羟乙基甲基纤维素改性水泥砂浆的物理力学性能和孔隙率

材料导报

2020, Vol. 34

Issue (Z2): 607-611

高分子与聚合物基复合材料

羟乙基甲基纤维素改性水泥砂浆的物理力学性能和孔隙率

张绍康¹, 王茹^1,2, 徐玲琳^1,2, 钟世云^1,2, 张国防^1,2, 王培铭^1,2

1 同济大学材料科学与工程学院,上海 201804
2 同济大学先进土木工程材料教育部重点实验室,上海 201804

Physical and Mechanical Properties and Porosity of Cement Mortar Modified by Hydroxyethyl Methyl Cellulose

ZHANG Shaokang¹, WANG Ru^1,2, XU Linglin^1,2, ZHONG Shiyun^1,2, ZHANG Guofang^1,2, WANG Peiming^1,2

1 School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
2 Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804, China

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摘要为了研究不同羟乙基甲基纤维素(HEMC)对水泥砂浆性能的影响差异,本工作选用了三种HEMC制备改性水泥砂浆,分别为高、低取代度和聚丙烯酰胺(PAAm)改性HEMC,并从砂浆物理力学性能和孔隙率及孔径分布等角度进行了比较。结果表明,HEMC的掺加可使新拌砂浆保水率和稠度提高,同时使砂浆的拉伸粘结强度提高,但使抗压和抗折强度下降。取代度和PAAm改性对砂浆保水率和抗折强度的影响不大。相较于低取代度HEMC,高取代度HEMC改性砂浆具有更高的稠度和较高的拉伸粘结强度以及干燥收缩率。PAAm改性使HEMC改性砂浆稠度大幅下降,拉伸粘结强度降低。压汞法测试结果表明:纤维素醚的加入使砂浆中小孔减少,但却引入了相当数量的微米级大孔,增大了孔隙率,但不同HEMC改性砂浆之间的差异不显著。

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关键词: 羟乙基甲基纤维素取代度水泥砂浆物理力学性能孔隙率

Abstract: In order to study the influence of different hydroxyethyl methyl celluloses (HEMCs) on the properties of cement mortar, three kinds of HEMCs were used to prepare modified cement mortar in this paper. Those HEMCs are high, low substitution degree and polyacrylamide (PAAm) modified HEMC. The influence of the HEMCs on cement mortar was compared from the mechanical properties, porosity and pore size distribution. The results show that the addition of HEMCs can improve the water retention rate and consistence of fresh cement mortar, increase the tensile bond strength, but decrease the compressive strength and flexural strength. The substitution degree and PAAm have minor influence on the water retention rate and flexural strength. Compared to HEMC with low substitution degree, HEMC with higher substitution degree have higher consistence, tensile bond strength and dry shrinkage rate. PAAm significantly decreases the consistence of HEMC-modified cement paste and decreases the tensile bond strength too. The result of mercury intrusion porosimeter (MIP) shows that the small pores of mortar are reduced by the addition of HEMCs, meanwhile a considerable number of micro-sized macropores are introduced, and the porosity of cement mortar also are increased; but no significant difference observed among the HEMC-modified mortars.

Key words: hydroxyethyl methyl cellulose degree of substitution cement mortar physical and mechanical properties porosity

出版日期: 2020-11-25 发布日期: 2021-01-08

ZTFLH:

TU526

基金资助: 国家自然科学基金(51872203;51572196);中德科学中心基金(GZ 1290)

通讯作者: ruwang@tongji.edu.cn

作者简介: 张绍康,2016年6月毕业于中国矿业大学,获得工学学士学位。现在同济大学攻读硕士学位,主要从事聚合物改性水泥砂浆的研究。王茹,同济大学教授,博士研究生导师。2003年毕业于四川大学获得材料学专业博士学位,先后在同济大学和奥地利维也纳技术大学进行博士后研究工作,回国后在同济大学工作至今,2010—2011年在美国哥伦比亚大学进行访问;兼任国际聚合物混凝土学会理事会副理事长。主要从事聚合物水泥基复合材料的基础理论和工程应用研究,发表相关学术论文100余篇,多数被SCI和EI收录;主编Progress in Polymers in Concrete和《干混砂浆原材料及产品检测方法》等著作。

引用本文:

张绍康, 王茹, 徐玲琳, 钟世云, 张国防, 王培铭. 羟乙基甲基纤维素改性水泥砂浆的物理力学性能和孔隙率[J]. 材料导报, 2020, 34(Z2): 607-611.
ZHANG Shaokang, WANG Ru, XU Linglin, ZHONG Shiyun, ZHANG Guofang, WANG Peiming. Physical and Mechanical Properties and Porosity of Cement Mortar Modified by Hydroxyethyl Methyl Cellulose. Materials Reports, 2020, 34(Z2): 607-611.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2020/V34/IZ2/607

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