Research Progress of BaO-Ln2O3-TiO2 System Microwave Dielectric Ceramics with High Permittivity and Low Loss
WANG Geng1,2,FU Qiuyun1,ZHANG Lu1,SHI Hao1,TIAN Fan1
1 School of Optical and Electronic Information, Engineering Research Center for Functional Ceramics of the Ministry of Education, Huazhong University of Science and Technology, Wuhan 430074 2 School of Electronic Information and Engineering, Hubei University of Science and Technology, Xianning 437100
Abstract: Microwave dielectric ceramics is a kind of functional ceramics which can be used in microwave frequency circuits as dielectric materials. It is also a new type of electronic ceramic materials developed in recent decades, and mainly used in microwave devices such as antennas duple-xers, frequency stabilized oscillators, microwave capacitors, filters and resonators. These components have a wide range of applications in many fields such as 4G/5G mobile communication systems, global satellite positioning systems, satellite communication systems, wireless Internet and military radar. With the rapid development of the 5G mobile communication system industry, microwave components especially filters and resonators, acting as important devices in communication equipment, have received extensive attention from researchers all over the world. In order to make a further improvement in the performance of microwave components, decrease the size of microwave components and reduce manufactu-ring costs, the requirements for microwave dielectric materials are shown as follows: (1) high dielectric constant(εr); (2) high quality factor(Qf); (3) near zero temperature coefficient of resonance frequency(TCF); (4) cheap, non-toxic and environmentally friendly raw materials. From the perspective of dielectric constant, high dielectric constant microwave dielectric ceramics generally refer to the materials with dielectric constants above 70. The main material systems of high dielectric constant microwave dielectric ceramics usually include barium lanthanum titanium system(BaO-Ln2O3-TiO2), ABO3 perovskite structure system, calcium lithium lanthanum titanium system, bismuth based system, lithium based system and lead based perovskite system. In the high dielectric constant microwave dielectric material system studied in recent years, the barium lanthanum titanium system has got the most attention. This system belongs to the perovskite-like tungsten bronze structure, and there are several types of voids in the structural unit with different shapes and sizes, which can be filled by ions with different valence states and radii. The filling of different ions would cause corresponding changes in the structure, and would influence the microwave dielectric properties at the same time. Based on the property above, many researchers have incorporated ions of different valences and radii into the Ba-Ln-Ti system, and desired to fill the ions into a certain space in the crystal structure, in order to obtain better microwave dielectric properties. BaO-Ln2O3-TiO2 system microwave dielectric ceramics is widely used in mobile communication for its good temperature stability, high permitti-vity and low loss. With the rapid development of 5G communication, the research on this system exhibits great theoretical significance and application value, therefore becoming one of the hottest research topics in microwave dielectric area. This article first introduces the crystal structure and solid solubility limit of BaO-Ln2O3-TiO2 ceramics, and then provides an overview of the progress on BaO-Ln2O3-TiO2 system in recent years from several aspects including A-site substitution, B-site substitution, A/B-site collaborative substitution, combined modification, anti-reduction and low-temperature sintering. Current existed problems and future research priorities are also discussed in the end of the article.
作者简介: 王耿,2012年6月毕业于湖北工业大学,获得工学硕士学位。现为华中科技大学光学与电子信息学院博士研究生,在傅邱云教授的指导下进行研究。目前主要研究领域为高性能微波介质及滤波器件。 傅邱云,华中科技大学光学与电子信息学院教授、博士研究生导师,华中科技大学“华中学者”特聘教授,教育部敏感陶瓷工程研究中心主任。主持并完成国家自然科学基金面上项目、国家863目标导向项目等国家与省部级项目10余项,与企业合作开发项目20余项。授权中国发明专利20余项、美国发明专利2项;在Advanced Materials、ACS Applied Materials & Interfaces、Applied Physics Letter、Journal of the European Ceramics Society、Journal of the American Ceramics Society、Sensors and Actuators B等发表SCI论文50余篇;国内外会议大会报告与特邀报告多次;担任中国电子学会元件分会委员、青年科学家俱乐部委员、中国硅酸盐学会特种陶瓷分会理事等多种学术兼职。主要研究方向为信息存储器件、薄膜传感器、片式集成元件及LTCC无源集成技术。
引用本文:
王耿, 傅邱云, 张芦, 施浩, 田帆. 钡镧钛系高介低损耗微波介质陶瓷研究进展[J]. 材料导报, 2019, 33(13): 2151-2158.
WANG Geng, FU Qiuyun, ZHANG Lu, SHI Hao, TIAN Fan. Research Progress of BaO-Ln2O3-TiO2 System Microwave Dielectric Ceramics with High Permittivity and Low Loss. Materials Reports, 2019, 33(13): 2151-2158.
Sebastian M T.Dielectric materials for wireless communication, Elsevier, Netherlands, 2010.2 Sebastian M T, Jantunen H.International Materials Reviews, 2008, 53(2), 57.3 Reaney I M, Iddles D.Journal of the American Ceramic Society, 2006, 89(7), 2063.4 Sebastian M T, Ubic R, Jantunen H.International Materials Reviews, 2015, 60(7), 392.5 Ohsato H.Ceramics International, 2012, 38, S141.6 Hu J, Lu X P, Zhang T Y, et al. Materials Review, 2017, 31(S2), 107 (in Chinese).胡杰, 吕学鹏, 张天宇, 等.材料导报, 2017, 31(S2), 107.7 Andrews J G, Buzzi S, Choi W, et al.IEEE Journal on Selected Areas in Communications, 2014, 32(6), 1065.8 Wong V W, Schober R, Ng D W, et al.Key Technologies for 5G Wireless Systems, Cambridge University Press, UK, 2017.9 Sebastian M T, Ubic R, Jantunen H.Microwave materials and applications, John Wiley & Sons, USA, 2017.10 Xiong Z, Tang B, Fang Z, et al.Journal of Alloys and Compounds, 2017, 723, 580.11 Xiong Z, Tang B, Yang C, et al.Journal of Alloys and Compounds, 2018, 740, 492.12 Ullah B, Lei W, Song X Q, et al.Journal of the European Ceramic Society, 2017, 37(9), 3051.13 Li Z, Yan Y, Zhang M, et al.Ceramics International, 2017, 43(2), 2899.14 Gu Y, Li C, Huang J, et al.Journal of the European Ceramic Society, 2017, 37(15), 4673.15 Ning F, Gan L, Yuan S, et al.Journal of Alloys and Compounds, 2017, 729, 742.16 Zhou D, Guo D, Li W B, et al.Journal of Materials Chemistry C, 2016, 4(23), 5357.17 Zhou D, Pang L X, Wang D W, et al.Journal of Materials Chemistry C, 2017, 5(38), 10094.18 Long Y, Wang Y, Wu W, et al.Journal of the American Ceramic Society, 2009, 92(11), 2630.19 Sun H, Li E, Yang H, et al.Materials Letters, 2018, 210, 275.20 Kucheiko S, Choi J W, Kim H J, et al.Journal of the American Ceramic Society, 1997, 80(11), 2937.21 Yoon K H, Kim E S, Jeon J S.Journal of the European Ceramic Society, 2003, 23(14), 2391.22 Bolton R L. Temperature compensating ceramic capacitors in the system baria-rare-earth-oxide-titania. Ph.D. Thesis. University of Illinois at Urbana-Champaign,USA,1968.23 Matveeva R G, Varfolomeev M B, Il'Yushchenko L S.Zhurnal Neorganicheskoj Khimii, 1984, 29(1), 31.24 Ohsato H, Mizuta M, Ikoma T, et al.Journal of the Ceramic Society of Japan, 1998, 106(1230), 178.25 Ohsato H, Imaeda M.Materials Chemistry and Physics, 2003, 79(2-3),208.26 kapin S, Kolar D, Suvorov D, et al. Journal of Materials Research, 1998, 13(5), 1327.27 Fukuda K, Kitoh R, Awai I.Journal of Materials Research, 1995, 10(2), 312.28 Ohsato H, Ohhashi T, Nishigaki S, et al.Japanese Journal of Applied Physics, 1993, 32(9S), 4323.29 Negas T, Davies P K.Cheminform, 1996, 27(5), no.30 Cruickshank K M, Jing X, Wood G, et al.Journal of the American Cera-mic Society, 1996, 79(6), 1605.31 Ubic R, Reaney I M, Lee W E.International Materials Reviews, 1998, 43(5), 205.32 Zhang L, Chen X M, Qin N, et al.Journal of the European Ceramic Society, 2007, 27(8-9), 3011.33 Zhong L, Zhu X L, Chen X M, et al.Ceramics International, 2011, 37(8), 3575.34 Ichinose N, Amada H.Journal of the European Ceramic Society, 2001, 21(15), 2751.35 Li Y, Chen X M.Journal of the European Ceramic Society, 2002, 22(5), 715.36 Qin N, Chen X M.Materials Science and Engineering: B, 2004, 111(1), 90.37 Qin N, Chen X M.Key Engineering Materials, 2005, 280, 57.38 Zhang X, Zhang L, Zhang J, et al.Journal of Materials Science, 2015, 50(3), 1141.39 Huang X, Liu X, Liu F, et al.Journal of Advanced Ceramics, 2017, 6(1), 50.40 Wang X, Fu R, Xu Y.Journal of Materials Science: Materials in Electro-nics, 2016, 27(11), 11137.41 Wang X, Luo J, Guan H, et al.Journal of Materials Science: Materials in Electronics, 2017, 28(14), 10338.42 Gao X F, Qiu T.Journal of Rare Earths, 2010, 28(3), 411.43 Chen H, Tang B, Gao A, et al.Journal of Materials Science: Materials in Electronics, 2015, 26(1), 405.44 Chen H, Tang B, Duan S, et al.Journal of Electronic Materials, 2015, 44(4), 1081.45 Huang B, Wang Z, Chen T, et al.Journal of Materials Science Materials in Electronics, 2015, 26(5), 3375.46 Guo X, Tang B, Liu J, et al.Journal of Alloys and Compounds, 2015, 646, 512.47 Chen H, Tang B, Guo X, et al.International Journal of Applied Ceramic Technology, 2016, 12(S3), E170.48 Chen J S, Chen G H, Kang X L, et al.Journal of Materials Science Materials in Electronics, 2016, 27(8), 8234.49 Xiang M C, Yi L.Journal of the American Ceramic Society, 2002, 85(3), 579.50 Gao X F, Qiu T.Journal of Alloys & Compounds, 2010, 502(2), 333.51 Guo X, Tang B, Chen H, et al.Journal of Materials Science Materials in Electronics, 2015, 26(8), 6182.52 Chen H, Tang B, Xiong Z, et al.Applied Physics A, 2015, 121(1), 283.53 Chen H, Xiong Z, Yuan Y, et al.Journal of Materials Science Materials in Electronics, 2016, 27(10), 10951.54 Chen H, Tang B, Guo X, et al.Journal of Electronic Materials, 2017, 46, 1.55 Ohsato H, Komura A, Takagi Y, et al.Japanese Journal of Applied Phy-sics, 1998, 37, 5357.56 Wu Y J, Chen X M.Journal of the European Ceramic Society, 1999, 19(6-7), 1123.57 Liang B L, Zheng X H, Ni W Q, et al. Journal of the Chinese Ceramic Society, 2006, 34(12), 17 (in Chinese).梁炳亮, 郑兴华, 倪维庆, 等. 硅酸盐学报, 2006, 34(12), 17.58 Zheng X H, Liang B L, Tang D P, et al.Journal of the Ceramic Society of Japan, 2009, 117(1371), 1254.59 Lu W Z, Wang X C, Zhu J H, et al. Ferroelectrics, 2009, 387(1), 137.60 Zhu J H, Lu W Z, Lei W, et al. Ceramics International, 2009, 35(2), 855.61 Zhu J H, Kipkoech E R, Lu W Z. Journal of the European Ceramic Society, 2006, 26(10-11), 2027.62 Huang B, Wang Z, Chen T, et al.Journal of Materials Science Materials in Electronics, 2014, 25(12), 5264.63 Chang G, Zhou X H, Zhang S R, et al.Journal of Materials Science Materials in Electronics, 2014, 25(10), 4439.64 Xu Y, Fu R, Agathopoulos S, et al.Ceramics International, 2016, 42(13), 14573.65 Wang X, Fu R, Xu Y.Journal of Materials Science: Materials in Electro-nics, 2017, 28(5), 4328.66 Yao X, Lin H, Chen W, et al.Ceramics International, 2012, 38(4), 3011.67 Yao X, Lin H, Zhao X, et al.Ceramics International, 2012, 38(8), 6723.68 Huang B, Yan Z, Lu X, et al.Ceramics International, 2016, 42(9), 10758.69 Tao J, Mu M, Wang X, et al.Journal of Materials Science Materials in Electronics, 2017, 28(22), 16888.70 Tao J, Mu M, Wang X, et al.Journal of Materials Science Materials in Electronics, 2018, 29(2), 1392.71 Tang B, Xiang Q, Fang Z, et al.Journal of Materials Science: Materials in Electronics, 2018, 29(1), 535.72 Lim J B, Cho K H, Nahm S, et al.Materials Research Bulletin, 2006, 41(10), 1868.73 Santha N, Sebastian M T, George V, et al.Materials Chemistry & Physics, 2006, 100(2), 423.74 Pang L X, Wang H, Zhou D, et al.Materials Chemistry & Physics, 2010, 123(2-3), 727.75 Zeng Y, Wang H, Zhou H.Journal of Materials Research, 2010, 25(12), 2380.76 Yang W, Zuo R, Zhou Y, et al.Journal of Materials Science, 2011, 46(6), 1932.77 Shih Y T, Jean J H.Journal of the American Ceramic Society, 2013, 96(12), 3849.78 Zhou X, Zhang Y, Chang G, et al.Journal of Materials Science Materials in Electronics, 2016, 27(3), 2783.79 Li E, Chen Y, Xiong J, et al.Journal of Materials Science Materials in Electronics, 2016, 27(8), 8428.80 Long M, Tang B, Zhang S, et al. Materials Letters, 2012, 68, 486.81 Chen H, Zhang Z, Xiong Z, et al.Journal of the American Ceramic Society, 2017, 100(9), 4058.82 Pullar R C, Penn S J, Wang X, et al.Journal of the European Ceramic Society, 2009, 29(3), 419.83 Xia H T, Kuang X J, Wang C H, et al. Acta Physico-Chimica Sinica, 2011, 27(8), 2009.
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2019, Vol. 33 
