Research Progress in Tailoring the Microstructure of Resorcinol-Formaldehyde Organic/Carbon Aerogel
YAN Jiao1,2, KUANG Minxuan1, HU Honglin2, KONG Lei2, MA Huiling2, ZHANG Xiuqin1
1 Beijing Engineering Research Center of Textile Nanofiber, School of Materials Science and Engineering, Beijing Institute of Fashion Technology, Beijing 100029, China 2 Science and Technology on Advanced Functional Composites Laboratory, Aerospace Research Institute of Materials & Processing Technology, Beijing 100076, China
Abstract: Because of the excellent ablation resistance and physical/chemical properties, phenolic/carbon aerogel has great potential in the fields of acoustic/thermal resistance material, absorption material, energy storage material, sensor, aerospace industry, etc. This mini-review introduced the main factors in the synthesis of resorcinol-formaldehyde organic/carbon aerogel, including catalyst, additives and drying methods. First, the catalytic mechanism of acids/bases, the impact of the catalyst types and solution pH value on the microstructure of the aerogel were discussed. Then, while the interaction mechanism of surfactants was analyzed, how the types and the amount of surfactants influence the microstructure was elucidated. Further, the role of additives, such as carbon nanotubes, graphene oxide, chitosan, salts, etc., was discussed. The effects of different drying methods i.e., supercritical drying, freeze-drying and ambient pressure drying, on the microstructure of the aerogel were compared, with an emphasis on the prerequisites and principles for ambient pressure drying. Finally, the current challenges were summarized and the possible future developments of resorcinol-formaldehyde polymer/carbon aerogel were prospected, such as improvement of mechanical properties, cost-effective, super elastic aerogel and 3D printable aerogel.
严蛟, 邝旻翾, 胡宏林, 孔磊, 马慧玲, 张秀芹. 间苯二酚-甲醛基酚醛/碳气凝胶微观结构调控研究进展[J]. 材料导报, 2022, 36(12): 20090342-10.
YAN Jiao, KUANG Minxuan, HU Honglin, KONG Lei, MA Huiling, ZHANG Xiuqin. Research Progress in Tailoring the Microstructure of Resorcinol-Formaldehyde Organic/Carbon Aerogel. Materials Reports, 2022, 36(12): 20090342-10.
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