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材料导报  2024, Vol. 38 Issue (17): 23050159-10    https://doi.org/10.11896/cldb.23050159
  高分子与聚合物基复合材料 |
纳米纤维素的点击反应改性及应用研究进展
龙娟1, 李宇展2, 李志强1,*, 钟土华1,*
1 国际竹藤中心,北京 100102
2 北京科技大学材料科学与工程学院,北京 100083
Research Progress on Click Chemistry Modification and Applications of Nanocellulose
LONG Juan1, LI Yuzhan2, LI Zhiqiang1,*, ZHONG Tuhua1,*
1 International Centre for Bamboo and Rattan, Beijing 100102, China
2 School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
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摘要 纳米纤维素是从植物细胞壁中提取的一种直径小于100 nm的棒状、须状或纤丝状纤维素,具有密度低、可再生、可降解和生物相容性等特性,同时具有模量高、热膨胀系数低等优点。纳米纤维素表面化学性质单一,含有大量羟基,具有强亲水性质,限制了其应用范围。纤维素表面大量活泼的羟基为进行化学改性提供了各种可能性。通过对纳米纤维素进行表面化学修饰或功能化以拓展其应用领域。点击化学具有高度选择性、模块化、产率高、反应迅速等优点,反应条件相对简单,对水、氧气都不敏感。近年来,点击化学越来越多地被用于纳米纤维素的化学改性和功能化。本文主要综述了点击化学中叠氮-炔基和硫醇-烯烃两类反应用于纳米纤维素改性的研究进展,简单概述了点击反应改性的纳米纤维素在复合材料、水凝胶和气凝胶等方面的应用,最后总结了基于点击化学策略制备、改性和应用纳米纤维素所面临的困难和挑战。
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龙娟
李宇展
李志强
钟土华
关键词:  纳米纤维素  点击化学  叠氮-炔基点击反应  硫醇-烯烃点击反应  纳米材料    
Abstract: Nanocellulose is a type of cellulose with a diameter smaller than 100 nm, which is extracted from plant cell walls and can be rod-, whisker- and fiber-shaped. Nanocellulose possesses impressive features, including low density, renewability, biodegradability, biocompatibility, high modulus and low thermal expansion coefficient, and so on . The chemical properties of nanocellulose are monotonous due to the abundance of active hydroxyl groups on its surface, which makes it strong hydrophilicity and therefore limits its applications. The abundant hydroxyl groups on the cellulose surface provide a wide range of possibilities for chemical modifications and functionalization. Further chemical modification and functionalization can help expand the scope of their applications. Click chemistry possesses remarkable advantages such as high selectivity, modula-rization, high yield, rapid reaction, and so on. The click reaction is simple and is not sensitive to water or oxygen. In recent years, click chemistry has been increasingly applied for the chemical modification and functionalization of nanocellulose. In this review, the research progress on the applications of two main types of click reactions, i. e. azide-alkyne and thiol-ene, in the modification and functionalization of nanocellulose is mainly introduced, and the applications of click-modified nanocellulose used in composites, hydrogels, aerogels are also briefly summarized. Finally, difficulties and challenges facing the preparation, modification, and applications of nanocellulose based on the ‘click chemistry' strategy are summarized.
Key words:  nanocellulose    click chemistry    azide-alkyne click reaction    thiol-ene click reaction    nanomaterial
出版日期:  2024-09-10      发布日期:  2024-09-30
ZTFLH:  TQ352.2  
基金资助: 国际竹藤中心基本科研业务费项目(1632022025;1632023017)
通讯作者:  *李志强,国际竹藤中心研究员。2004年河北工业大学化学工程与工艺专业毕业,获学士学位;2007年北京化工研究院工业催化专业毕业,获硕士学位;2010年中国林科院木材科学与技术专业毕业,获工学博士学位。2011年7月至2012年1月作为访问学者,赴美国威斯康星大学和林产品研究院开展生物乙醇化学预处理研究工作。自2010年以来致力于竹藤生物质液体燃料及化学品的研究,主要从事竹子制取生物乙醇和乳酸、竹材纤维素糖化、竹半纤维素提取利用和竹材催化液化等技术与机理研究。先后主持国际竹藤中心基本科研业务费项目4项,外专局引智项目1项,参与“十二五”科技支撑计划项目1项,“十三五”重点研发计划项目1项。在国内外核心刊物上发表学术论文30余篇,获得发明专利10余项。主编和参加编著《木材生物降解与保护》等学术专著2部。参与起草制定国家标准3项。入选国家林业和草原科技创新领军人才和百千万人才工程省部级人选。lizq@icbr.ac.cn;
钟土华,国际竹藤中心副研究员。2008年6月华南农业大学木材科学与工程专业本科毕业,2011年6月华南农业大学木材科学与技术专业硕士毕业,2015年12月美国西弗吉尼亚大学森林资源科学专业博士毕业,2016年3月至2020年10月在美国华盛顿州立大学复合材料与工程中心进行博士后研究。2020年10月到国际竹藤中心工作至今,主持国际竹藤中心基本科研业务费人才和团队培育项目3项,主持“十四五”国家重点研发计划子课题项目,主要从事竹/木纳米材料制备、改性和应用等方面的研究工作。发表论文40余篇,包括Cellulose、Carbohydrate Polymers、ACS Sustainable Chemistry & Engineering等。zhongth@icbr.ac.cn   
作者简介:  龙娟,2021年6月毕业于广西中医药大学并获得工学学士学位。现为国际竹藤中心硕士研究生,主要从事竹基纳米纤维素制备和改性等方面的研究工作。
引用本文:    
龙娟, 李宇展, 李志强, 钟土华. 纳米纤维素的点击反应改性及应用研究进展[J]. 材料导报, 2024, 38(17): 23050159-10.
LONG Juan, LI Yuzhan, LI Zhiqiang, ZHONG Tuhua. Research Progress on Click Chemistry Modification and Applications of Nanocellulose. Materials Reports, 2024, 38(17): 23050159-10.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.23050159  或          http://www.mater-rep.com/CN/Y2024/V38/I17/23050159
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