超临界二氧化碳输送管道内腐蚀研究进展

doi:10.11896/cldb.22120216

材料导报

2024, Vol. 38

Issue (12): 22120216-8 https://doi.org/10.11896/cldb.22120216

金属与金属基复合材料

超临界二氧化碳输送管道内腐蚀研究进展

高怡萱^1,2,3, 潘杰^1,3,*, 李焰^2,*, 张建^1,3, 李阳³

1 中石化石油工程设计有限公司,山东东营 257000
2 中国石油大学(华东)材料科学与工程学院,山东青岛 266580
3 中国石化碳捕集、利用与封存(CCUS)重点实验室,山东东营 257000

Research Progress on the Corrosion of the Inner Surface of Pipeline Used for Transporting Supercritical Carbon Dioxide

GAO Yixuan^1,2,3, PAN Jie^1,3,*, LI Yan^2,*, ZHANG Jian^1,3, LI Yang³

1 SINOPEC Petroleum Engineering Corporation, Dongying 257000, Shandong, China
2 School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, Shandong, China
3 SINOPEC Key Lab of Carbon Capture, Utilization and Storage (CCUS), Dongying 257000, Shandong, China

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摘要碳捕集、利用与封存技术(CCUS)是目前实现化石能源低碳化利用和碳中和的关键途径。随着CCUS技术的不断发展,超临界二氧化碳(CO₂)输送管道的内腐蚀问题势必成为影响输碳管道工程安全运维的痛点之一。管线钢在超临界CO₂环境中的腐蚀行为和机理与传统油气田CO₂腐蚀有着较大不同,是一种在全新环境体系下的腐蚀问题。本文以水相介质导致超临界CO₂管道内腐蚀这一主要诱因为线索,综述了杂质、温度、压力以及流速等因素对典型管线钢在超临界工况下的CO₂内腐蚀行为的影响,尤其针对含水量这一关键因素进行了详述和对比,分析了当前超临界CO₂管输过程中仍然存在的腐蚀与防护问题以及挑战,最后对超临界CO₂腐蚀问题未来的重点关注方向进行了展望,结论有助于优化未来输碳管道工程设计与制定对应的腐蚀控制方法。

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	高怡萱
	潘杰
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	李阳

关键词: 超临界二氧化碳管线钢腐蚀

Abstract: Carbon capture, utilization and storage (CCUS) is a key method to achieve low carbon utilization and carbon neutrality of fossil energy. With the continuous development of CCUS technology, the internal corrosion problem of supercritical carbon dioxide (CO₂) transportation pipeline has gradually become one of the key pain points affecting the safe operation of CO₂ transportation pipeline. The corrosion behavior and mechanism of pipeline steel in supercritical CO₂ medium are quite different from that of traditional CO₂ corrosion happened in oil & gas environment, which is a bran-new corrosion problem research system. This paper reviews the influence of impurities, temperature, pressure and flow rate on the CO₂ internal corrosion behavior of typical pipeline steels under supercritical conditions and the main incentive of supercritical CO₂ pipeline corrosion caused by aqueous medium is taken as a clue. The water content is detailly discussed and compared especially. Generally, the future focus on the supercritical CO₂ corrosion issues is prospected. The challenges that still exist in the current supercritical CO₂ pipeline transportation process are analyzed as well. The conclusions are helpful to guide the design optimization of future carbon pipeline engineering and develop corresponding corrosion control methods.

Key words: supercritical CO₂ pipeline steel internal corrosion

出版日期: 2024-06-25 发布日期: 2024-07-17

ZTFLH:

TG178

基金资助: 中国工程院战略研究与咨询项目

通讯作者: *潘杰,中石化石油工程设计有限公司博士后。2021年中国石油大学(华东)材料科学与工程学院材料科学与工程专业博士研究生毕业,2021—2022年到法国索邦大学交流学习,2022年5月至今在中石化石油工程设计有限公司博士后工作站工作。目前主要从事油气管道内腐蚀、金属材料表面处理等方面的研究工作。发表Corrosion Science等国内外高水平论文10余篇,授权发明专利1项。 panjie1061512@sina.com
李焰,中国石油大学(华东)材料科学与工程学院教授、博士研究生导师。主要从事腐蚀与防护方面的研究,主持各类科研项目30余项,获得4项人才基金项目资助,荣获中国石油和化工自动化行业科学技术奖一等奖、山东省科学技术进步一等奖、中国科学院卢嘉锡青年人才奖、青岛市青年科技奖等诸多奖项,发表论文(著)100余篇(部),其中SCI、EI核心期刊60余篇,被SCI他人引用2 000余次、授权发明专利20余项。yanlee@upc.edu.cn

作者简介: 高怡萱,2021年6月毕业于青岛农业大学获得工学学士学位。现为中国石油大学(华东)材料科学与工程学院硕士研究生,在李焰教授的指导下进行研究。目前主要研究领域为装备材料工程。

引用本文:

高怡萱, 潘杰, 李焰, 张建, 李阳. 超临界二氧化碳输送管道内腐蚀研究进展[J]. 材料导报, 2024, 38(12): 22120216-8.
GAO Yixuan, PAN Jie, LI Yan, ZHANG Jian, LI Yang. Research Progress on the Corrosion of the Inner Surface of Pipeline Used for Transporting Supercritical Carbon Dioxide. Materials Reports, 2024, 38(12): 22120216-8.

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http://www.mater-rep.com/CN/10.11896/cldb.22120216 或 http://www.mater-rep.com/CN/Y2024/V38/I12/22120216

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