可逆锌-空气电池锌阳极研究进展及挑战

doi:10.11896/cldb.23040162

材料导报

2024, Vol. 38

Issue (6): 23040162-10 https://doi.org/10.11896/cldb.23040162

电化学能源材料与器件

可逆锌-空气电池锌阳极研究进展及挑战

王越, 周本基, 徐能能^*, 乔锦丽^*

东华大学环境科学与工程学院,纤维材料改性国家重点实验室,上海 201600

Research Progress and Challenges of Anode for Reversible Zinc-Air Batteries

WANG Yue, ZHOU Benji, XU Nengneng^*, QIAO Jinli^*

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Environmental Science and Engineering, Donghua University, Shanghai 201600, China

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摘要锌-空气电池因安全性高、容量大、成本低和环境友好等特点而受到广泛关注。其中,锌-空气电池阴极双功能催化剂的设计开发取得了突破性进展。因此,锌阳极的可逆性成为决定锌-空气电池充放电性能的关键。然而,锌阳极仍面临枝晶、形变、钝化、析氢腐蚀等严重挑战,直接阻碍了可逆锌-空气电池的实际应用。为此,本文从枝晶形成、电极形变、钝化、析氢腐蚀四个方面系统介绍了锌阳极研究现状;讨论了添加剂、涂层、隔膜和充电方式对锌枝晶生长的影响;提出了电极形变的机理和常见解决方案;归纳了锌阳极发生钝化的关键因素和影响机制;分析了合金组分对析氢腐蚀的抑制。最后,基于锌阳极当前的主要研究现状,本文展望了获得稳定可逆锌阳极的多种策略及研究方向。

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	王越
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关键词: 可逆锌空气电池锌阳极枝晶生长形变钝化析氢腐蚀

Abstract: Zinc-air battery has attracted wide attention because of its high safety, large capacity, low cost and environmental friendliness. Among them, the design and development of cathode bifunctional catalyst for zinc-air battery has made breakthrough progress. Therefore, the reversibility of zinc anode has become the key to determine the charging and discharging performance of zinc-air battery. However, the zinc anode still faces serious challenges such as dendrite, deformation, passivation and hydrogen evolution corrosion, which directly hinders the practical application of reversible zinc-air batteries. Therefore, this paper systematically introduces the research status of zinc anode from four aspects, dendrite formation, electrode deformation, passivation and hydrogen evolution corrosion. The effects of additives, coatings, separators and charging methods on the growth of zinc dendrites are discussed. The mechanism of electrode deformation and common solutions are studied. The key factors and influencing mechanism of zinc anode passivation are summarized. The inhibition of alloy components on hydrogen evolution corrosion is analyzed. Finally, based on the current research status of zinc anode, this paper looks forward to various strategies and research directions for obtaining stable and reversible zinc anode.

Key words: zinc-air battery zinc anode dendrite growth shape change passivation hydrogen evolution corrosion

出版日期: 2024-03-25 发布日期: 2024-04-07

ZTFLH:

TM911

基金资助: 中央高校基本科研业务费专项资金(2232022D-18);上海市扬帆计划(22YF1400700);国家自然科学基金面上项目(21972017)

通讯作者: ^*徐能能,东华大学副研究员、硕士研究生导师。2019年获东华大学环境科学与工程工学博士学位,并在美国University of Louisiana at Lafayatee开展联合培养、博士后以及助理教授等研究工作,长期致力于能源环境材料的开发、设计及应用,包括小分子电催化电极材料结构优化、电极表界面调控及高比能锌空气电池/燃料电池等;发表期刊论文40余篇,授权发明/实用新型专利16项;先后主持/参与了美国能源部/国家自然基金项目、上海市启明星计划扬帆专项以及中央高校基础研究项目等项目。
乔锦丽,东华大学教授,先进电化学能源学术带头人。获日本独立行政法人山口大学大学院物质工学(应用电化学)博士学位。随后于日本产业技术综合研究所(AIST)任研究员。长期专注于先进电化学能源存储和转换材料与器件,包括燃料电池、金属空气电池、CO₂电化学还原等领域的基础研究和应用研究。以第一/通信作者发表期刊论文230余篇,撰写/编著电化学能源系列英文专著6部/10章节,获日本/中国发明专利授权40余项。入选"全球前2%顶尖科学家榜单"(World's Top 2% Scientists,终身科学影响力)。先后主持国家面上/联合/重大前瞻项目以及国家重点研发计划政府间专项等。

作者简介: 王越,2020年6月于中北学院获得工学学士学位。现为东华大学环境科学与工程学院硕士研究生,师从东华大学乔锦丽教授。目前主要研究领域为锌-空气电池锌阳极设计、调控及性能优化。

引用本文:

王越, 周本基, 徐能能, 乔锦丽. 可逆锌-空气电池锌阳极研究进展及挑战[J]. 材料导报, 2024, 38(6): 23040162-10.
WANG Yue, ZHOU Benji, XU Nengneng, QIAO Jinli. Research Progress and Challenges of Anode for Reversible Zinc-Air Batteries. Materials Reports, 2024, 38(6): 23040162-10.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.23040162 或 https://www.mater-rep.com/CN/Y2024/V38/I6/23040162

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