Please wait a minute...
《材料导报》期刊社  2017, Vol. 31 Issue (12): 73-78    https://doi.org/10.11896/j.issn.1005-023X.2017.012.016
  材料研究 |
细晶Mg-Ce中间合金的制备及其对AZ91D组织和性能的影响*
董天顺, 王拓, 郑晓东, 周秀锴, 刘金海, 李国禄, 崔春翔
河北工业大学材料科学与工程学院, 天津 300132
Preparation of Fine-grained Mg-Ce Master Alloy and Its Effect on Microstructure and Properties of AZ91D
DONG Tianshun, WANG Tuo, ZHENG Xiaodong, ZHOU Xiukai, LIU Jinhai, LI Guolu, CUI Chunxiang
School of Material Science and Engineering, Hebei University of Technology, Tianjin 300132
下载:  全 文 ( PDF ) ( 2370KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 为了探索细晶Mg-Ce中间合金对AZ91D的变质效果,通过铜模喷铸法制备了细晶Mg-Ce中间合金,在此基础上研究了其对AZ91D组织和性能的影响。结果表明:经过铜模喷铸获得的细晶Mg-Ce中间合金中Mg12Ce相的平均尺寸由50 μm下降至10 μm,相比于粗晶Mg-Ce中间合金,组织显著细化;细晶Mg-Ce中间合金的变质效果好于粗晶Mg-Ce中间合金,采用细晶Mg-Ce中间合金变质的AZ91D相较于粗晶Mg-Ce中间合金变质的AZ91D,抗拉强度提高了5.23%,延伸率提高了15.14%,维氏硬度提高了6.92%,腐蚀速率降低了44.62%。因此,铜模喷铸是提高Mg-Ce中间合金变质效果的有效手段。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
董天顺
王拓
郑晓东
周秀锴
刘金海
李国禄
崔春翔
关键词:  铜模喷铸  细晶Mg-Ce中间合金  AZ91D    
Abstract: In order to research the modification effect of fine-grained Mg-Ce master alloy on AZ91D, fine-grained Mg-Ce master alloy was prepared by copper mold inject casting and the influence of it on the microstructure and properties of AZ91D alloy was investigated. Results showed that the size of Mg12Ce phase in fine-grained Mg-Ce master alloy was reduced from 50 μm to 10 μm, which indicated the fine-grained Mg-Ce master alloy had been refined dramatically. The modification effect of fine-grained Mg-Ce master alloy was better than that of coarse-grained Mg-Ce master alloy. Compared with AZ91D modified by coarse-grained Mg-Ce master alloy, the tensile strength, elongation rate and Brinell hardness of AZ91D modified by fine-grained Mg-Ce master alloy increased by 5.23%, 15.14% and 6.92% respectively, and the corrosion rate decreased by 44.62%. Therefore, copper mold inject casting is an effective way to improve the modification effect of Mg-Ce master alloy.
Key words:  copper mold inject casting    fine-grained Mg-Ce master alloy    AZ91D
               出版日期:  2017-06-25      发布日期:  2018-05-08
ZTFLH:  TG146.2  
基金资助: *河北省高等学校科学技术研究项目(ZD2014040);河北省自然科学基金重点项目(E2016202406);河北工业大学博士科研启动经费资助
作者简介:  董天顺:男,1968年生,副教授,从事新型材料及加工技术研究 E-mail:dongtianshun111@163.com
引用本文:    
董天顺, 王拓, 郑晓东, 周秀锴, 刘金海, 李国禄, 崔春翔. 细晶Mg-Ce中间合金的制备及其对AZ91D组织和性能的影响*[J]. 《材料导报》期刊社, 2017, 31(12): 73-78.
DONG Tianshun, WANG Tuo, ZHENG Xiaodong, ZHOU Xiukai, LIU Jinhai, LI Guolu, CUI Chunxiang. Preparation of Fine-grained Mg-Ce Master Alloy and Its Effect on Microstructure and Properties of AZ91D. Materials Reports, 2017, 31(12): 73-78.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.012.016  或          http://www.mater-rep.com/CN/Y2017/V31/I12/73
1 Zhang Jinghuai,Leng Zhe,Zhang Milin,et al. Effect of Ce on microstructure,mechanical properties and corrosion behavior of high-pressure die-cast Mg-4Al-based alloy [J].J Alloys Compd,2011,509(3):1069.
2 Niu Jiexin,Chen Qiurong,Xu Naixin,et al. Effect of combinative addition of strontium and rare earth elements on corrosion resistance of AZ91D magnesium alloy [J]. Trans Nonferr Met Soc China,2008,18(5):1058.
3 Ma Guolong,Han Guang,Liu Xiangfa. Grain refining efficiency of a new Al-1B-0.6C master alloy on AZ63 magnesium alloy [J].J Alloys Compd,2010,491(1):165.
4 Yang M,Liu Y H,Liu J A,et al. Corrosion and mechanical properties of AM50 magnesium alloy after being modified by 1wt.% rare earth element gadolinium [J]. Rare Earths,2014,32(6):558.
5 Srinivasan A,Swaminathan J,Gunjan M K,et al. Effect of intermetallic phases on the creep behavior of AZ91 magnesium alloy [J]. Mater Sci Eng A,2010,527(527):1395.
6 Han Hui,Lü Cheng,Miao Huaming,et al. Fabrication of a new Mg-50%Al4C3-6%Ce master alloy and its refinement mechanism on AZ91D alloy [J]. Rare Met Mater Eng,2013,42(1):28.
7 Han Baojun,Gu Dongdong,He Qiong,et al. Fabrication of a novel Mg-RE (Nd, Ce) intermetallic compound coating by molten salt diffusion and its effect on corrosion resistance of magnesium alloys[J]. J Rare Earths,2016,34(7):731.
8 Wang Yingxin,Guan Shaoxang,Wang Jianqiang. Effects of RE on microstructures of Mg-8Zn-4Al-0.3Mn magnesium alloys [J]. Chin J Nonferr Met,2003,13(3):616.
9 Osório W R, Freire C M,Garcia A. The role of macrostructural morphology and grain size on the corrosion resistance of Zn and Al castings [J]. Mater Sci Eng A,2005,402(1-2):22.
10 Jin Yaxu,Tian Yuming,Liu Jiexing,et al. Effect of Al4C3 and Ce on the microstructure and mechanical property of ZM5 magnesium alloy [J]. Rare Met Mater Eng,2014,43(7):1774(in Chinese).
金亚旭,田玉明,刘杰兴,等. Al4C3和铈复合添加对ZM5镁合金组织和力学性能的影响[J].稀有金属材料与工程,2014,43(7):1774.
11 Wang Bin,Yang Yuansheng,Zhou Jixue,et al. Microstructure refinement of AZ91D alloy solidified with pulsed magnetic field [J]. Trans Nonferr Met Soc China,2008,18(3):536.
12 Wu Guohua,Li Guanqun,Fan Yu,et al. Effect of Y on microstructure and mechanical properties of AZ91D magnesium alloy [J]. Special Cast Nonferr Alloys,2006,26(15):260(in Chinese).
吴国华,李冠群,樊昱,等. Y对AZ91D镁合金组织及力学性能的影响[J].特种铸造及有色合金,2006,26(5):260.
13 Fan Yu,Wu Guohua,Gao Hongtao,et al. Effect of La on the mechanical property and corrosion resistance of AZ91D magnesium alloy [J]. Acta Metall Sin,2006,42(1):35(in Chinese).
樊昱,吴国华,高洪涛,等. La对AZ91D镁合金力学性能和腐蚀性能的影响[J].金属学报2006,42(1):35.
14 Chen T J,Wang R Q,Ma Y,et al. Grain refinement of AZ91D magnesium alloy by Al-Ti-B master alloy and its effect on mechanical properties [J]. Mater Des,2012,34(1):637.
15 He Guangjin. Study on the strengthening mechanism of n-SiCp/AZ91D composites [D].Beijing: Tsinghua University,2012(in Chinese).
何广进. 纳米SiC颗粒增强AZ91D镁基复合材料的强化机制研究[D].北京:清华大学,2012.
16 Zhou Haitao,Zeng Xiaoqin,Liu Wenfa,et al. Effect of Ce on microstructures and mechanical properties of AZ61 wrought magnesium [J]. Chin J Nonferr Met,2004,14(1):100(in Chinese).
周海涛,曾小勤,刘文法,等. 稀土铈对AZ61变形镁合金组织和力学性能的影响[J].中国有色金属学报,2004,14(1):100.
17 Xiao Xiaoling,Luo Chengping,Nie Jianfeng,et al. Morphology and crystallography of β-(Mg17Al12) precipitate in an AZ91 magnesium-aluminum alloy [J]. Acta Metall Sin, 2001,37(1):2(in Chinese).
肖晓玲,罗承萍,聂建峰,等.AZ91Mg-Al合金中β-(Mg17Al12)析出相的形态及其晶体学特征[J].金属学报,2001,37(1):2.
18 Zhang Wei,Wang Yanchun,Zhang Shouting,et al. Study on effect of Ce and La for Mg-Al alloy mechanical properties with valence electron theory [J]. Light Met,2008(8):52(in Chinese).
张伟,王彦春,张寿庭,等. Ce,La对Mg-Al合金力学性能影响的价电子理论研究[J].轻金属,2008(8):52.
19 Zhang Shichang,Wei Bokang,Lin Hantong,et al. Effects of Y,Ce and La on the microstructure of as cast AZ91 magnesium alloy [J]. Chin J Nonferr Met,2001,11(S2):101(in Chinese).
张诗昌,魏伯康,林汉同,等. 钇及铈镧混合稀土对AZ91D镁合金铸态组织的影响[J].中国有色金属学报,2001,11(S2):101.
20 Wang Shaowu,Xia Changqing,Wu Anru. Effects of Ce on the microstructure and mechanical properties of AZ31 magnesium alloy [J]. Mining Metall Eng,2006,26(4):77(in Chinese).
王少武,夏长清,吴安如. 稀土铈对AZ31镁合金显微组织和力学性能的影响[J].矿冶工程,2006,26(4):77.
21 Jiang Bailing, Zhang Jiyuan, Xia Pengju. Effects of Ce on the divorced eutectic β phase in the AZ31 magnesium alloy [J]. Special Cast Nonferr Alloys,2008,28(2):101(in Chinese).
蒋百灵,张继源,夏鹏举.Ce对AZ31镁合金中离异共晶β相的影响[J].特种铸造及有色合金,2008,28(2):101.
22 Lu Y Z,Wang Q D,Zeng X Q,et al. Effects of rare earths on the microstructure, properties and fracture behavior of Mg-Al Alloys [J]. Mater Sci Eng A,2000,278(1-2):67.
23 Hu Yong,Rao Li,Li Qiuping. Effect of Ce content on microstructure and properties of AZ91D magnesium alloy [J].Trans Mater Heat Treat, 2014,35(4):124(in Chinese).
胡勇,饶丽,黎秋萍. 稀土Ce含量对AZ91D镁合金组织和性能的影响[J].材料热处理学报,2014,35(4):124.
24 边秀房,刘相法,马家骥. 铸造金属遗传学[M].济南:山东科学技术出版社,1998.
[1] 张娜,程仁菊,董含武,刘文君,詹俊,蒋斌,潘复生. Sr在耐热镁合金中的应用及研究进展[J]. 材料导报, 2019, 33(15): 2565-2571.
[2] 毛虎,杨宏亮,史晓斌. 纳米晶NiTi形状记忆合金的研究进展[J]. 材料导报, 2019, 33(13): 2237-2242.
[3] 雷林, 杨庆波, 张志清, 樊祥泽, 李旭, 杨谋, 邓赞辉. AA2195铝锂合金多道次压缩行为及微观组织演变[J]. 材料导报, 2019, 33(z1): 348-352.
[4] 梁斌斌, 郭炜, 刘振兴, 杨洪广. 高活性氚钛靶膜固氦特性研究[J]. 材料导报, 2019, 33(z1): 153-157.
[5] 赵曦, 于振涛, 郑继明, 余森, 王昌. 合金元素影响镁合金弹性性能的第一性原理计算研究[J]. 材料导报, 2019, 33(z1): 293-296.
[6] 康凤, 陈文, 胡传凯, 林军, 夏祥生, 吴洋. 时效参数对Ti12LC钛合金组织及性能的影响[J]. 材料导报, 2019, 33(z1): 326-328.
[7] 崔利群, 韩胜利, 李达人, 胡建召, 刘祖岩. 钨铜粉末轧制的数值模拟研究[J]. 材料导报, 2019, 33(z1): 358-361.
[8] 郑嫄, 蔡中义, 程丽任, 车朝杰, 张洪杰. 铸态和挤压态Mg-4Sm-Al-0.3Mn-xZn合金微观组织和力学性能研究[J]. 材料导报, 2019, 33(8): 1354-1360.
[9] 李响, 毛萍莉, 王峰, 王志, 刘正, 周乐. 长周期有序堆垛相(LPSO)的研究现状及在镁合金中的作用[J]. 材料导报, 2019, 33(7): 1182-1189.
[10] 徐从昌, 叶拓, 唐明, 郭鹏程, 唐徐, 吴远志, 李落星. 动态载荷下7005铝合金力学行为及数值模拟[J]. 材料导报, 2019, 33(4): 670-673.
[11] 赵立臣, 谢宇, 张喆, 王铁宝, 王新, 崔春翔. ZnO纳米棒/多孔锌泡沫的制备及其压缩和抗菌性能[J]. 材料导报, 2019, 33(4): 577-581.
[12] 周杰, 李克, 王彪, 艾凡荣. 添加Nd对Mg-Zn-Ca合金非晶形成能力和耐蚀性的影响[J]. 材料导报, 2019, 33(1): 73-77.
[13] 黄硕文, 黄春平, 吴中文, 夏春, 刘奋成, 柯黎明. 后热处理对搅拌摩擦加工制备Al-Ti复合材料组织特征的影响[J]. 材料导报, 2018, 32(22): 3908-3912.
[14] 薛喜丽, 陈鑫, 李龙, 周德敬. Mn、Fe含量对3003铝合金铸锭均匀化行为的影响[J]. 材料导报, 2018, 32(22): 3913-3918.
[15] 程鹏, 陈云贵, 丁武成, 王春明. 热挤压Mg-3Sn-1Zn-xCu合金的显微组织与力学性能[J]. 材料导报, 2018, 32(20): 3562-3565.
[1] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3] Siyuan ZHOU,Jianfeng JIN,Lu WANG,Jingyi CAO,Peijun YANG. Multiscale Simulation of Geometric Effect on Onset Plasticity of Nano-scale Asperities[J]. Materials Reports, 2018, 32(2): 316 -321 .
[4] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[5] Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[6] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7] ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[8] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[9] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[10] YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed