Please wait a minute...
材料导报  2025, Vol. 39 Issue (11): 24030106-11    https://doi.org/10.11896/cldb.24030106
  无机非金属及其复合材料 |
高纯磷制备工艺研究进展
姜宗魁1,2,3, 田阳1,2,3,4,*, 徐宝强1,2,3,4, 杨斌1,2,3,4, 孔令鑫1,2,3,4, 梁栋1,2,3, 王立鹏1,2,3, 张嘉鹏1,2,3
1 昆明理工大学真空冶金国家工程研究中心,昆明 650093
2 昆明理工大学冶金与能源工程学院,昆明 650093
3 昆明理工大学云南省有色金属真空冶金重点实验室,昆明 650093
4 昆明理工大学省部共建复杂有色金属资源清洁利用国家重点实验室,昆明 650093
Research Progress on Preparation Technology of High Purity Phosphorus
JIANG Zongkui1,2,3, TIAN Yang1,2,3,4,*, XU Baoqiang1,2,3,4, YANG Bin1,2,3,4, KONG Lingxin1,2,3,4, LIANG Dong1,2,3, WANG Lipeng1,2,3, ZHANG Jiapeng1,2,3
1 National Engineering Research Center of Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, China
2 Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
3 Key Laboratory for Nonferrous Vacuum Metallurgy of Yunnan Province, Kunming University of Science and Technology, Kunming 650093, China
4 State Key Laboratory of Clean Utilization of Complex Nonferrous Metal Resources, Kunming University of Science and Technology, Kunming 650093, China
下载:  全 文 ( PDF ) ( 27421KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 随着半导体和电子仪器等关键产业的飞速发展,我国对高纯磷的需求急剧增加。高纯磷是这些领域的重要原料,尤其在第二代半导体材料制造中发挥着至关重要的作用。然而,我国6N及以上高纯磷主要采用湿法制备,仍存在工艺流程长、磷收率低等问题,这在很大程度上制约了我国在全球高纯磷市场的竞争力。因此对高纯磷制备工艺的研究有重要意义和巨大的经济潜力。本文以高纯磷制备方法为主线,介绍了高纯磷火法及湿法制备工艺的原理及研究进展,对比了各自的工艺流程及优缺点,并探讨了高纯磷提纯工艺的发展方向。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
姜宗魁
田阳
徐宝强
杨斌
孔令鑫
梁栋
王立鹏
张嘉鹏
关键词:    高纯材料  分离纯化  火法制备  湿法制备    
Abstract: With the rapid development of key industries such as semiconductors and electronic instruments, the demand for high-purity phosphorus in China has sharply increased. High-purity phosphorus is an important raw material in these fields, especially playing a crucial role in the manufacturing of second-generation semiconductor materials. However, in China, the high purity phosphorus of 6N and above is mainly prepared by wet method, and there are some problems such as long process flow and low phosphorus yield. Which significantly constrain China’s compe-titiveness in the global high-purity phosphorus market. Therefore, research on the preparation technology of high-purity phosphorus is of great significance and has enormous economic potential. Considering the preparation methods of high-purity phosphorus as the main focus, this paper introduces the principles and research progress of both high-purity phosphorus pyrometallurgy and wet preparation processes, compares the respective process flows and advantages and disadvantages, and discusses the development direction of high-purity phosphorus purification technology.
Key words:  phosphorus    high-purity material    separation and purification    pyrometallurgical preparation    hydrometallurgical preparation
发布日期:  2025-05-29
ZTFLH:  TQ126.3  
基金资助: 云南省重大科技专项(202202AB080018)
通讯作者:  *田阳,博士,昆明理工大学冶金与能源工程学院教授、博士研究生导师。目前主要从事镁合金材料、二次资源回收利用、高纯金属材料制备等方面的研究。emontian@hotmail.com   
作者简介:  姜宗魁,现为昆明理工大学冶金与能源工程学院,真空冶金国家工程研究中心硕士研究生。目前主要从事高纯磷材料制备方向的研究。
引用本文:    
姜宗魁, 田阳, 徐宝强, 杨斌, 孔令鑫, 梁栋, 王立鹏, 张嘉鹏. 高纯磷制备工艺研究进展[J]. 材料导报, 2025, 39(11): 24030106-11.
JIANG Zongkui, TIAN Yang, XU Baoqiang, YANG Bin, KONG Lingxin, LIANG Dong, WANG Lipeng, ZHANG Jiapeng. Research Progress on Preparation Technology of High Purity Phosphorus. Materials Reports, 2025, 39(11): 24030106-11.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24030106  或          https://www.mater-rep.com/CN/Y2025/V39/I11/24030106
1 Qiu Z S, Ma Y X, Wang K X, et al. Journal of Yunnan University (Na-tural Sciences Edition), 2023, 45(5), 1089(in Chinese).
邱之实, 马宇翔, 王可欣, 等. 云南大学学报(自然科学版), 2023, 45(5), 1089.
2 Chang W, Gao J, Zhai J R, et al. Science and Technology in Chemical Industry, 2023, 31(4), 58 (in Chinese).
常伟, 高健, 翟婧如, 等. 化工科技, 2023, 31(4), 58.
3 Zhang S. Fabrication and characterization of crystal fiber red phosphorus and its controllable preparation for sensitive devices. Ph. D. Thesis, Shaanxi University of Science and Technology, China, 2022 (in Chinese).
张帅. 晶体纤维红磷的可控制备及在敏感元件中的研究. 博士学位论文, 陕西科技大学, 2022.
4 曹昌威, 唐朝辉. 中国专利, CN212595718U, 2021.
5 Ren X, Lian P, Xie D, et al. Journal of Materials Science, 2017, 52, 10364.
6 吴展平, 吴跃友, 王天喜, 等. 中国专利, CN101214935B, 2010.
7 Jiang Y, Zhao J, Lian P, et al. Industrial & Engineering Chemistry Research, 2022, 61(35), 13032.
8 United States Pharmacopeial Convention. Council of Experts, United States Pharmacopeial Convention. Food Ingredient Expert Committee. Food chemicals codex. US Pharmacopeia Conv, 2010, pp. 139.
9 Sun Z L, Wen L N. Chemical Fertilizer Industry, 2018, 45(3), 1(in Chinese).
孙志立, 问立宁. 化肥工业, 2018, 45(3), 1.
10 Kinose Y, Hata T, Aikawa M. U. S. Patent, US20120009112, 2014.
11 王邵东, 时宏杰, 汪勇平, 等. 中国专利, CN103641090B, 2015.
12 林军, 吴小海, 何忠华, 等. 中国专利, CN103754840B, 2016.
13 Geng R, Xia J, Chen Z, et al. Phosphorus, Sulfur, and Silicon and the Related Elements, 2017, 192(4), 475.
14 Reijnders L. Resources, Conservation and Recycling, 2014, 93, 32.
15 Webeck E, Matsubae K, Nakajima K, et al. Sociotechnica, 2014, 11, 119.
16 Liu Y, Qu H. Journal of Environmental Chemical Engineering, 2016, 4(2), 2155.
17 Cui J R, Gao Y F. Fertilizers and Health, 2020, 47(4), 1(in Chinese).
崔继荣, 高永峰. 肥料与健康, 2020, 47(4), 1.
18 Wen L N, Sun Z L. Phosphate & Compound Fertilizer, 2018, 33(12), 35(in Chinese).
问立宁, 孙志立. 磷肥与复肥, 2018, 33(12), 35.
19 Muster T H, Douglas G B, Sherman N, et al. Chemosphere, 2013, 91(5), 676.
20 Kuang G M. Phosphate & Compound Fertilizer, 2005(2), 45(in Chinese).
匡国明. 磷肥与复肥, 2005(2), 45.
21 Chen J F. Sulphur, Phosphorus & Bulk Materials Handling, 2007(2), 14(in Chinese).
陈嘉甫. 硫磷设计与粉体工程, 2007(2), 14.
22 Huang Q J. Inorganic Chemicals Industry, 2012, 44(2), 1(in Chinese).
黄千钧. 无机盐工业, 2012, 44(2), 1.
23 Wang H D, Fan T J, Xie Z J, et al. Materials Reports, 2017, 31(9), 45(in Chinese).
王慧德, 范涛健, 谢中建, 等. 材料导报, 2017, 31(9), 45.
24 Sun D D, Su W Y. Materials Reports, 2018, 32(12), 2105(in Chinese).
孙豆豆, 苏文勇. 材料导报, 2018, 32(12), 2105.
25 林军, 吴小海, 何忠华, 等. 中国专利, CN103771366B, 2016.
26 陈名东. 中国专利, CN102249201A, 2011.
27 Ren Y S, Li J, Ma R, et al. Journal of Sichuan University (Engineering Science Edition), 2009, 41(6), 73(in Chinese).
任永胜, 李军, 马睿, 等. 四川大学学报(工程科学版), 2009, 41(6), 73.
28 刘中华, 沈强华, 陈雯, 等. 中国专利, CN1194118C, 2005.
29 Wen J J, Wu Y, Wu M Z, et al. Materials Reports, 2022, 36(S2), 98(in Chinese).
文家俊, 吴尧, 伍美珍, 等. 材料导报, 2022, 36(S2), 982.
30 Wan H, Kong L, Yang B, et al. Journal of Materials Research and Technology, 2022, 17, 802.
31 Pfann W G. Solid state physics. Academic Press, 1957, 4, 423.
32 Tian Q H, He Z Q, Guo X Y, et al. The Chinese Journal of Nonferrous Metals, 2023, 33(10), 3321(in Chinese).
田庆华, 何志强, 郭学益, 等. 中国有色金属学报, 2023, 33(10), 3321.
33 Li W L, Luo Y H. Mining and Metallurgy, 2010, 19, 57.
34 Yongsheng R E N, Jun L I, Xiaoxiao D. Chinese Journal of Chemical Engineering, 2011, 19(2), 223.
35 Ren Y S, Li J, Ma R, et al. Journal of Sichuan University (Engineering Science Edition), 2009, 41(6), 73(in Chinese).
任永胜, 李军, 马睿, 等. 四川大学学报(工程科学版), 2009, 41(6), 73.
36 Miwa T, Kono T, Isomura R, et al. Talanta, 1970, 17(1), 108.
37 Liu X F, Li J, Luo J H, et al. Chinese Journal of Chemical Engineering, 2014, 22(3), 294.
38 Wan H, Kong L, Yang B, et al. Journal of Materials Research and Technology, 2022, 17, 802.
39 Zha G, Wang Y, Cheng M, et al. Journal of Materials Research and Technology, 2020, 9(3), 2926.
40 张智, 弭永利. 中国专利, CN1962419B, 2010.
41 李红林, 杨光明, 汪勇平, 等. 中国专利, CN103641085B, 2015.
42 王邵东, 段仕东, 时宏杰, 等. 中国专利, CN103641086B, 2015.
43 El-Kharraf S, El-Guendouz S, Abdellah F, et al. Pharmaceuticals, 2022, 15(5), 567.
44 Talanov N D, Astakhova G V, Shchigareva Z H T. Zhurnal Prikladnoy Khimii, 1970, 43, 820.
45 Hu C X, Wu Q K, Tian X J, et al. Agricultural Products Processing, 2018(9), 57(in Chinese).
胡程香, 吴启康, 田晓静, 等. 农产品加工, 2018(9), 57.
46 Meteleva-Fischer Y V, Yang Y, Boom R, et al. Intermetallics, 2012, 25, 9.
47 Zhang C, Lai H, Zhang Y, et al. Separation and Purification Technology, 2020, 232, 115954.
48 Yang Z, Dai L Q, Zhang L B, et al. Materials Reports, 2024, 38(5), 155 (in Chinese).
杨政, 代林晴, 张利波, 等. 材料导报, 2024, 38(5), 155.
49 Tang D Y, Huang N B, Tang M, et al. Chemical Engineering, 1999(6), 39(in Chinese).
汤德元, 黄乃宝, 汤敏, 等. 化学工程, 1999(6), 39.
50 Wang P Y, Liu M S, Liu Y C, et al. Journal of Kunming University of Science and Technology (Natural Sciences Edition), 2003(2), 12(in Chinese).
王平艳, 刘谋盛, 刘永成, 等. 昆明理工大学学报(理工版), 2003(2), 12.
51 Jiang Z, Yu H, Tian Y, et al. Separation and Purification Technology, 2024, 334, 126067.
52 李国璋, 华超, 方兴, 等. 中国专利, CN101912691A, 2010.
53 马兴良, 吴建军, 骆彪, 等. 中国专利, CN1289388C, 2006.
54 张双全, 曹昌威, 段榆忠, 等. 中国专利, CN206184018U, 2017.
55 蒋飚, 郭之军, 欧才彰, 等. 中国专利, CN109516446A, 2019.
56 Losev G, Mamykin A, Kolesnichenko I. Magnetohydrodynamics, 2021, 57(1), 73.
57 Li X, Wu J, Xu M, et al. Journal of Cleaner Production, 2019, 211, 695.
58 Zhang X X, Wang J, Ren Z M. Foundry Technology, 2022, 43(9), 761(in Chinese).
张小新, 王江, 任忠鸣. 铸造技术, 2022, 43(9), 761.
59 刘中华, 沈强华, 陈雯, 等. 中国专利, CN1194118C, 2005.
60 Ren Y S, Li J, Zhou N D, et al. Inorganic Salt Industry, 2009, 41(1), 12(in Chinese).
任永胜, 李军, 周能冬, 等. 无机盐工业, 2009, 41 (1), 12.
61 Ning P, Wang X, Bart H J, et al. Journal of Cleaner Production, 2011, 19(13), 1547.
62 李少平, 杜林, 张庭, 等. 中国专利, CN109052352B, 2021.
63 Heidarinejad Z, Dehghani M H, Heidari M, et al. Environmental Che-mistry Letters, 2020, 18, 393.
64 刘飞, 李天祥, 解田,等. 磷肥与复肥, 2009, 24(2), 19.
65 Tang X, Xiu Z, Han C, et al. Advances and achievements. American Chemical Society, 2013, pp. 181.
66 Li J, Ren Y S, Jin Y, et al. China Patent, CN100581997C, 2010(in Chinese).
李军, 任永胜, 金央, 等. 中国专利, CN100581997C, 2010.
67 Zhang C, Huang L, Danaei A, et al. Materials Letters, 2022, 308, 131126.
68 李军, 李敬东, 金央, 等. 中国专利, CN108892114B, 2023.
69 林军, 吴小海, 何忠华, 等. 中国专利, CN103754840B, 2016.
70 杨陆华, 马兴良, 吴建军, 等. 中国专利, CN1315289, 2001.
71 Ren Y, Li J, Dong X. The Canadian Journal of Chemical Engineering, 2011, 89(3), 491.
72 Al-Gaashani R, Najjar A, Zakaria Y, et al. Ceramics International, 2019, 45(11), 14439-.
73 El-Sherif S, Bejan D, Bunce N J. Canadian Journal of Chemistry, 2010, 88(9), 928.
74 Rosca I D, Watari F, Uo M, et al. Carbon, 2005, 43(15), 3124.
75 Chen Z, Xie G, Pan Z, et al. Journal of Alloys and Compounds, 2021, 851, 156834.
76 Seitz A E, Hippauf F, Kremer W, et al. Nature Communications, 2018, 9(1), 361.
77 Wang H T, Zhang H B, Lin H B. Fine Chemicals, 2004(9), 701(in Chinese).
王海涛, 张恒彬, 林海波. 精细化工, 2004(9), 701.
78 Cohen I, Shapira B, Avraham E, et al. Environmental Science & Technology, 2018, 52(11), 6275.
79 Li J, Jin Y, Chen M, et al. Separation and Purification Technology, 2019, 213, 314.
80 张双全, 李帅兵, 干长明, 等. 中国专利, CN212166569U, 2020.
81 Wang Z Y. Chlor-Alkali Industry, 2009, 45(8), 27(in Chinese).
王志勇. 氯碱工业, 2009, 45(8), 27.
82 杨盼, 谢佳华, 高云山, 等. 中国专利, CN113694852B, 2023.
83 张保华, 裴海朝. 中国专利, CN103130204A, 2013.
84 郁红明, 邱鸿恩. 中国专利, CN113264512A, 2021.
85 吴陶陶, 王同胜, 崔远闯, 等. 中国专利, CN216703388U, 2022.
86 曹昌威, 唐朝辉. 中国专利, CN212476115U, 2021.
87 肖兴强. 中国专利, CN217612986U, 2022.
88 白平平, 乐卫华, 朱刘. 中国专利, CN215048682U, 2021.
89 Du Z X, Gao Y F, Zhao Y F. Modern Chemical Industry, 2022, 42(S2), 283(in Chinese).
杜招鑫, 高有飞, 赵远方. 现代化工, 2022, 42 (S2), 283.
90 杨亚斌, 梅毅, 何锦林, 等. 中国专利, CN112875661A, 2021.
91 刘玉蒙, 苏毅, 马业梅, 等. 中国专利, CN112458481A, 2021.
[1] 赵岚, 韩颖超. 纳米氢氧化镧磷吸附剂的制备及水体除磷研究[J]. 材料导报, 2025, 39(8): 24010253-7.
[2] 吴学虎, 孙立贤, 徐芬, 李彬, 方淞文, 张靖, 陈翔, 宋领君, 卢俊铭, 高源, 杜毛湛, 徐如丹. 具有P和S双空位的镍钴纳米花复合材料用作超级电容器电极的研究[J]. 材料导报, 2025, 39(7): 24030138-7.
[3] 姜文平, 庞兴志, 何娟霞, 杨文超, 湛永钟. 骨修复用钛合金-羟基磷灰石复合材料的制备工艺及性能综述[J]. 材料导报, 2025, 39(5): 24090227-14.
[4] 李迎昕, 陈雅君, 钱立军. 含磷酰胺结构阻燃剂在高分子材料中的应用进展[J]. 材料导报, 2025, 39(5): 23120086-8.
[5] 邹振羽, 刘伟, 李朋娟, 李晓丽. 共活化法制备等级多孔炭材料及其储能性能研究[J]. 材料导报, 2025, 39(3): 23080193-7.
[6] 方双明, 付娟, 罗洁, 彭祝, 李子玲, 程金科. 无机碱与季铵盐协同改性磷石膏的抗霉特性及物理力学性能研究[J]. 材料导报, 2025, 39(3): 24010006-8.
[7] 董舵, 管婧宇, 王子祺, 肖逸. 核电厂放射性废物安全处置技术研究[J]. 材料导报, 2025, 39(11): 24110091-17.
[8] 陈畅, 丁学成, 酒少武, 陈延信. 纤维特性对磷酸镁基免蒸压加气混凝土性能的影响[J]. 材料导报, 2025, 39(10): 24050176-7.
[9] 胡乾宇, 陈昆峰, 薛冬峰. 异质界面对磷酸二氢铵单液滴结晶行为的影响[J]. 材料导报, 2025, 39(1): 24010234-5.
[10] 宋学锋, 王楠. 原位合成LDHs@地聚物复合材料的矿物组成及除磷效果[J]. 材料导报, 2024, 38(8): 22110080-6.
[11] 刘卉, 杨牛娃, 马梦圆, 田少囡, 张玉, 杨军. 金属基磷化物纳米材料制备与电催化应用研究进展[J]. 材料导报, 2024, 38(8): 23080249-17.
[12] 周翔, 李太, 黄振玲, 赵亮, 康家铭, 李绍元, 任永生, 马文会, 吕国强. 大尺寸直拉法单晶硅生长过程中晶体缺陷的研究进展[J]. 材料导报, 2024, 38(24): 23100030-9.
[13] 宋茂林, 张朝阳, 张尚枫, 侯晓伟, 石礼岗, 于斌, 罗宇维, 孔祥明. 超临界CO2环境下磷酸盐改性铝酸盐水泥性能变化[J]. 材料导报, 2024, 38(24): 23090114-4.
[14] 王郎郎, 张韶, 费政富, 宁平, 王学谦, 刘敬业, 谢怡冰, 马懿星, 王华. 黄磷生产中固废处置与资源化利用研究进展[J]. 材料导报, 2024, 38(22): 23080072-8.
[15] 刘雨昕, 胡倩, 粟茵, 文麒麟, 刘丽欣, 覃钺, 梁露露, 张宏志, 朱静. 具有高热稳定性Sm3+激活硼磷酸盐Na3B6PO13橙红色荧光粉的发光特性[J]. 材料导报, 2024, 38(21): 23080106-6.
[1] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[2] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[3] WU Wei, CHEN Shiying, ZONG Mengjingzi. Dielectric Properties and Thermal Stability of Nano-Al2O3/Polyether Sulfone-epoxy Resin Composites[J]. Materials Reports, 2017, 31(20): 21 -24 .
[4] MO Peicheng, WU Yi, YU Wenlin, WANG Jilin, ZOU Zhengguang, ZHONG Shenglin, WANG Peng. In Situ Synthesis of PcBN Composites by cBN-Ti-Al-Si and Their Mechanical Property[J]. Materials Reports, 2018, 32(14): 2355 -2359 .
[5] HU Yaoqiang, CHEN Fajin, LIU Haining, ZHANG Huifang, WU Zhijian, YE Xiushen. Preparation of Poly(N-isopropylacrylamide) Hydrogel and Its Thermally Induced Aggregation Behavior[J]. Materials Reports, 2018, 32(14): 2491 -2496 .
[6] SONG Gang, CHI Jiayu, YU Jingwei, LIU Liming. Corrosion Behavior of Mg-steel Laser-TIG Hybrid Welding Joint[J]. Materials Reports, 2018, 32(16): 2773 -2777 .
[7] HUANG Hui, HAN Jianfeng, WANG Yishun, XIA Yang, ZHANG Jun, GAN Yongping, LIANG Chu, ZHANG Wenkui. Supercritical CO2 Assisting Cladding of LiMnPO4 on the Surface of Li[Li0.2-Mn0.54Co0.13Ni0.13]O2 and Its Electrochemical Properties[J]. Materials Reports, 2018, 32(23): 4072 -4078 .
[8] WANG Zhonghui, XIN Yong. Molecular Dynamics Simulation on the Relationship of Oxygen Diffusion and Polymer Chains Activity[J]. Materials Reports, 2019, 33(8): 1293 -1297 .
[9] CHANG Jingjing. Spin Coating Epitaxial Films[J]. Materials Reports, 2019, 33(12): 1919 -1920 .
[10] ZHUANG Xiaodong, LI Rongxing, YU Xiaohua, XIE Gang, HE Xiaocai, XU Qingxin. Preparation of Lithium Titanate Electrode Materials by Solid Phase Method[J]. Materials Reports, 2019, 33(16): 2654 -2659 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed