N T, et al. Chemosphere, 2021, 282, 131009.
9 Ding Y, Shan B, Cao X, et al. Journal of Cleaner Production, 2021, 288, 125586.
10 Kabir S F, Mousavi M, Fini E H. Journal of Cleaner Production, 2020, 252, 119856.
11 Edu S X X N, Zhang Y, Shahbazi A. BioResources, 2015, 10(2), 458.
12 Vardon D R, Moser B R, Zheng W, et al. ACS Sustainable Chemistry and Engineering, 2013(10), 1286.
13 Zhao N, Liu Z, Yu T, et al. Trends in Food Science & Technology, 2024, 143, 104312.
14 Zhang Y, Si C, Fan T, et al. Construction and Building Materials, 2023, 389, 131796.
15 Lyu P, Wang H, Wang Z, et al. Highway, 2023, 68(1), 23(in Chinese).
吕鹏磊, 王宏光, 王子照, 等. 公路, 2023, 68(1), 23.
16 Liu W, Huang Z, Zhang Y, et al. Highway, 2024, 69(9), 28(in Chinese).
刘卫东, 黄志鹏, 张仰鹏, 等. 公路, 2024, 69(9), 28.
17 Xue Y, Ge D, Lv S, et al. Construction and Building Materials, 2023, 408, 133656.
18 Ji C, Zhao S, Peng C, et al. Forest Engineering, 2020, 36(5), 106(in Chinese).
吉淳, 赵双, 彭超, 等. 森林工程, 2020, 36(5), 106.
19 Chen L, Li X, Duan H, et al. Materials Science and Technology, 2023, 31(5), 24(in Chinese).
陈黎维, 李雄, 段浩, 等. 材料科学与工艺, 2023, 31(5), 24.
20 Liu L, Liu Z, Xiang Y, et al. Journal of Building Materials, 2017, 20(1), 150(in Chinese).
柳力, 刘朝晖, 向宇, 等. 建筑材料学报, 2017, 20(1), 150.
21 Gao Y, Li Y, Tian W, et al. Materials Reports, 2025, 39(9), 24040022(in Chinese).
高英力, 李昀博, 田维伟, 等. 材料导报, 2025, 39(9), 24040022.
22 Li C, Wang H, Fu C, et al. Construction and Building Materials, 2023, 366, 130086.
23 Cao L, Zhang X, Yang C, et al. Journal of Central South University(Science and Technology), 2021, 52(7), 2276(in Chinese).
曹丽萍, 张晓亢, 杨晨, 等. 中南大学学报(自然科学版), 2021, 52(7), 2276.
24 Lyu S, Fan X, Lu W, et al. Journal of Functional Materials, 2020, 51(4), 4199(in Chinese).
吕松涛, 樊现鹏, 鲁巍巍, 等. 功能材料, 2020, 51(4), 4199.
25 Cheng X, Liu J, Han C, et al. Construction and Building Materials, 2023, 366, 130182.
26 Han X, Cao Z, Wang R, et al. Construction and Building Materials, 2020, 259, 119713.
27 Ran W, Zhu H, Shen X, et al. Construction and Building Materials, 2022, 329, 127057.
28 Cheng C, Tao G, Wang Q, et al. Journal of Forestry Engineering, 2019, 4(1), 141(in Chinese).
程承, 陶桂祥, 王琦, 等. 林业工程学报, 2019, 4(1), 141.
29 Batista K B, Padilha R P L, Castro T O, et al. Industrial Crops and Products, 2018, 111, 107.
30 Fan W, Xin X, Liang M, et al. Journal of China University of Petroleum(Edition of Natural Science), 2015, 39(4), 165(in Chinese).
范维玉, 辛雪, 梁明, 等. 中国石油大学学报(自然科学版), 2015, 39(4), 165.
31 Li Y, He T, Tang J. Case Studies in Construction Materials, 2024, 20, e02988.
32 Han X, Cao Z, Wang R, et al. Construction and Building Materials, 2020, 259, 119713.
33 Meng Y, Yan T, Muhammad Y, et al. Journal of Cleaner Production, 2022, 338, 130563.
34 Xu L, Li X, Zong Q, et al. Construction and Building Materials, 2021, 272, 121972.
35 Li J, Yang S, Liu Y, et al. Construction and Building Materials, 2019, 218, 413.
36 Yin Y, Muhammad Y, Zeng X, et al. Progress in Organic Coatings, 2018, 125, 234.
37 Yan K, Chen J, You L, et al. Journal of Cleaner Production, 2020, 258, 120732.
38 Xiang Y, Fan H, Liu Z. Construction and Building Materials, 2020, 236, 117600.
39 Ren R, Han K, Zhao P, et al. Construction and Building Materials, 2019, 198, 662.
[1] 高英力, 李昀博, 田维伟, 朱俊材, 廖美捷, 王蒴. 胶粉改性沥青预处理技术研究进展[J]. 材料导报, 2025, 39(9): 24040022-10.
[2] 王欣宇, 惠迎新, 徐新强, 李博文, 顾士周. 盐蚀作用对钢渣-SBS/胶粉复合改性沥青界面粘附特性的影响[J]. 材料导报, 2025, 39(23): 24060230-9.
[3] 李亚莎, 田泽, 王璐敏, 庞梦昊, 曾跃凯, 赵光辉. 表面接枝KH550 的石墨烯改性聚二甲基硅氧烷热力学性能的分子动力学模拟[J]. 材料导报, 2025, 39(2): 24010155-6.
[4] 田小革, 李光耀, 高凯, 吴清浩, 黄思丹, 谢振. 硅烷偶联剂接枝活化废胶粉与沥青相容性及微观机理研究[J]. 材料导报, 2025, 39(18): 24070126-10.
[5] 凡涛涛, 韩松凯, 司春棣. 紫外老化对硫酸钙晶须改性沥青疲劳性能的影响[J]. 材料导报, 2025, 39(11): 24040015-6.
[6] 张园, 曹子萱, 虞将苗, 于华洋, 邹桂莲. 聚合物改性沥青老化机理研究综述[J]. 材料导报, 2025, 39(10): 24030218-12.
[7] 杨程程, 柳力, 刘朝晖, 黄优, 刘磊鑫. 基于分子动力学的偶联剂接枝改性玄武岩纤维与沥青粘附特性研究[J]. 材料导报, 2024, 38(6): 22110027-7.
[8] 田小革, 李光耀, 陈功, 姚世林, 黄雪梅, 王俊杰, 陆劲州. TPU/Nano-ZnO复合改性沥青的性能研究及微观机制[J]. 材料导报, 2024, 38(16): 23050071-10.
[9] 李嘉, 肖鹏, 范思源, 周壹伍. 基于表面能理论的粘结剂-UHPC粘结失效模式分析[J]. 材料导报, 2024, 38(14): 23030069-7.
[10] 张伟钢, 李娇, 吕丹丹. 涂料助剂对PDMS改性环氧树脂/Al复合涂层性能的影响[J]. 材料导报, 2024, 38(10): 23010030-5.
[11] 吴智恒, 黄伊琳, 毕雁冰, 梁立喆, 归立发, 李卫庆, 沈培康, 田植群. 石墨烯及其衍生物改性沥青的研究进展[J]. 材料导报, 2024, 38(1): 22040410-9.
[12] 刘圣洁, 林钰, 李梦然, 周胜波. 基于MSCR试验的温拌阻燃沥青高温性能评价与分级[J]. 材料导报, 2023, 37(9): 21060064-6.
[13] 栗启, 胡魁, 俞才华, 张桃利, 王丹丹. 聚乙烯与沥青相互作用的分子动力学机理研究[J]. 材料导报, 2023, 37(5): 21080176-6.
[14] 于本田, 杨玉祥, 刘江, 王永刚, 王朋勇, 谢超. 改性SiO2气凝胶水泥基复合砂浆性能及冻融损伤研究[J]. 材料导报, 2023, 37(23): 22040197-6.
[15] 丁鹤洋, 汪海年, 徐宁, 王宠惠, 屈鑫, 尤占平. 基于分子动力学的生物质油改性沥青相容性研究[J]. 材料导报, 2023, 37(2): 21050266-8.
[1] Huanchun WU, Fei XUE, Chengtao LI, Kewei FANG, Bin YANG, Xiping SONG. Fatigue Crack Initiation Behaviors of Nuclear Power Plant Main Pipe Stainless Steel in Water with High Temperature and High Pressure[J]. Materials Reports, 2018, 32(3): 373 -377 .
[2] Miaomiao ZHANG,Xuyan LIU,Wei QIAN. Research Development of Polypyrrole Electrode Materials in Supercapacitors[J]. Materials Reports, 2018, 32(3): 378 -383 .
[3] Congshuo ZHAO,Zhiguo XING,Haidou WANG,Guolu LI,Zhe LIU. Advances in Laser Cladding on the Surface of Iron Carbon Alloy Matrix[J]. Materials Reports, 2018, 32(3): 418 -426 .
[4] Huaibin DONG,Changqing LI,Xiahui ZOU. Research Progress of Orientation and Alignment of Carbon Nanotubes in Polymer Implemented by Applying Electric Field[J]. Materials Reports, 2018, 32(3): 427 -433 .
[5] Xiaoyu ZHANG,Min XU,Shengzhu CAO. Research Progress on Interfacial Modification of Diamond/Copper Composites with High Thermal Conductivity[J]. Materials Reports, 2018, 32(3): 443 -452 .
[6] Anmin LI,Junzuo SHI,Mingkuan XIE. Research Progress on Mechanical Properties of High Entropy Alloys[J]. Materials Reports, 2018, 32(3): 461 -466 .
[7] Qingqing DING,Qian YU,Jixue LI,Ze ZHANG. Research Progresses of Rhenium Effect in Nickel Based Superalloys[J]. Materials Reports, 2018, 32(1): 110 -115 .
[8] Yaxiong GUO,Qibin LIU,Xiaojuan SHANG,Peng XU,Fang ZHOU. Structure and Phase Transition in CoCrFeNi-M High-entropy Alloys Systems[J]. Materials Reports, 2018, 32(1): 122 -127 .
[9] Changsai LIU,Yujiang WANG,Zhongqi SHENG,Shicheng WEI,Yi LIANG,Yuebin LI,Bo WANG. State-of-arts and Perspectives of Crankshaft Repair and Remanufacture[J]. Materials Reports, 2018, 32(1): 141 -148 .
[10] Xia WANG,Liping AN,Xiaotao ZHANG,Ximing WANG. Progress in Application of Porous Materials in VOCs Adsorption During Wood Drying[J]. Materials Reports, 2018, 32(1): 93 -101 .
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed