Please wait a minute...
材料导报  2020, Vol. 34 Issue (Z1): 498-502    
  高分子与聚合物基复合材料 |
兼具聚集诱导发光和激发态分子内质子转移特性的有机小分子发光体
杜飞跃, 周徐, 谢叔媚, 王二静, 王世敏
湖北大学材料科学与工程学院,高分子材料湖北省重点实验室,绿色制备与应用教育部重点实验室,武汉 430062
Organic Small Molecule Emitters Possessing Aggregation-induced Emission andExcited-stated Intramolecular Proton Transfer: a Review
DU Feiyue, ZHOU Xu, XIE Shumei, WANG Erjing, WANG Shimin
Hubei Provincial Key Laboratory of Polymers, Key Laboratory for the Green Preparation and Application of Function Materials of Ministry of Education, School of Materials Science and Engineering, Hubei University, Wuhan 430062,China
下载:  全 文 ( PDF ) ( 3657KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 有机小分子聚集诱导发光体系的聚集态受到光激发后,由于分子内运动受限,激发态能量以辐射衰减途径回到基态的比例增加,从而增强聚集态发光。聚集诱导发光的提出克服了传统有机发光分子的聚集引起发光淬灭的缺陷,具有聚集诱导发光特性的材料在有机发光二极管、有机激光、生物医学治疗诊断等方面全面发力,得到广泛关注。具有激发态分子内质子转移特性的材料其发光一般都有较大的斯托克斯位移,可避免激发光谱和发射光谱的重叠,从而改善材料发光性能和提高荧光探针的灵敏性。兼具聚集诱导发光和激发态分子内质子转移的有机小分子结合了两者的优点,呈现出更优异的固态发光性能。本文主要从结构分类、光电性质和应用等几个方面介绍关于该类分子的最近研究成果。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
杜飞跃
周徐
谢叔媚
王二静
王世敏
关键词:  聚集诱导发光  激发态分子内质子转移  斯托克斯位移  化学传感    
Abstract: When an organic small molecule with aggregation-induced luminescence (AIE) under aggregation or solid state is excited, the excitons will preferably relax in a radiative way owing to the restriction of intramolecular motion, thus triggering the aggregation-state emission. The AIE occurrence conquers the drawback of aggregation-causing quenching existing in traditional organic emitters, and has found wide applications in organic light-emitting diodes, organic lasers, biomedical diagnosis and therapy, etc. Meanwhile, material with excitation-state intramolecular proton transfer (ESIPT) usually exhibits large Stokes shift and therefore can improve the sensitivity of fluorescent probes. Organic small molecule emitters with the combinations of AIE and ESIPT demonstrate superior solid-state luminescence performance. Herein, the recent progress in the AIE-ESIPT organic small molecule emitters is reviewed in terms of their structures, optoelectronic properties and applications.
Key words:  aggregation-induced emission    excited-state intramolecular proton transfer    Stokes shift    chemosensing
                    发布日期:  2020-07-01
ZTFLH:  O626  
基金资助: 国家自然科学基金(51603063);湖北省自然科学基金(2017CFB489)
作者简介:  杜飞跃,湖北大学硕士研究生,主要研究方向为有机荧光分子;王二静,副教授,主要从事有机光电功能材料的研究。
引用本文:    
杜飞跃, 周徐, 谢叔媚, 王二静, 王世敏. 兼具聚集诱导发光和激发态分子内质子转移特性的有机小分子发光体[J]. 材料导报, 2020, 34(Z1): 498-502.
DU Feiyue, ZHOU Xu, XIE Shumei, WANG Erjing, WANG Shimin. Organic Small Molecule Emitters Possessing Aggregation-induced Emission andExcited-stated Intramolecular Proton Transfer: a Review. Materials Reports, 2020, 34(Z1): 498-502.
链接本文:  
http://www.mater-rep.com/CN/  或          http://www.mater-rep.com/CN/Y2020/V34/IZ1/498
1 Förster P D T. Angewandte Chemie International Edition,1969,8(5),333.
2 Luo J, Xie Z, Lam J W Y, et al. Chemical Communications,2001(18),1740.
3 Mei J, Hong Y, Lam J W Y, et al. Advanced Materials,2014,26(31),5429.
4 Mei J, Leung N L C, Tang B Z, et al. Chemical Reviews,2015,115,11718.
5 Weller A. Naturwissenschaften,1955,42,175.
6 Padalkar V S, Seki S. Chemical Society Reviews,2016,45,169.
7 Barman S, Mukhopadhyay S K, Gangopadhyay M, et al. Journal of Materials Chemistry B,2015,3,3490.
8 Peng L, Zheng Y, Wang X, et al. Chemistry-A European Journal,2015,21(11),4326.
9 Peng L, Xu S, Zheng X, et al. Analytical Chemistry,2017,89(5),3162.
10 Schmidtke S J, Underwood D F, Blank D A. JACS,2004,126(28),8620.
11 Ma X F, Cheng J H, Liu J Y, et al. New Journal of Chemistry,2015,39,492.
12 Biswas S, Mengji R, Barman S, et al. Chemical Communication,2018,54,168.
13 Li R J, Yan L Q, Wang Z W, et al. Journal of Molecular Structure,2017,1136,1.
14 Yang W G, Zhao X X, Zhang J, et al. Dyes of Pigments,2018,156,100.
15 Chen Q, Jia C, Zhang Y, et al. Journal of Materials Chemistry B,2017,5,7736.
16 Zhang P S, Nie X Z, Gao M, et al. Materials Chemistry Frontiers,2017,1,838.
17 Jia J H, Zhao H X. Organic Electronics,2019,73,55.
18 Liu Y, Nie J, Niu J, et al. Journal of Materials Chemistry B,2018,6,1973.
19 Dong Y J, Shen J J, Li W J, et al. Tetrahedron,2019,75(18),2670.
20 王凡.基于AIEE和ESIPT机理的荧光染料分子的合成与性质研究,硕士学位论文,天津理工大学,2019.
21 Wang X W, Huang Y Z, Lv W W, et al. Analytica Methods,2017,9(12),1872.
22 Wang Z M, Zhou F, Wang J, et al. Science China Chemistry,2018,61(1),76.
23 Samanta S, Manna U, Das G. New Journal of Chemistry,2017,41(3),1064.
24 Jung H, Kang S, Sim Y, et al. Organic Electronics,2019,73,261.
25 Wu Y, Chen X, Mu Y, et al. Dyes of Pigments,2019,169,81.
26 Yan L Q, Li R J, Shen W, et al. Journal of Luminescence,2017,194,151.
27 Yuan W Z, Yu Z Q, Lu, et al. Journal of Materials Chemistry,2012,22(8),3323.
28 Padalkar V S, Tsutsui Y, Sakurai T, et al. The Journal of Physical Chemistry B,2017,121(45),10407.
29 Park S, Kwon O H, Kim S, et al. Journal of the American Chemistry So-ciety,2005,127(28),10070.
30 Tang B, Liu H, Li F, et al. Chemical Communications,2016,52(39),6577.
31 Wang Q, Xu L, Niu Y, et al. Dyes of Pigments,2017,142,365.
32 Lin L, Fan J, Cai L, et al. RSC Advances,2017,7(70),44089.
33 Ni J S, Zhang P F, Jiang T, et al. Advanced Materials,2018,1805220.
34 Kumar G, Paul K, Luxami V. Sensors and Actuators B: Chemical,2018,263(15),585.
35 Wang J, Gu X, Zhang P, et al. Journal of the American Chemistry Society,2017,139(46),16974.
36 Sen G A, Paul K, Luxami V. Sensors and Actuators B: Chemical,2017,246,653.
37 Chen L Y, Wu D, Lim C S, et al. Chemical Communications,2017,53,4791.
38 Zhou X, Guo D, Jiang Y, et al. Tetrahedron Letters,2017,58(33),3214.
39 Peng L, Gao M, Cai X L, et al. Journal of Materials Chemistry B,2015,3,9168.
40 Xu D, Liu M, Zou H, et al. Talanta,2017,174,803.
41 Wei R, Song P, Tong A. The Journal of Physical Chemistry C,2013,117(7),3467.
42 Jin X D, Dong L B, Di X Y, et al. RSC Advances,2015,5,87306.
[1] 齐云霞, 赵小伟, 杨永新, 黄冬维, 赵辉玲, 丁海生, 程广龙. TiO2基光电化学传感器电极结构调控的研究进展[J]. 材料导报, 2019, 33(Z2): 48-52.
[2] 赵秋丽, 卞洁鹏, 杨庆浩, 彭龙贵, 王志华, 后振中, 李颖. 聚集诱导发红光材料在生物成像领域的应用[J]. 材料导报, 2019, 33(3): 522-535.
[3] 赵秋丽, 王金磊, 杨庆浩, 陈进, 后振中. 烷基链长对四苯基乙烯衍生物聚集行为和光学性质的影响*[J]. 《材料导报》期刊社, 2017, 31(8): 6-10.
[4] 李娜, 李曦, 褚梅, 程丹, 周键, 陈奇, 李玉刚, 董玉林. DNA电化学传感器对金属离子检测的研究进展*[J]. 《材料导报》期刊社, 2017, 31(11): 115-120.
[1] Wei ZHOU, Xixi WANG, Yinlong ZHU, Jie DAI, Yanping ZHU, Zongping SHAO. A Complete Review of Cobalt-based Electrocatalysts Applying to Metal-Air Batteries and Intermediate-Low Temperature Solid Oxide Fuel Cells[J]. Materials Reports, 2018, 32(3): 337 -356 .
[2] Yanzhen WANG, Mingming CHEN, Chengyang WANG. Preparation and Electrochemical Properties Characterization of High-rate SiO2/C Composite Materials[J]. Materials Reports, 2018, 32(3): 357 -361 .
[3] Yimeng XIA, Shuai WU, Feng TAN, Wei LI, Qingmao WEI, Chungang MIN, Xikun YANG. Effect of Anionic Groups of Cobalt Salt on the Electrocatalytic Activity of Co-N-C Catalysts[J]. Materials Reports, 2018, 32(3): 362 -367 .
[4] Dongyong SI, Guangxu HUANG, Chuanxiang ZHANG, Baolin XING, Zehua CHEN, Liwei CHEN, Haoran ZHANG. Preparation and Electrochemical Performance of Humic Acid-based Graphitized Materials[J]. Materials Reports, 2018, 32(3): 368 -372 .
[5] Huanchun WU, Fei XUE, Chengtao LI, Kewei FANG, Bin YANG, Xiping SONG. Fatigue Crack Initiation Behaviors of Nuclear Power Plant Main Pipe Stainless Steel in Water with High Temperature and High Pressure[J]. Materials Reports, 2018, 32(3): 373 -377 .
[6] Miaomiao ZHANG,Xuyan LIU,Wei QIAN. Research Development of Polypyrrole Electrode Materials in Supercapacitors[J]. Materials Reports, 2018, 32(3): 378 -383 .
[7] Qingshun GUAN,Jian LI,Ruyuan SONG,Zhaoyang XU,Weibing WU,Yi JING,Hongqi DAI,Guigan FANG. A Survey on Preparation and Application of Aerogels Based on Nanomaterials[J]. Materials Reports, 2018, 32(3): 384 -390 .
[8] Yunzi LIU,Wei ZHANG,Zhanyong SONG. Technological Advances in Preparation and Posterior Treatment of Metal Nanoparticles-based Conductive Inks[J]. Materials Reports, 2018, 32(3): 391 -397 .
[9] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[10] Lanyan LIU,Jun SONG,Bowen CHENG,Wenchi XUE,Yunbo ZHENG. Research Progress in Preparation of Lignin-based Carbon Fiber[J]. Materials Reports, 2018, 32(3): 405 -411 .
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed