镁合金表面化学转化涂层研究进展

doi:10.11896/cldb.23010121

材料导报

2024, Vol. 38

Issue (12): 23010121-12 https://doi.org/10.11896/cldb.23010121

金属与金属基复合材料

镁合金表面化学转化涂层研究进展

肖雯心¹, 王叶¹, 马凯¹, 代朝能¹, 裴三略¹, 王丹芊¹, 王敬丰^1,2,*

1 重庆大学材料科学与工程学院,重庆 400045
2 重庆大学国家镁合金材料工程技术研究中心,重庆 400044

Research Progress of Chemical Conversion Coatings on Magnesium Alloys

XIAO Wenxin¹, WANG Ye¹, MA Kai¹, DAI Chaoneng¹, PEI Sanlue¹, WANG Danqian¹, WANG Jingfeng^1,2,*

1 College of Materials Science and Engineering, Chongqing University, Chongqing 400045, China
2 National Engineering Research Center for Magnesium Alloys, Chongqing University, Chongqing 400044, China

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摘要作为最具潜力的轻量化材料,镁及镁合金具有密度低、比强度高、生物相容性好、电磁屏蔽强等优点,在生物医学、电子器件乃至建筑工程领域都受到了广泛关注。然而,镁在某些使用场景中容易发生腐蚀,因此找到最合适的使用场景以及在使用场景下提供足够的保护是镁及镁合金的重要研究课题。通过表面处理技术在基体上制备保护涂层是提高镁及镁合金耐蚀性的有效方法。现有的表面处理技术有很多种,如气相沉积技术、阳极氧化、电镀和化学镀、激光束改性技术、离子注入、化学转化技术等。其中化学转化技术具有成本低、制备简单、处理效率高等优点且不需要复杂昂贵的设备,对样品几何形状也没有限制。本文基于近年来国内外化学转化涂层的发展,综述了镁合金在生物医用、电子器件以及建筑工程领域化学转化涂层的研究现状,并对不同领域化学转化涂层的发展进行了展望。

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	肖雯心
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	王敬丰

关键词: 镁合金耐蚀性表面处理化学转化涂层

Abstract: Magnesium alloy has been considered as a promising material due to its low density, high specific strength, good biocompatibility and strong electromagnetic shielding. Therefore, it has attracted wide attention in the applications of biomedicine, electronic devices and even building engineering. The weak anticorrosion is the main reason for restricting the application of magnesium alloys, so it is important for them to find the most suitable application scenario and take protection measures to develop high performance. In order to increase the corrosion resistance, the most effective method is the surface modification techniques, including vapor deposition technology, anodic oxidation, electroplating and electroless plating, laser beam modification technology, ion implantation, chemical conversion technology, etc. Among them, chemical conversion technology has the advantages of low costs, simple preparations, high processing efficiencies, no need for complex and expensive equipment, and no limit to the sample geometry. Based on the development of chemical conversion coatings at home and abroad in recent years, the research progress of chemical conversion coatings on magnesium alloys in the fields of biomedicine, electronic devices and building engineering are reviewed, and the future development of chemical conversion coatings in these fields are prospected.

Key words: magnesium alloys corrosion resistance surface modification techniques chemical conversion coatings

出版日期: 2024-06-25 发布日期: 2024-07-17

ZTFLH:

TG178

基金资助: 国家重点研发计划(2021YFB3701100);国家自然科学基金资助项目(U20A20234;51874062);重庆市自然科学基金重点项目(cstc2019jcyj-zdxmX0010);山西省科技重大专项(20191102008);山东省重大科技创新工程项目(2019JZZY020329)

通讯作者: *王敬丰,重庆大学材料科学与工程学院教授、博士研究生导师。1993年武汉大学物理系本科毕业,2004年于华中科技大学材料学院硕博连读毕业,2005年到重庆大学工作至今。目前主要从事新型结构功能一体化镁合金(高性能可控降解镁合金、高性能阻尼减振镁合金、高性能阻燃镁合金)及其制备成形技术、新型镁电池、镁合金塑性成形与组织性能调控等方面的研究工作。已主持国家重点研发计划项目/课题、国家科技支撑计划项目、国家973项目子课题、国家自然基金重点项目、科技部国际科技合作项目、重庆市科技重点项目等国家级和省部级科研项目20余项,发表SCI论文150余篇,获权国家发明专利40余件、申请国际PCT专利3件,获批国家/国际标准牌号4个,主持/参与制定国家标准4项、国际标准2项。jfwang@cqu.edu.cn

作者简介: 肖雯心,2022年6月于华南农业大学大学获得工学学士学位。现为重庆大学材料科学与工程学院硕士研究生,在王敬丰教授的指导下进行研究。目前主要研究领域为建筑镁合金表面改性。

引用本文:

肖雯心, 王叶, 马凯, 代朝能, 裴三略, 王丹芊, 王敬丰. 镁合金表面化学转化涂层研究进展[J]. 材料导报, 2024, 38(12): 23010121-12.
XIAO Wenxin, WANG Ye, MA Kai, DAI Chaoneng, PEI Sanlue, WANG Danqian, WANG Jingfeng. Research Progress of Chemical Conversion Coatings on Magnesium Alloys. Materials Reports, 2024, 38(12): 23010121-12.

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http://www.mater-rep.com/CN/10.11896/cldb.23010121 或 http://www.mater-rep.com/CN/Y2024/V38/I12/23010121

1 Li T, Leng Z J, Wang S F, et al. Journal of Magnesium and Alloys, 2021, 11, 18.
2 Nguyen T L, Cheng T C, Yang J Y, et al. Journal of Materials Research and Technology, 2022, 19, 2965.
3 Pereira G S, Ramirez O M P, Avila P R T, et al. Corrosion Science, 2022, 206, 110527.
4 Peng F, Zhang D D, Liu X Y, et al. Journal of Magnesium and Alloys, 2021, 9 (5), 1471.
5 Liu S Q, Qi Y M, Peng Z J, et al. Surface and Coatings Technology, 2021, 406, 126655.
6 Zhang Y Y, Xu K L, Liu B, et al. International Journal of Hydrogen Energy, 2022, 47 (67), 29172.
7 Salman S A, Gouda M K. Materials Today:Proceedings, 2022, 62, 611.
8 Yu G, Liu Y L, Li Y, et al. The Chinese Journal of Nonferrous Metals, 2022(6), 1087.
余刚, 刘跃龙, 李瑛, 等. 中国有色金属学报, 2022(6), 1087.
9 Zhang Y J, Yan C W, Wang F H, et al. Materials Protection, 2002(4), 4.
张永君, 严川伟, 王福会, 等. 材料保护, 2002(4), 4.
10 Zhang W Q, Shan D Y, Zeng R C, et al. Materials Protection, 2002(7), 1.
周婉秋, 单大勇, 曾荣昌, 等. 材料保护, 2002(7), 1.
11 Zeng A P, Xue Y, Qian Y F, et al. Corrosion & Protection, 2000(2), 55.
曾爱平, 薛颖, 钱宇峰, 等. 腐蚀与防护, 2000(2), 55.
12 Li Y, Yu G, Liu Y L, et al. Surface Technology, 2003(2), 1.
李瑛, 余刚, 刘跃龙, 等. 表面技术, 2003(2), 1.
13 Li L C, Gao J C, Wang Y. Surface & Coatings Technology, 2004, 185(1), 92.
14 Yuan G Y, Zhang X B, Niu J L, et al. The Chinese Journal of Nonferrous Metals, 2011, 21(10), 2476.
袁广银, 章晓波, 牛佳林, 等. 中国有色金属学报, 2011, 21(10), 2476.
15 Zhang Y Q, Zhao J N, Bao N R, et al. Chinese Journal of Tissue Engineering Research, 2018, 22(22), 3589.
张永强, 赵建宁, 包倪荣, 等. 中国组织工程研究, 2018, 22(22), 3589.
16 Barajasa J, Joyaa J, Durán K, et al. Surface & Coatings Technology, 2019, 374, 424.
17 Mohan S P, Ravichandran K, Sankara N T. Journal of Magnesium and Alloys, 2022, 10 (1), 295.
18 Mao L, Zhu H W, Chen L, et al. Journal of Materials Research and Technology, 2020, 9 (3), 6409.
19 Shadanbaz S, Dias G J. Acta Biomaterialia, 2012, 8 (1), 20.
20 Liu G X, Wang J Y, Bian K K, et al. Materials Letters, 2017, 209, 323.
21 Li C L, Yao X H, Hang R Q, et al. Colloids and Surfaces B:Biointerfaces, 2021, 197, 111426.
22 Kotoka R, Yamoah N K, Mensah-Darkwa K, et al. Surface and Coatings Technology, 2016, 292, 99.
23 Sun J E, Cai S, Sun J Y, et al. Ultrasonics Sonochemistry, 2019, 58, 104677.
24 You M Y, Echeverry-Rendón M, Zhang L, et al. Materials Science and Engineering:C, 2021, 120, 111734.
25 Prabhu D, Gopalakrishnan P, Ravi K. Journal of Alloys and Compounds, 2020, 812, 152146.
26 Popa M, Stefan L M, Prelipcean A M, et al. Corrosion Science, 2022, 209, 110775.
27 Liu H L, Gu J Y, Tong Z P, et al. Materials Today Communications, 2022, 31, 103678.
28 Saranya K, Kalaiyarasan M, Rajendran N. Surface and Coatings Techno-logy, 2019, 378, 124902.
29 Saranya K, Kalaiyarasan M, Agilan P, et al. Surfaces and Interfaces, 2022, 31, 101948.
30 Zai W, Zhang X R, Su Y C, et al. Surface and Coatings Technology, 2020, 397, 125919.
31 Trang L T, Cao N Q, Hiromoto S, et al. Surface and Coatings Technology, 2022, 444, 128639.
32 Kalaiyarasan M, Pugalmani S, Rajendran N. Journal of Magnesium and Alloys, 2022, 11, 85.
33 Hu G W, Zeng L C, Du H, et al. Surface and Coatings Technology, 2017, 325, 127.
34 Xue K, Tan P H, Zhao Z H, et al. Journal of Materials Science & Technology, 2023, 132, 179.
35 Liu L, Yang Q Y, Huang L, et al. Applied Surface Science, 2019, 484, 511.
36 Mu S L, Du J, Jiang H, et al. Surface and Coatings Technology, 2014, 254, 364.
37 Wu F, Zhang S, Tao Z. Materials and Corrosion, 2011, 62 (3), 234.
38 Zhou P, Yang L, Hou Y, et al. Corrosion Communications, 2021, 1, 47.
39 Guo L S, Yu B X, Zhou P, et al. Corrosion Science, 2021, 183, 109329.
40 Hu L F, Meng Q S, Chen S P, et al. Applied Surface Science, 2012, 259, 816.
41 Xue Z Y, Li X J, Chu J H, et al. Journal of Magnesium and Alloys, 2022, 5, 55.
42 Wang G X, Zhang M L, Wu R Z. Applied Surface Science, 2012, 258 (7), 2648.
43 Jian S Y, Chu Y R, Lin C S. Corrosion Science, 2015, 93, 301.
44 Zhang S T, Wu F J. Surface and Interface Analysis, 2011, 43 (3), 752.
45 Fekry A M, Ghoneim A A, Ameer M A. Surface and Coatings Technology, 2014, 238, 126.
46 Duan G Q, Yang L X, Liao S J, et al. Corrosion Science, 2018, 135, 197.
47 Wu Z X, Ahmad R, Yin B L, et al. Science, 2018, 359 (6374), 447.
48 Wang Y, Wu G S, Xu, C, et al. Materials Letters, 2021, 285, 129047.
49 Wang Y, You Z P, Pei S L, et al. Journal of Magnesium and Alloys, 2023, 8, 47.
50 Wang D Q, Wang Y, Wang J X, et al. Construction and Building Materials, 2022, 325, 126745.
51 Wang Y, Wu G S, Sun J P. Scanning, 2020, 2020, 1.
52 Wang Y, Wu G S. Scanning, 2021, 2021, 1.
53 Wang Y, You Z P, Ma K, et al. Corrosion Science, 2023, 211, 110841.
54 Cui L Y, Liu H P, Zhang W L, et al. Journal of Materials Science & Technology, 2017, 33 (11), 1263.

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