A Review of Aging Mechanism on Polymer-modified Asphalt Binders
ZHANG Yuan1,2, CAO Zixuan1, YU Jiangmiao1,2,3, YU Huayang1, ZOU Guilian1,*
1 School of Civil Engineering and Transportation, South China University of Technology, Guangzhou 510641, China 2 State Key Laboratory of Subtropical Building and Urban Science, South China University of Technology, Guangzhou 510640, China 3 Central Fortune Creation Technology Group Co., Ltd., Foshan 528000, Guangdong, China
Abstract: This paper reviews three types of polymer modifiers commonly used in asphaltbinders and their improvement in the performance of asphalt binders, analyses the effect of aging on polymer-modified asphalt. Moreover, the aging mechanism of polymer-modified asphalt binders is explained from polymer phase degradation, chain breakage, and free radical formation respectively. Differences in different polymer-modified asphalt binders due to aging at the macro and micro scales have been generalized. Finally, the research progress of antioxidants based on aging mechanism is summarized. The results show that the three main types of polymers used in asphalt are thermoplastic elastomers, thermoset elastomers, and plastics. Polymer-modified asphalt binders exhibit different aging characteristics from base asphalt binders, resulting from the dominant role of polymer degradation in the aging of modified asphalt binders. Macroscopically, the aging of polymer-modified asphalt includes oxidation of the base binders and degradation of the polymer phase. Microscopically, this includes dehydrogenation of the asphalt molecule, cycloalkane aromatization, polymer molecule chain breakage, the formation of oxygen-containing groups, and chemical-physical cross-linking of the polymer and asphalt binders groups. Currently, the methods for studying polymer degradation levels include the solvent oil method, extraction met-hod and characteristic peak method, which have their pros and cons, and more experimental methods for polymer degradation characterization need to be explored in the future. In addition, it is recommended to establish a complete aging theory system from various aspects such as rheological properties, microstructure, and molecular dynamics. At the same time, the development of antioxidants from the multifunctionality, economy, sustainability, and long-lasting and other aspects of comprehensive consideration is also one of the directions in future research.
1 Tauste R, Moreno-Navarro F, Sol-Sánchez M, et al. Construction and Building Materials, 2018, 192, 593. 2 Hu D L, Gu X Y, Sun L J, et al. Journal of Traffic and Transportation Engineering, 2023, 23(2), 141 (in Chinese). 胡栋梁, 顾兴宇, 孙丽君, 等. 交通运输工程学报, 2023, 23(2), 141. 3 Guo M, Ren X, Jiao Y B, et al. China Journal of Highway and Transport, 2022, 35(4), 41 (in Chinese). 郭猛, 任鑫, 焦峪波, 等. 中国公路学报, 2022, 35(4), 41. 4 Xu S, Jia X J, Huang R Y, et al. Construction and Building Materials, 2023, 367, 130286. 5 Alfaqawi R M, Fareed A, Zaidi S B A, et al. Construction and Building Materials, 2022, 315, 125789. 6 Luz P M S G, Ziegler C R, Mendonça A M G D, et al. Materials and Structures, 2021, 54, 166. 7 Zhang W G, Jia Z R, Zhang Y X, et al. Polymers, 2019, 11, 140. 8 Alnadish A M, Katman H Y B, Ibrahim M R, et al. Frontiers in Materials, 2023, 10, 1225830. 9 Yildirim Y. Construction and Building Materials, 2007, 21, 66. 10 Wu J, Liu Q, Wang C, et al. Journal of Cleaner Production, 2021, 283, 124663. 11 Nivitha M R, Prasad E, Krishnan J M. International Journal of Pavement Engineering, 2016, 17, 565. 12 Sun D Q, Ye F, Shi F Z, et al. Petroleum Science and Technology, 2006, 24, 1067. 13 Song L, Wang Z H, Shu C, et al. China Journal of Highway and Transport, 2021, 34(10), 17 (in Chinese). 宋亮, 王朝辉, 舒诚等. 中国公路学报, 2021, 34(10), 17. 14 Fan J W, Xu G J, Ma T, et al. Journal of Southeast University(Natural Science Edition), 2023, 53(3), 377 (in Chinese). 范剑伟, 徐光霁, 马涛, 等. 东南大学学报(自然科学版), 2023, 53(3), 377. 15 Deng W, Lai H, Wu J, et al. Applied Chemical Industry, 2024, 16581 (in Chinese). 邓威, 赖淏, 吴婧, 等. 应用化工, 2024, 16581. 16 Qian C X, Xie J G, Wang H B. Journal of Southeast University(Natural Science Edition), 2005(6), 945(in Chinese). 钱春香, 解建光, 王鸿博. 东南大学学报(自然科学版), 2005(6), 945. 17 Tan Y Q, Fu Y K, Ji L, et al. Journal of Harbin Institute of Technology, 2016, 48(3), 66 (in Chinese). 谭忆秋, 符永康, 纪伦, 等. 哈尔滨工业大学学报, 2016, 48(3), 66. 18 Wang S, Huang W D, Liu X Y, et al. Construction and Building Materials, 2022, 327, 126937. 19 Jiang Z L, Hu C B, Easa S M, et al. Journal of Applied Polymer Science, 2017, 134, 44850. 20 He W T, Zhao Z F, Yuan J, et al. Construction and Building Materials, 2023, 363, 129800. 21 Huang G, Yang T H, He Z, et al. Construction and Building Materials, 2022, 356, 129058. 22 Cong L, Yang F, Guo G H, et al. Construction and Building Materials, 2019, 225, 1012. 23 Xu P J, Zhu Z, Wang Y D, et al. Construction and Building Materials, 2022, 320, 126262. 24 Jin X, Guo N S, You Z P, et al. Materials Reports, 2019, 33(21), 3686 (in Chinese). 金鑫, 郭乃胜, 尤占平, 等. 材料导报, 2019, 33(21), 3686. 25 Zhu J Q, Birgisson B, Kringos N. European Polymer Journal, 2014, 54, 18. 26 Xu L, Zhang Y, Zhang Z S, et al. Construction and Building Materials, 2023, 389, 131551. 27 Porto M, Caputo P, Loise V, et al. Applied Sciences, 2019, 9, 742. 28 Mahida S, Shah Y U, Sharma S, et al. Journal of Materials Science, 2023, 58, 6106. 29 Tang N, Lv Q, Huang W, et al. Construction and Building Materials, 2019, 205, 87. 30 Wang S, Cheng D, Xiao F. Construction and Building Materials, 2017, 131, 101. 31 Lu X, Isacsson U. Journal of Applied Polymer Science, 2000, 76, 1811. 32 Wang J Y. Study on degradation of polymer modified asphalt binders during thermal storage and transportation. Master’s Thesis, Chang’an University, China, 2021 (in Chinese). 王俊岩. 聚合物改性沥青在热储存及运输过程中的降解研究. 硕士学位论文, 长安大学, 2020. 33 Cong L, Yang F, Guo G H, et al. Construction and Building Materials, 2019, 225, 1012. 34 Diab A, Enieb M, Singh D. Construction and Building Materials, 2019, 196, 54. 35 Cui Y N, Chen R P, Chen C, et al. Acta Materiae Compositae Sinica, 2018, 35, 1619 (in Chinese). 崔亚楠, 陈瑞璞, 陈超, 等. 复合材料学报, 2018, 35, 1619. 36 Zhao Y, Tian Y F, Huang D, et al. Journal of Materials Science and Engineering, 2023, 41(4), 597 (in Chinese). 赵毅, 田于锋, 黄东, 等. 材料科学与工程学报, 2023, 41(4), 597. 37 Habbouche J, Boz I, Hajj E Y, et al. International Journal of Pavement Engineering, 2022, 23, 3285. 38 Cui Y N, Guo L D, Chen D S. Journal of Building Materials, 2020, 23(5), 1183 (in Chinese). 崔亚楠, 郭立典, 陈东升. 建筑材料学报, 2020, 23(5), 1183. 39 Ma Y, Wang S, Zhang M, et al. Science of the Total Environment, 2023, 865, 161089. 40 Gu L P. Research on property of PE modified asphalt aging and regeneration. Master’s Thesis, Changsha University of Science & Technology, China, 2012 (in Chinese). 辜丽萍. PE改性沥青的老化与再生性能研究. 硕士学位论文, 长沙理工大学, 2012. 41 Xiao P, Zheng J H, Ding Y. Journal of Materials Science and Engineering, 2019, 37(1), 113 (in Chinese). 肖鹏, 郑佳辉, 丁燕. 材料科学与工程学报, 2019, 37(1), 113. 42 Wang H P, Liu X, Y Apostolidis P, et al. Materials and Structures, 2020, 53, 1. 43 Xing C W, Liu L P, Li M C. Energy & Fuels, 2020, 34, 4194. 44 Sugano M, Kajita J, Arai T, et al. Waste and Biomass Valorization, 2019, 10, 3579. 45 Kaya D, Topal A, Gupta J, et al. Construction and Building Materials, 2020, 235, 117450. 46 Sun G Q, Zhu X B, Zhang Q Y, et al. Science of the Total Environment, 2022, 813, 152601. 47 Roja K L, Masad E, Krishnamoorthy S K, et al. Road Materials and Pavement Design, 2023, 24, 672. 48 Sun G Q, Li B, Sun D Q, et al. Fuel, 2021, 285, 118989. 49 Chang M F, Zhang Y X, Pei J Z, et al. Materials, 2020, 13, 4120. 50 Yan K Z, Wang D C. Journal of Building Materials, 2020, 23(2), 479 (in Chinese). 颜可珍, 王道珵. 建筑材料学报, 2020, 23(2), 479. 51 Gao M X, Fan C H, Chen X X, et al. Advances in Materials Science and Engineering, 2022, 812, 152601. 52 Peng C, Lu L, You Z P, et al. Journal of Materials in Civil Engineering, 2022, 34, 04022274. 53 Yu C H, Hu K, Yang Q L, et al. Construction and Building Materials, 2021, 313, 125478. 54 Hu D L, Gu X, Cui B. Frontiers of Structural and Civil Engineering, 2021, 15, 1261. 55 Chen Q T, Wang Z X. Journal of Wuhan University of Technology(Transportation Science & Engineering), 2021, 45(6), 1145 (in Chinese). 陈钦庭, 王志祥. 武汉理工大学学报(交通科学与工程版), 2021, 45(6), 1145. 56 Yan C Q, Huang W D, Lin P, et al. Fuel, 2019, 252, 417. 57 Zhang H L, Yang X, Lin Y T, et al. Road Materials and Pavement Design, 2023, 24, 1088. 58 Xu X. Investigation on properties of rejuvenated SBS modified bitumen and their mixture based on structure reconstruction. Ph. D. Thesis, Wuhan University of Technology, China, 2018 (in Chinese). 徐雄. 基于结构重建的再生SBS改性沥青及其混合料性能研究. 博士学位论文, 武汉理工大学, 2018. 59 Yang X. Performance investigation of rejuvenator for aged SBS modified asphalt based on asphalt component reconciliation and SBS molecular structural repair. Master’s Thesis, Hunan University, 2021 (in Chinese). 杨雪. 基于组分调节和结构修复的老化SBS改性沥青再生性能研究. 硕士学位论文, 湖南大学, 2021. 60 Ni H T, Hu M J, Sun D Q, et al. Construction and Building Materials, 2023, 369, 130549. 61 Hossain R. Novel methods for determining polymer content and polymer degradation in asphalt binder. Ph. D. Thesis, Louisiana Tech University, 2021. 62 Sugano M, Iwabuchi Y, Watanabe T, et al. Clean Technologies and Environmental Policy, 2010, 12, 653. 63 Tang N P, Xue C Y, Liu S P, et al. Journal of Jilin University(Engineering and Technology Edition), 2024, 54(1), 22 (in Chinese). 唐乃膨, 薛晨阳, 刘少鹏,等. 吉林大学学报(工学版), 2024, 54(1), 22. 64 Wang L, Chen G, Xing Y M, et al. Journal of Building Materials, 2015, 18(3), 499 (in Chinese). 王岚, 陈刚, 邢永明, 等. 建筑材料学报, 2015, 18(3), 499 (in Chinese). 65 Lyu W J, Liu H, Chang P T, et al. New Chemical Materials, 2022, 50(5), 227 (in Chinese). 吕文江, 刘浩, 常鹏涛, 等. 化工新型材料, 2022, 50(5), 227. 66 Gómez N H C, Fleischel O, Oeser M. Construction and Building Materials, 2022, 327, 126932. 67 Hong B, Lu G Y, Gao J L, et al. China Journal of Highway and Transport, 2020, 33(10), 240 (in Chinese). 洪斌, 陆国阳, 高峻凌, 等. 中国公路学报, 2020, 33(10), 240. 68 Xiang Q, Xiao F P. Construction and Building Materials, 2020, 235, 117529. 69 Zhang Y H. Study on microstructure and properties for epoxy asphalt. Master’s Thesis, Chang’an University, China, 2018 (in Chinese). 张一函. 环氧沥青微观结构与性能研究. 硕士学位论文, 长安大学, 2019. 70 Apostolidis P, Liu X, Erkens S, et al. International Journal of Pavement Engineering, 2022, 23, 1471. 71 Cuciniello G, Leandri P, Losa M, et al. International Journal of Pavement Engineering, 2022, 23, 1083. 72 Li H L. Study on the properties of LDPE and EVA compound modified asphalt. Master’s Thesis, Shantou University, China, 2018 (in Chinese). 李慧丽. LDPE与EVA复合改性沥青性能研究. 硕士学位论文, 湖南大学, 2022. 73 Singh P, Swamy A K. International Journal of Sustainable Engineering, 2019, 12, 141. 74 Joohari I B, Maniam S, Giustozzi F. Journal of Materials in Civil Engineering, 2022, 34, 04022286. 75 Huang X, Yao X G. Highway Engineering, 2018, 43(6), 228 (in Chinese). 黄旭, 姚晓光. 公路工程, 2018, 43(6), 228. 76 Yang F H, Hu Z, Xi H Y. Advances in Materials Science and Engineering, 2022, 2022. 77 Xu S, Wang Y F, Jia X J, et al. Construction and Building Materials, 2022, 361, 129660. 78 Ding Z, Wang A B, Li H F. Applied Chemical Industry, 2023, 52(2), 350 (in Chinese). 丁湛, 王爱波, 栗慧峰, 等. 应用化工, 2023, 52(2), 350. 79 Li Y T, Li L F, Zhang Y, et al. Journal of Applied Polymer Science, 2010, 116(2), 754. 80 Cortizo M S, Larsen D O, Bianchetto H, et al. Polymer Degradation and Stability, 2004, 86, 275. 81 Geng J G, Chen M Y, Xia C Y, et al. Journal of Cleaner Production, 2022, 331, 129978. 82 Chen H P, Qiao Q, Tu G G. Liaoning Chemical Industry, 2007(8), 535 (in Chinese). 陈海平, 乔迁, 涂根国. 辽宁化工, 2007(8), 535. 83 You G X, CAI S D, Zhou X L, et al. Engineering Plastics Application, 2017, 45(9), 93 (in Chinese). 游革新, 蔡斯迪, 周序霖, 等. 工程塑料应用, 2017, 45(9), 93. 84 Fang C Q, Zhang M R, Zhang Z P, et al. Polymer-Plastics Technology and Engineering, 2009, 48, 945. 85 Hou X D, Lv S T, Chen Z, et al. Measurement, 2018, 121, 304. 86 Qu X, Ding H Y, Wang H N. China Journal of Highway and Transport, 2022, 35(6), 205 (in Chinese). 屈鑫, 丁鹤洋, 汪海年. 中国公路学报, 2022, 35(6), 205. 87 Feng Z G, Bian H J, Li J X, et al. Material and Structures, 2016, 49, 1381. 88 Fernández-Gómez W D, Quintana H A R, Daza C E, et al. Fuel, 2014, 115, 321. 89 Dessouky S, Ilias M, Park D W, et al. Advances in Materials Science and Engineering, 2015, 2015. 90 Cong P L, Wang J Y, Luo W H, et al. Construction and Building Materials, 2021, 302, 124413. 91 Collins M N, Nechifor M, Tanasă F, et al. International Journal of Biological Macromolecules, 2019, 131, 828. 92 Dessouky S, Contreras D, Sanchez J, et al. Construction and Building Materials, 2013, 38, 214. 93 Shah P M, Mir M S. Korea-Australia Rheology Journal, 2020, 32, 235. 94 Cheng P F, Yang Z H, Zhang Z M, et al. Materials Reports, 2022, 36(9), 114 (in Chinese). 程培峰, 杨宗昊, 张展铭, 等. 材料导报, 2022, 36(9), 114. 95 Wu Z H, Huang Y L, Bi Y B, et al. Materials Reports, 2024, 38(1), 61 (in Chinese). 吴智恒, 黄伊琳, 毕雁冰, 等. 材料导报, 2024, 38(1), 61. 96 Liu Z H, Han X B, Qi C, et al. Journal of Materials Science and Engineering, 2023, 41(5), 741 (in Chinese). 刘志航, 韩晓斌, 祁聪, 等. 材料科学与工程学报, 2023, 41(5), 741. 97 Zhang D M, Chen Z H, Zhang H L, et al. Construction and Building Materials, 2018, 188, 409. 98 Han D Q, Hu G S, Zhang J T. Polymers, 2023, 15, 256. 99 Ji Z Y, Wu X, Zhang Y, et al. Materials, 2023, 16, 5866. 100 Peng B, Ling T Q, Ge H. Materials Reports, 2022, 36(20), 269 (in Chinese). 彭博, 凌天清, 葛豪. 材料导报, 2022, 36(20), 269. 101 Xu N, Wang H N, Chen Y, et al. Construction and Building Materials, 2022, 322, 126494. 102 Apeagyei A K. Construction and Building Materials, 2011, 25, 47. 103 Cong P L, Wang X, Xu P J, et al. Polymer Degradation and Stability, 2013, 98, 2627. 104 Zhao K C, Chen Y, Huang K Q. Materials Reports, 2019, 33(S2), 261 (in Chinese). 赵可成, 陈宇, 黄考取. 材料导报, 2019, 33(S2), 261. 105 Kassem E, Khan M S, Katukuri S, et al. International Journal of Pavement Engineering, 2019, 20, 1154. 106 Su Y, Tang S, Cai M, et al. Construction and Building Materials, 2023, 363, 129863. 107 Liang M C, Guo M, Tan Y Q, et al. International Journal of Pavement Engineering, 2023, 24, 2213385.
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