Research Progress on Defect Structure Evolution and the Corresponding Physical Mechanisms of Molybdenum Disulfide Under Electron Beam Irradiation
JI Xuemei1, HAO Chi1, ZHU Xiumei1, SU Jiangbin1,2,3,*, HE Zuming1, TANG Bin1, ZHU Xianfang2,*
1 Experimental Center of Electronic Science and Technology, School of Microelectronics and Control Engineering, Changzhou University, Changzhou 213159, Jiangsu, China 2 China-Australia Joint Laboratory of Functional Nanomaterials, School of Physical Science and Technology, Xiamen University, Xiamen 361005, Fujian, China 3 Key Laboratory of MEMS Education Department, School of Electronic Science and Engineering, Southeast University, Nanjing 210096,China
Abstract: The rich polyatomic structures of molybdenum disulfide (MoS2) bestow upon it with excellent electrical, optical, and catalytic properties, arousing great interest. The defect structures in MoS2 often have a significant impact on its performance, which is generally considered to be negative. Therefore, previous studies aimed at avoiding the occurrence of defect structures. However, some recent studies have shown that MoS2 defects also have positive significance in their applications. To better leverage the defect structures of MoS2 and harness their positive impact, it is first necessary to understand these defect structures, their evolution modes and related physical mechanisms, and use them to guide the controllable nanoprocessing and practical applications. In this review, the authors summarize the different types of defect structures in MoS2 and the structural evolution behavior of MoS2 under electron beam irradiation, and then explore the mechanisms of the interaction between electron beam and MoS2 defect structures. By analyzing the limitations of traditional physical mechanisms, the authors propose two new concepts—nanocurvature effect and non-thermal activation effect to delve into the underlying physical mechanisms of these experimental phenomena. This exploration is conducted from the perspectives of nano-space limitation and ultrafast time limitation. Finally, the authors present their perspectives and prospects on defect structure modulation and controllable nanoprocessing of MoS2.
通讯作者:
*苏江滨,常州大学微电子与控制工程学院教授、硕士研究生导师。2005年厦门大学物理系物理学专业本科毕业,2008年厦门大学物理系凝聚态物理专业硕士毕业后到常州大学工作至今,2017年厦门大学物理系凝聚态物理专业博士毕业。目前主要从事光电功能材料与器件、纳米科学与技术等方面的研究工作。发表论文80余篇,包括Nanoscale、Nanotechnology、Science China Materials、Surface & Coatings Technology、Journal of Physical Chemistry C、Journal of Alloys and Compounds等。jbsu@cczu.edu.cn; 朱贤方,厦门大学物理科学与技术学院教授,澳大利亚昆士兰大学兼职教授,博士研究生导师,中国-澳大利亚功能纳米材料联合实验室主任。主要从事纳米材料设计、制备、改性及纳米结构稳定方面的研究工作。目前共发表100余篇论文(80%以上为第一或独立作者),相关技术已申请发明专利7项,参与制定国家标准1个。zhux@xmu.edu.cn
季雪梅, 郝驰, 朱秀梅, 苏江滨, 何祖明, 唐斌, 朱贤方. 二硫化钼在电子束辐照下的缺陷结构演变及其物理机制研究进展[J]. 材料导报, 2024, 38(3): 22070109-11.
JI Xuemei, HAO Chi, ZHU Xiumei, SU Jiangbin, HE Zuming, TANG Bin, ZHU Xianfang. Research Progress on Defect Structure Evolution and the Corresponding Physical Mechanisms of Molybdenum Disulfide Under Electron Beam Irradiation. Materials Reports, 2024, 38(3): 22070109-11.
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2024, Vol. 38 
