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《材料导报》期刊社  2018, Vol. 32 Issue (3): 405-411    https://doi.org/10.11896/j.issn.1005-023X.2018.03.010
     材料综述 ｜ |
木质素基碳纤维制备的研究进展
刘兰燕1,宋俊1,程博闻1,薛文池1,郑云波2
1 天津工业大学材料科学与工程学院,天津 300387
2 中国纺织科学研究院海西分院,晋江 362200
Research Progress in Preparation of Lignin-based Carbon Fiber
Lanyan LIU1,Jun SONG1,Bowen CHENG1,Wenchi XUE1,Yunbo ZHENG2
1 School of Material Science and Engineering, Tianjin Polytechnic University, Tianjin 300387
2 Haixi Branch of China Textile Academy, Jinjiang 362200
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摘要 

木质素在自然界中储量丰富,并且可再生、碳含量高,将其应用于碳纤维的制备有着无可比拟的成本优势。简要介绍了木质素基碳纤维的发展进程,详述了硫酸盐木质素、有机溶剂型木质素和蒸汽爆破木质素的来源、结构差异及其碳纤维制备工艺过程进展,通过对比得出硫酸盐木质素是制备低成本碳纤维的最佳木质素原料,同时指出了木质素制备碳纤维的未来研究方向,旨在为木质素制备碳纤维的研究者提供参考。
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刘兰燕
宋俊
程博闻
薛文池
郑云波
关键词:  硫酸盐木质素  有机溶剂型木质素  碳纤维  制备方法  结构与性能    
Abstract: 

Lignin is rich in nature, it is also renewable and with high carbon content. The application of lignin in the preparation of carbon fiber has an unparalleled cost advantage.The development of lignin-based carbon fiber is briefly introduced. The progress of the source, structure difference and carbon fiber preparation methods of kraft lignin, organosolv lignin and steam-explosion lignin is discussed in detail. As a result, the kraft lignin has been chosen as the best raw material for the preparation of low cost carbon fiber. Furthermore, the future direction of lignin-based carbon fiber is pointed out, which aims to provide reference for the initial research of lignin-based carbon fiber.
Key words:  kraft lignin    organosolv lignin    carbon fiber    preparation methods    structure and properties
               出版日期:  2018-02-10      发布日期:  2018-02-10
ZTFLH:  TB34  
作者简介:  刘兰燕:女,1989年生,硕士研究生,主要从事木质素及碳纤维的制备研究 E-mail: lanyan_oni@163.com|宋俊:通信作者,男,副教授,主要从事生物材料制备纤维的研究 E-mail: sjhb2000@163.com|程博闻:通信作者,男,教授,主要从事环境友好型纤维素及木质素纤维的研究 E-mail: bowen15@tjpu.edu.cn
引用本文:    
刘兰燕,宋俊,程博闻,薛文池,郑云波. 木质素基碳纤维制备的研究进展[J]. 《材料导报》期刊社, 2018, 32(3): 405-411.
Lanyan LIU,Jun SONG,Bowen CHENG,Wenchi XUE,Yunbo ZHENG. Research Progress in Preparation of Lignin-based Carbon Fiber. Materials Reports, 2018, 32(3): 405-411.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.03.010  或          http://www.mater-rep.com/CN/Y2018/V32/I3/405
图1  PAN制备碳纤维成本分布[3](电子版为彩图)
图2  木质素基本结构单元
图3  干法纺丝得到的木质素基碳纤维SEM图[36]
图4  (a)同轴静电纺丝喷头和(b)三维静电纺丝喷头[51]
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