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材料导报  2024, Vol. 38 Issue (18): 23070037-6    https://doi.org/10.11896/cldb.23070037
  金属与金属基复合材料 |
热障涂层对DD6单晶燃气热腐蚀及力学性能的影响
王玉锋1,2,*, 付前刚1,*, 杨俊3, 张华2, 杨岩2
1 西北工业大学国家卓越工程师学院,西安 710072
2 中国航发动力股份有限公司,西安 710021
3 空军装备部驻西安地区某军事代表室,西安 710021
Effect of TBCs on Gas Thermal Corrosion Resistance and Mechanical Properties of DD6 Single Crystal
WANG Yufeng1,2,*, FU Qiangang1,*, YANG Jun3, ZHANG Hua2, YANG Yan2
1 National Elite Institute of Engineering, Northwestern Polytechnical University, Xi’an 710072, China
2 AECC Aviation Power Co., Ltd., Xi’an 710021, China
3 The Military Representative Office of the Air Force Equipment Department in Xi’an, Xi’an 710021, China
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摘要 DD6单晶高温合金材料以其优异的高温服役性能,在我国多型航空发动机制造领域拥有十分广阔的应用前景。随着我国航空发动机技术的不断发展,燃烧室涡轮前服役温度不断提升,DD6单晶高温合金无法完全满足高温、高压、高转速的服役环境,急需开展DD6单晶表面热障涂层技术研究。鉴于此,本工作采用多弧离子镀技术在DD6单晶高温合金上制备了NiCoCrAlY金属粘结层(BC),然后采用电子束物理气相沉积技术制备了Y2O3·ZrO2(YSZ)陶瓷面层,研究热障涂层对DD6单晶抗燃气热腐蚀及力学性能的影响。结果表明:在900 ℃条件下,燃气热腐蚀性能测试100 h后,DD6合金表面形成了厚度约100 μm的腐蚀疏松结构、孔洞及横向裂纹,DD6合金抗燃气热腐蚀性能较差;BC涂层或YSZ涂层内部未出现Na、K、Ca、Cl、S等腐蚀性元素,BC涂层表面形成了均匀连续的Al2O3层,在其表面粘附的Na2SO4未出现高温分解,腐蚀介质未对BC涂层产生侵蚀;YSZ涂层柱状晶组织具有较好的应变容限,高温时柱状晶膨胀引起柱晶间隙缩小,外部的腐蚀介质无法有效渗入YSZ涂层内部,从而避免了腐蚀介质对涂层或基体的侵蚀破坏。热障涂层对DD6单晶合金980 ℃条件下的抗拉强度σb、屈服强度σ0.2、延伸率δ和断面收缩率ψ无不良影响,断裂模式与未涂覆涂层试样一致,均呈典型的韧性断裂。在980 ℃、250 MPa条件下,涂覆与未涂覆涂层的DD6试样高温持久时间和延伸率δ无明显差异,呈典型的塑性变形和蠕变变形韧性断裂机制。本工作的研究结果为DD6单晶高温合金热障涂层技术的开发与工程化应用奠定了技术支撑。
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王玉锋
付前刚
杨俊
张华
杨岩
关键词:  DD6单晶  热障涂层  燃气热腐蚀  高温持久性能  EB-PVD  金属粘结层    
Abstract: DD6 single crystal high-temperature alloy material has a very broad application prospect in the field of multi type aviation engine manufacturing in China due to its excellent high-temperature service performance. With the continuous development of aviation engine technology in China, the service temperature of the combustion chamber turbine is constantly increasing. DD6 single crystal superalloy cannot fully meet the service environment of high temperature, high pressure, and high speed, and there is an urgent need to research DD6 single crystal surface thermal barrier coating technology. In view of this, this article uses multi arc ion plating technology to prepare NiCoCrAlY metal bonding layer on DD6 single crystal high-temperature alloy, and then uses electron beam physical vapor deposition technology to prepare Y2O3·ZrO2 ceramic surface layer, to study the effect of thermal barrier coating on the gas thermal corrosion resistance and mechanical properties of DD6 single crystal. The results indicate that, after 100 hours of gas hot corrosion performance testing at 900 ℃, a thickness of approximately 100 μm corrosion porosity, pores, and transverse cracks was formed on the surface of DD6. There were no corrosive elements such as Na, K, Ca, Cl, S present inside the BC coating or YSZ coating. A uniform and continuous Al2O3 layer was formed on the surface of the BC coating, and the Na2SO4 adhered to its surface did not undergo high-temperature decomposition. The corrosive medium did not corrode the BC coating. The YSZ coating columnar crystals have good strain tolerance. At high temperatures, the expansion of columnar crystals leads to a reduction in the gap between columnar crystals, and external corrosion media cannot effectively penetrate into the interior of YSZ coating, thus avoiding corrosion damage to the coating or substrate caused by corrosion media. Tensile strength of thermal barrier coating on DD6 single crystal alloy at 980 ℃, there is no adverse effects onσb0.2,δ and ψ, and the fracture mode of the sample is basically consistent. High temperature endurance time and elongation of DD6 single crystal sample coated with thermal barrier coating at 980 ℃,250 MPa, there is no significant difference, and the fracture has a typical dimple fracture morphology, with the fracture mechanism being a ductile fracture mechanism of plastic deformation and creep deformation. Based on the research results of this work, the technical support for the technical development and engineering application of DD6 single crystal super alloy TBCs is established.
Key words:  DD6 single crystal    thermal barrier coatings    gas thermal corrosion resistance    high temperature endurance performance    EB-PVD    metal bond coating
发布日期:  2024-10-12
ZTFLH:  V259  
基金资助: 国家科技重大专项(2017-Ⅶ-0007-0100)
通讯作者:  *付前刚,通信作者,西北工业大学材料学院教授、博士研究生导师。2001年7月获西北工业大学工学学士;2004年4月获西北工业大学工学硕士学位,2007年4月获西北工业大学工学博士学位。主要研究方向为高温抗氧化涂层技术,碳/碳复合材料基体改性技术,碳和碳化硅纳米材料的制备、表征与应用。主持国家重点研发计划、国家自然科学基金杰青、优青、基础科研、国家重大研究计划、教育部科学技术研究重大项目等20余项。作为研究骨干参与国家自然基金创新群体等10余项课题。在Carbon、Journal of American Ceramics Society、Corrosion Science等国际著名学术刊物上发表论文300余篇,他人引用5 000余次。获授权发明专利50余项。fuqiangang@nwpu.edu.cn;wyfeng3705@163.com   
作者简介:  王玉锋,2009年7月、2012年5月分别于济南大学和北京理工大学获得工学学士学位和硕士学位。现为西北工业大学材料学院博士研究生,就职于中国航发动力股份有限公司,在付前刚教授的指导下进行研究工作。目前主要研究领域为航空发动机涡轮部件高温热防护技术;授权国家发明专利11项,获得陕西省科学技术进步奖2项,获得中国航发人才成长奖。
引用本文:    
王玉锋, 付前刚, 杨俊, 张华, 杨岩. 热障涂层对DD6单晶燃气热腐蚀及力学性能的影响[J]. 材料导报, 2024, 38(18): 23070037-6.
WANG Yufeng, FU Qiangang, YANG Jun, ZHANG Hua, YANG Yan. Effect of TBCs on Gas Thermal Corrosion Resistance and Mechanical Properties of DD6 Single Crystal. Materials Reports, 2024, 38(18): 23070037-6.
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http://www.mater-rep.com/CN/10.11896/cldb.23070037  或          http://www.mater-rep.com/CN/Y2024/V38/I18/23070037
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