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材料导报  2024, Vol. 38 Issue (21): 23040102-11    https://doi.org/10.11896/cldb.23040102
  无机非金属及其复合材料 |
氧化锡电子传输层在正置钙钛矿太阳能电池中的研究进展
赵登婕1,2, 李康宁1,2, 胡李纳1,2, 闫彤1,2, 杨艳坤1,2, 郝阳1,2, 张晨曦1,2,*, 郝玉英1,2,*
1 太原理工大学物理与光电工程学院, 新型传感与智能控制教育部重点实验室,太原 030024
2 山西浙大新材料与化工研究院,太原 030000
Research Progress of Tin Oxide Electron Transport Layer in n-i-p Perovskite Solar Cells
ZHAO Dengjie1,2, LI Kangning1,2, HU Lina1,2, YAN Tong1,2, YANG Yankun1,2, HAO Yang1,2, ZHANG Chenxi1,2,*, HAO Yuying1,2,*
1 College of Physics and Optoelectronics, Key Lab of Advanced Transducers and Intelligent Control System, Taiyuan University of Technology, Taiyuan 030024, China
2 Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering, Taiyuan 030000, China
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摘要 近年来,钙钛矿太阳能电池(Perovskite solar cells, PSCs)由于具有光伏性能优异、材料成本低、制造工艺简单等优势,引起了科研工作者广泛的研究兴趣。在PSCs中,电子传输层(Electron transport layer, ETL)在提取和传输光生电子方面起着至关重要的作用。氧化锡(SnO2)由于具有高光学透过率、高电子迁移率、良好的化学稳定性、合理的能级结构和可低温制备等优异性能,成为PSCs器件中理想的ETL。本文围绕SnO2 ETL在正置PSCs中的研究进展进行综述,首先介绍了SnO2的结构与光电特性,并归纳了SnO2的制备方法,随后对有机无机杂化PSCs及全无机PSCs中SnO2 ETL的改性进行了详细的阐述和总结,包括掺杂及界面修饰处理,最后总结全文,对SnO2 ETL的发展进行展望。
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赵登婕
李康宁
胡李纳
闫彤
杨艳坤
郝阳
张晨曦
郝玉英
关键词:  氧化锡  有机无机杂化  全无机  钙钛矿太阳能电池  掺杂  界面修饰    
Abstract: In recent years, perovskite solar cells (PSCs) have attracted extensive research interest due to their excellent photovoltaic performance, low material cost and simple fabrication process. In PSCs, the electron transport layer (ETL) plays a crucial role in extracting and transporting photogenerated electrons from the perovskite layer to the cathode. Due to its high optical transmittance, high electron mobility, good chemical stability, good match with the energy level structure of the perovskite layer and the ability to be prepared at low temperatures, tin oxide (SnO2) has become an ideal ETL for PSCs. This paper reviews the research progress of SnO2 ETL in n-i-p PSCs, firstly, it introduces the structure and photoelectric characteristics of SnO2, and summarizes the preparation methods of SnO2. And then, the modification of SnO2 ETL in organic-inorganic hybrid PSCs and all-inorganic PSCs is elaborated and summarized in detail, including doping and interface modification. Finally, the full text is summarized and the development of SnO2 ETL is prospected.
Key words:  tin oxide    organic-inorganic hybrid    all-inorganic    perovskite solar cells (PSCs)    doping    interface modification
出版日期:  2024-11-10      发布日期:  2024-11-11
ZTFLH:  TM914  
基金资助: 国家自然科学基金(62074108);国家自然科学基金区域创新与发展联合基金(U21A20102);山西浙大先进材料与化工研究院基金(2022SX-TD019);山西省科技重大专项(20201101012);山西省平台与基地专项(201605D131038);山西省基础研究计划(20210302124629;20210302124163;20210302124392)
通讯作者:  *张晨曦,太原理工大学物理与光电工程学院讲师。2013年太原理工大学化工系化学工程与工艺专业本科毕业,2019年华东师范大学物理系材料与光电子专业博士毕业后到太原理工大学工作至今。目前主要从事钙钛矿材料、新型光电器件等方面的研究工作。发表论文20余篇,包括Advanced Functional Materials、Journal of Materials Che-mistry C、Electrochimica Acta、Nanoscale、Nano-Micro Letters等。zhangchenxi@tyut.edu.cn;郝玉英,太原理工大学物理与光电工程学院教授、博士研究生导师。2006年毕业于太原理工大学,获博士学位。先后主持国家级自然科学基金、山西省重点研发计划等项目10余项,获山西省科学技术奖技术发明二等奖1项,山西省科学技术奖自然科学二等奖1项。目前主要从事钙钛矿/有机太阳能电池优化制备与性能等方面的研究工作。在Advanced Materials、Journal of Materials Che-mistry A、Small、Journal of Materials Chemistry C、ACS Applied Materials & Interfaces、Solar Energy Materials & Solar Cells等国内外高水平学术期刊上发表学术论文60余篇。haoyuying@tyut.edu.cn   
作者简介:  赵登婕,2018年于山西大同大学获得学士学位。现为太原理工大学物理与光电工程学院博士研究生,在郝玉英教授的指导下进行研究。目前主要研究领域为钙钛矿太阳能电池。
引用本文:    
赵登婕, 李康宁, 胡李纳, 闫彤, 杨艳坤, 郝阳, 张晨曦, 郝玉英. 氧化锡电子传输层在正置钙钛矿太阳能电池中的研究进展[J]. 材料导报, 2024, 38(21): 23040102-11.
ZHAO Dengjie, LI Kangning, HU Lina, YAN Tong, YANG Yankun, HAO Yang, ZHANG Chenxi, HAO Yuying. Research Progress of Tin Oxide Electron Transport Layer in n-i-p Perovskite Solar Cells. Materials Reports, 2024, 38(21): 23040102-11.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.23040102  或          http://www.mater-rep.com/CN/Y2024/V38/I21/23040102
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