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材料导报  2024, Vol. 38 Issue (6): 22120129-8    https://doi.org/10.11896/cldb.22120129
  高分子与聚合物基复合材料 |
地下水低渗透区重非水相液体(DNAPL)的增渗增移技术综述
黄霄伊1, 代朝猛1,*, 游学极1, 李思1, 童汪凯1, 李继香2
1 同济大学土木工程学院,上海 200092
2 中国科学院上海高等研究院,上海 200120
Enhancing the Permeability and Migration of DNAPL in Low-permeability Zones of Groundwater: a Technological Review
HUANG Xiaoyi1, DAI Chaomeng1,*, YOU Xueji1, LI Si1, TONG Wangkai1, LI Jixiang2
1 College of Civil Engineering, Tongji University, Shanghai 200092, China
2 Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 200120, China
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摘要 重非水相液体(DNAPL)是一种物化性质稳定且毒性较强的有机污染物,对人类健康和生态环境存在极大威胁。由于其密度较大、穿透性强,DNAPL渗入地下后易在低渗透区积聚,形成长期污染源。低渗透区流速慢、传质难的特点使得常用地下水污染修复技术难以奏效,而目前针对该问题的系统性研究尚显不足,因此亟需梳理并总结通过增渗增移DNAPL实现低渗透区污染增效修复的方法,为后续研究提供一定参考价值。本文首先通过控制方程描述了增渗增移的原理;其次综述了两种分别以表面活性剂和电动为核心的增渗增移方法:表面活性剂通过胶束增溶和降低吸附实现增渗增移,电动则通过电渗和电迁移增移DNAPL;同时介绍了实际应用中耦合其他技术的案例,总结优缺点;最后对DNAPL未来的发展方向进行了展望。
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黄霄伊
代朝猛
游学极
李思
童汪凯
李继香
关键词:  重非水相液体(DNAPL)  低渗透区  增渗增移  表面活性剂  电动    
Abstract: Dense non-aqueous phase liquids (DNAPL) is a kind of organic pollutant with stable physicochemical properties and strong toxicity, which poses a great threat to human health and the ecological environment. Due to its high density and strong penetration, DNAPL tends to accumulate in low-permeability zones, forming a long-term source of pollution. The slow flow rate and difficult mass transfer in low-permeability zones make frequently-used remediation methods ineffective, whereas the systematic research focusing on this issue is insufficient. Therefore, it is urgent to summarize the methods of enhancing permeability and migration of DNAPL which are aimed to promote pollutant remediation in low-permeability zones, so that it can serve as the reference for subsequent research. In this paper, firstly, the principle of aforementioned enhancement was delineated through the governing equation. Secondly, mechanisms underlying two methods of enhancing permeability and migration of DNAPL respectively based on surfactants and electrokinetics were summarized: surfactants enhance permeability and migration by micelle solubilizing and reducing adsorption, while electrokinetics enhances migration by electroosmotic flow and electromigration. Additionally, cases using coupling methodologies in practical applications and their effectiveness and feasibility were described. Finally, the future development direction was prospected.
Key words:  dense non-aqueous phase liquids (DNAPL)    low-permeability zones    enhancing permeability and migration    surfactant    electrokinetics
出版日期:  2024-03-25      发布日期:  2024-04-07
ZTFLH:  X523  
基金资助: 国家重点研发计划(2019YFE0114900);上海市扬帆计划(22YF1450200);国家自然科学基金(42077175;52270164)
通讯作者:  *代朝猛,同济大学土木学院研究员、博士研究生导师。2007年于郑州大学获得硕士学位,2011年获得同济大学和德国柏林工业大学博士学位。主要研究方向为地下水安全保障理论与技术、新型环境功能材料在地下水安全修复中的应用、地下水中污染物迁移转化规律及模拟。近年在国内外核心期刊上发表论文100余篇,主编专著2部,授权国家专利20余项。   
作者简介:  黄霄伊,2022年6月于河海大学获得工学学士学位。现为同济大学土木工程学院硕士研究生,在代朝猛教授的指导下进行研究。目前主要研究方向为地下水低渗透区重非水相液体的增渗增移。
引用本文:    
黄霄伊, 代朝猛, 游学极, 李思, 童汪凯, 李继香. 地下水低渗透区重非水相液体(DNAPL)的增渗增移技术综述[J]. 材料导报, 2024, 38(6): 22120129-8.
HUANG Xiaoyi, DAI Chaomeng, YOU Xueji, LI Si, TONG Wangkai, LI Jixiang. Enhancing the Permeability and Migration of DNAPL in Low-permeability Zones of Groundwater: a Technological Review. Materials Reports, 2024, 38(6): 22120129-8.
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http://www.mater-rep.com/CN/10.11896/cldb.22120129  或          http://www.mater-rep.com/CN/Y2024/V38/I6/22120129
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