聚合物类型对旧墙瓷砖界面剂性能和微观结构的影响

doi:10.11896/cldb.24030088

材料导报

2026, Vol. 40

Issue (3): 24030088-6 https://doi.org/10.11896/cldb.24030088

高分子与聚合物基复合材料

聚合物类型对旧墙瓷砖界面剂性能和微观结构的影响

吕官记^1,2, 季韬³, 郑明新^1,*, 马亚林³

1 华东交通大学交通运输工程学院,南昌 330013
2 福建商学院管理工程系,福州 350012
3 福州大学土木工程学院,福州 350116

Effects of Polymer Types on the Performance and Microstructure of Interface Agents for Aged Ceramic Wall Tiles

LYU Guanji^1,2, JI Tao³, ZHENG Mingxin^1,*, MA Yalin³

1 College of Transportation Engineering, East China Jiaotong University, Nanchang 330013, China
2 Department of Management Engineering, Fujian Business University, Fuzhou 350012, China
3 College of Civil Engineering, Fuzhou University, Fuzhou 350116, China

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摘要为提高旧墙翻新瓷砖界面剂的性能,分别对掺入四种聚合物(PTB、EVA、VAE及SAE)的界面剂进行对比,测试了其黏结性能(含冻融和风振)、压折比、吸水率和微观结构特征,并结合XRD、FTIR、压汞法(MIP)、SEM试验及孔隙、裂纹分析系统(PCAS)进行机理分析。结果表明:掺入聚合物改性后,增大了界面剂黏结强度(含冻融和风振),减小了界面剂压折比和吸水率。在P/W(聚合物与外加水体积比)为1∶1时,黏结强度(含冻融和风振)排序均为PTBJ(表示PTB界面剂)＞VAEJ＞SAEJ＞EVAJ,压折比排序为SAEJ＞VAEJ＞EVAJ＞PTBJ,吸水率排序为SAEJ＞EVAJ＞VAEJ＞PTBJ。PTBJ呈现更为复杂致密的、不完全连续的空间骨架-基体网状结构体系,具有更高的黏结强度以及较小的压折比和吸水率。本研究可为城市更新中旧墙瓷砖面翻新工程提供理论和试验基础。

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关键词: 界面剂 PTB乳液改性风振冻融

Abstract: To enhance the interfacial performance of renovation agents for old wall tiles, four polymer-modified formulations (PTB, EVA, VAE, and SAE) were evaluated. Systematic assessments of bond strength (including freeze-thaw and wind vibration), compressive-flexural ratio, water absorption, and microstructural characteristics were conducted through XRD, FTIR, mercury intrusion porosimetry(MIP), SEM, and pore and crack analysis system (PCAS) analyses. Results demonstrated that polymer modification significantly improved interfacial bond strength while reducing compressive-flexural ratio and water absorption. When the volume ratio of polymer to external water is 1∶1, the order of bond strength (including freeze-thaw and wind vibration) is PTBJ (representing PTB interface agent)＞VAEJ＞SAEJ＞EVAJ. The order of compressive-flexural ratio is SAEJ＞VAEJ＞EVAJ＞PTBJ. And the order of water absorption is SAEJ＞EVAJ＞VAEJ＞PTBJ. PTBJ exhibits a more complex and dense, yet incomplete, continuous spatial network structure, resulting in enhanced bond strength and reduced compressive-flexural ratio and water absorption. This study provides a theoretical and experimental foundation for optimizing polymer-modified interface agents in urban renewal projects that involve aged ceramic tile surfaces.

Key words: interface agent PTB emulsion modification wind vibration freeze-thaw

发布日期: 2026-02-13

ZTFLH:

TU528.41

基金资助: 国家自然科学基金(51568022);福建省科技厅自然科学基金(2020J01325);江西省自然科学基金重点项目(20242BAB26078)

通讯作者: ^*郑明新,华东交通大学交通运输工程学院教授、博士研究生导师。主要研究方向为滑坡与道路路基病害防治、道路路基设计优化与新型防护结构等。

作者简介: 吕官记,硕士,华东交通大学交通运输工程学院博士研究生。主要研究领域为工程材料、道路路基病害防治。

引用本文:

吕官记, 季韬, 郑明新, 马亚林. 聚合物类型对旧墙瓷砖界面剂性能和微观结构的影响[J]. 材料导报, 2026, 40(3): 24030088-6.
LYU Guanji, JI Tao, ZHENG Mingxin, MA Yalin. Effects of Polymer Types on the Performance and Microstructure of Interface Agents for Aged Ceramic Wall Tiles. Materials Reports, 2026, 40(3): 24030088-6.

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https://www.mater-rep.com/CN/10.11896/cldb.24030088 或 https://www.mater-rep.com/CN/Y2026/V40/I3/24030088

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