碳酸盐基常固态复合相变材料的制备与性能研究

材料导报

2020, Vol. 34

Issue (Z1): 137-139

无机非金属及其复合材料

碳酸盐基常固态复合相变材料的制备与性能研究

王启扬, 杨波

南瑞集团(国网电力科学研究院)有限公司,南京 211100

Research on Preparation and Properties of Carbonate-based Constant-Solid-StatedComposite Phase Change Materials

WANG Qiyang, YANG Bo

NARI Group Corporation (State Grid Electric Power Research Institute), Nanjing 211100, China

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摘要采用混合烧制工艺制备碳酸基常固态复合相变材料,研究碳酸盐和纳米吸附剂的配比对复合相变材料循环致密度的影响,确定最佳配比为6∶1.6(质量比)。热循环实验表明,不同配比的复合相变材料在循环5次后的质量趋于稳定。研究石墨与碳化硅导热材料对复合相变材料导热系数的影响,发现石墨虽能够大幅提升复合材料的导热系数,但其在高温循环过程中的氧化问题难以控制;而碳化硅与之相反,虽导热率略低,但能保证体系长期的使用稳定性。

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关键词: 常固态复合材料最优配比循环稳定性导热填充

Abstract: The carbonate-based constant-solid-stated composite phase change materials were prepared by mixed sintering process, the effects of addition ratio of carbonate and nano-adsorbent on the cyclic density of the composites were studied.The results show that the optimal ratio of carbonate and nano-adsorbent is 6∶1.6(mass ratio). The thermal cycle experiment indicates that the composites'density with different ratios tend to be stable after 5 cycles. The effects of different thermal conductive materials on the thermal conductivity of the composites were also investigated. We find that although graphite could greatly improve the thermal conductivity of the composites, the oxidation of graphite in the high-temperature cycle is difficult to control. Silicon carbide, on the other hand, can guarantee the long-term stability of the system, although the thermal conductivity is slightly lower.

Key words: constant-solid-stated composite materials optimal proportion cycle stability thermal conductive fillers

发布日期: 2020-07-01

ZTFLH:

TB32

基金资助: 国家重点研发计划资助项目(2018YFB0905000)

作者简介: 王启扬,2013年研究生毕业于武汉理工大学材料科学与工程学院,现任职于南瑞集团(国网电力科学研究院)有限公司。研究工作主要围绕太阳能光热综合利用及先进储能系统,授权发明专利3项,发表论文5篇。承担国网公司科技项目3项、江苏省重点示范项目1项,开发储冷、储热产品3款。

引用本文:

王启扬, 杨波. 碳酸盐基常固态复合相变材料的制备与性能研究[J]. 材料导报, 2020, 34(Z1): 137-139.
WANG Qiyang, YANG Bo. Research on Preparation and Properties of Carbonate-based Constant-Solid-StatedComposite Phase Change Materials. Materials Reports, 2020, 34(Z1): 137-139.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2020/V34/IZ1/137

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